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公开(公告)号:DE2937224A1
公开(公告)日:1981-04-02
申请号:DE2937224
申请日:1979-09-14
Applicant: BASF AG
Abstract: New alkoxylated amine cpds. (I) have the formula RR1N-CH2-CH(CH2Z)-O- (CHR4-CHR5-O)n-(CH2-CH2-O)m-H Z is -NR2R3 or -OR6. R is phenyl, opt. with 1-3 1-12C alkyl substits., alpha- or beta-naphthyl. R1 and R3 are H, 1-4C alkyl or -(CHR4-CHR5-O)n-(CH2-CH2-O)m-H. R2 is R or 12-20C alkyl(ene). R4 is Me or Et. R5 is H or Me. R6 is R or phenyl, opt. with 1-3 C6H5-CHMe substits. n is 0-10. m is 8-50. (I) are specified for use as emulsifiers, esp. in an amt. of 0.1-2.5wt.% in printing inks, which may or may not contain petrol. They have a high emulsifying effect and are useful in printing inks which are water-in-oil emulsions, ensuring good reproducibility of the pressure drop.
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公开(公告)号:DE2839463A1
公开(公告)日:1980-03-27
申请号:DE2839463
申请日:1978-09-11
Applicant: BASF AG
IPC: C07C41/00 , C07C43/20 , C07C43/23 , C07C67/00 , C08G65/00 , C08G65/26 , C08G65/28 , C09K23/00 , C09K23/42 , D06P1/613 , C07C43/26
Abstract: Oxyalkylated 1,3-bis-aryl-glycerol ethers of the formula (I) where R and R1 are aromatic substituents, R2 is -CH3 or -C2H5, R3 is -H or -CH3, n is from 0 to 10 and m is from 8 to 50. The compounds of the formula I are used as emulsifiers, preferably in the preparation of print pastes.
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公开(公告)号:DE2554082A1
公开(公告)日:1977-06-23
申请号:DE2554082
申请日:1975-12-02
Applicant: BASF AG
IPC: C08F2/32 , C08F20/56 , C09K23/42 , C08F120/56 , B01F17/44
Abstract: Stable water-in-oil dispersions of acrylamide (co)polymers are prepd. by polymerising a water-in-oil emulsion of an acrylamide soln., opt. with other water-sol. ethylenically unsatd. monomers, in an organic hydrophobic dispersion medium, in presence of a polymerisation initiator and an emulsifier. The emulsifiers are prepd. by reacting 1 mole of 10-22C (un)satd. fatty alcohols with 0.5-1.5 (1) moles epichlorohydrin, to form glycidyl ethers; 1 mole of the glycidyl ethers is then reacted with 0.5-6 moles of a 2-6C polyalcohol with 2-6 OH gps., or a mono-ether of such an alcohol with a 10-22C fatty alcohol, in presence of an acid or a base. The dispersions are used as flocculants for clarifying aq. systems, in paper mfr., in treating residual water, as dispersants and protective colloids in drilling muds, and as auxiliaries in flood water in sec. petroleum recovery. The dispersions are stable to sedimentation, and can be highly diluted with water.
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公开(公告)号:DE2544217A1
公开(公告)日:1977-04-21
申请号:DE2544217
申请日:1975-10-03
Applicant: BASF AG
Inventor: SCHUMACHER HORST DIPL CHEM DR , TIEFENBACHER HUBERT DR MED , KRAPF HEINZ DIPL CHEM DR , OPPENLAENDER KNUT DIPL CHEM DR
IPC: A23D7/01 , A23D9/013 , A23K20/158 , A23K1/00 , A23C11/00
Abstract: New emulsifier mixt. contains, as co-emulsifier, >=1 monoester of glycerol with a natural 10-24C unsatd. fatty acid, oxyethylated, on av. 6-9 (6.5-8.5) times molecule. Emulsifier is a soya oil- contg. lecithin. Mixt. is partic. useful in nutrition of young animals, e.g. calves and piglets. Monoglyceride oxyethylate, (I), compensates for low emulsifying properties of lecithin. Thus, addn. of 0.2 g glycerol monooleate + 7.5 C2H4O to 1 g lecithin and 20 g fat, gave a mixt. contg. 100 vol. % emulsion after 5, 30 and 60 min. and 99 vol. % emulsion after 24 hrs. No emulsion was obtd. without (I). (I) are liquid.
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公开(公告)号:DE3030053A1
公开(公告)日:1982-03-25
申请号:DE3030053
申请日:1980-08-08
Applicant: BASF AG
Inventor: HAHN KLAUS DIPL CHEM DR , RATH HANS PETER DIPL CHEM DR , KRAPF HEINZ DIPL CHEM DR , DEGRAVE ISIDOR DIPL PHYS DR , WALTER MANFRED DIPL CHEM DR
Abstract: Particulate styrene polymers which contain a blowing agent and are surface-coated with from 0.05 to 1% by weight of an ester. The coating agent is a hydroxycarboxylic acid ester, or an ester of a carboxylic acid with an oxyalkylated alcohol; tristearyl citrate is a preferred ester. The styrene polymers can be used to produce foam moldings, with short mold dwell times and good welding of the foam particles.
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公开(公告)号:DE2623085A1
公开(公告)日:1977-12-08
申请号:DE2623085
申请日:1976-05-22
Applicant: BASF AG
Abstract: Prodn. of water-in-oil emulsifiers (I) comprises first reacting opt. unsatd. 10-22C fatty alcohol (or mixts.) with epichlorohydrin at mole ratio 1:0.5-1.5 to give a glycidyl ether. This is then reacted with amines of formula R1R2R3N (II) in presence of acids or bases at mole ratio 1:0.1-6. (R1 and R2 are each H or 2-4C hydroxyalkyl and R3 = 2-4C hydroxyalkyl, or -(CH2)m- -Y-(CH2)m'- nX in which case R1=R2=H. Y = O or NH; and m and m' = 2 or 3; n = 0-6 and X = NH2 or OH). Used esp. in the cosmetic industry, (I) are at least as good as the fatty alcohol monoether emulsifiers of the parent patent, can be be used for all applications and are stable towards all likely chemical influences.
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公开(公告)号:DE3039770A1
公开(公告)日:1982-05-27
申请号:DE3039770
申请日:1980-10-22
Applicant: BASF AG
Inventor: KLEUSER DIETER DIPL CHEM DR , OPPENLAENDER KNUT DIPL CHEM DR , KRAPF HEINZ DIPL CHEM DR , STORK KARL DIPL CHEM DR , STRICKLER RAINER DIPL CHEM DR , FAULHABER GERHARD DIPL CHEM DR
Abstract: 1. The use of a compound of the formula I see diagramm : EP0050228,P9,F6 where R**1 and R**2 are identical or different and each is see diagramm : EP0050228,P9,F7 see diagramm : EP0050228,P9,F8 -O-alpha-naphthyl or O-beta-naphthyl, where R**4 , R**5 and R**6 are identical or different and each is H, C1 -C12 -alkyl or C7 -C10 -aralkyl, and R**7 is hydrogen or methyl and R**3 is a radical of the formula II or III -(C2 H4 O)n (C3 H6 O)m H -(C3 H6 O)m (C2 H4 O)n H, where n is a number from 0 to 50 and m is a number from 0 to 50, with the proviso that m or n is 5 or more, as a non-ionic oil-in-water emulsifier component for crop protection formulations.
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公开(公告)号:DE2949535A1
公开(公告)日:1981-06-11
申请号:DE2949535
申请日:1979-12-08
Applicant: BASF AG
Inventor: OPPENLAENDER KNUT DIPL CHEM DR , KRAPF HEINZ DIPL CHEM DR , STRICKLER RAINER DIPL CHEM DR , HOVEMANN FRIEDRICH DIPL CHEM D , STARKE KLAUS DIPL ING , SCHMIDT HELMUT ING GRAD
Abstract: Diesel fuels consist of (a) a petroleum middle distillate, suitable on its own as a diesel fuel (pref. at least 60 vol.%), (b) a smaller concn. of methanol (pref. 10-25 vol.%), and (c) aliphatic 6-20C (9-11C) alcohols, opt. etherified (pref. 5-15% of an alcohol liquid at ambient temp.). Component (c) acts as solvent for (a) and (b). The fuels make it possible to use in diesel engines at least some methanol (which can be made through synthesis gas from non-oil sources. The addn. of C gives homogeneous mixts. of relatively good ignitability.
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10.
公开(公告)号:DE2949118A1
公开(公告)日:1981-06-11
申请号:DE2949118
申请日:1979-12-06
Applicant: BASF AG
Inventor: OPPENLAENDER KNUT DIPL CHEM DR , KRAPF HEINZ DIPL CHEM DR , STRICKLER RAINER DIPL CHEM DR , HOVEMANN FRIEDRICH DIPL CHEM D , STARKE KLAUS DIPL ING , SCHMIDT HELMUT ING GRAD
Abstract: Diesel fuels consisting of (a) a petroleum middle distillate, suitable as a diesel fuel (pref. at least 60 vol.%); (b) a smaller concn. of ethanol (pref. 10-25 vol.%); and (c) 5-20C (9-11C) aliphatic alcohols, opt. etherified (pref. 5-15 vol.% of a 8-18C alcohol, liq. at ambient temp.). Component (c) acts as solvent for (a) and (b). The fuels make it possible to use at least some ethanol (a plant-derived prod.) in diesel engines (low ignitability prevents its use alone. Component (c) makes the mixt. less sensitive to phase sepn. by water addn. and improves the cold stability. The ignitability is relatively good.
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