公开(公告)号：WO2004024668A3

公开(公告)日：2004-10-14

申请号：PCT/EP0308831

申请日：2003-08-08

Applicant: BASF AG ,  FUNKE FRANK ,  HILL THOMAS ,  VON WATZDORF JOBST RUEDIGER ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED

Inventor： FUNKE FRANK ,  HILL THOMAS ,  VON WATZDORF JOBST RUEDIGER ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED

IPC: C07C209/86 ,  B01D3/14 ,  C07C209/84 ,  C07C211/36

CPC classification number: B01D3/141 ,  B01D3/146 ,  C07C209/84 ,  Y10S203/20 ,  C07C211/36

Abstract: The invention relates to a method for obtaining 3-aminomethyl-3,5,5-trimethyl cyclohexylamine (isophorone diamine, IPDA) with a cis/trans isomer ratio of at least 73/27 by fractional distillation. Said method comprises the following steps: a) preparation of IPDA with a cis/trans isomer ratio /=73/27 and iv) an IPDA fraction with a cis/trans isomer ratio

Abstract translation: 本发明涉及一种用于具有顺式/反式异构体中的至少73/27通过分馏，其包括以下步骤比率回收3-氨基甲基-3,5,5-三甲基环己胺（异佛尔酮二胺，IPDA）：a）提供 具有IPDA顺/反异构体比率<73/27; b）将IPDA送入蒸馏塔的中间区域具有内部和在一定温度下在该蒸馏塔中蒸馏IPDA。 为5〜300℃，为10〜2000毫巴的压力; c）任选地进一步纯化由步骤b）通过在至少一个另外的塔中蒸馏得到IPDA; 其中，所述步骤b）和c）需要在步骤a中使用的IPDA的分离）放置到至少五个级分IA）至iv）：IA）erunreinigungen低于一小部分的有机比例反式IPDA沸腾V，IB）的含水部分 一小部分比反式IPDA沸点杂质下，ii）除了顺式IPDA沸点杂质更高的馏分，iii）具有> = 73/27的顺/反异构体比率的IPDA馏分和iv）具有顺式的IPDA馏分 式/反式异构体比率<= 66/34。

公开(公告)号：AT343561T

公开(公告)日：2006-11-15

申请号：AT03794858

申请日：2003-08-08

Applicant: BASF AG

Inventor： FUNKE FRANK ,  HILL THOMAS ,  VON WATZDORF JOBST RUEDIGER ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED

IPC: C07C209/86 ,  B01D3/14 ,  C07C209/84 ,  C07C211/36

Abstract: Recovery of isophoronediamine (IPDA) comprises preparation of IPDA having a cis/trans isomer ratio of less than 73/27 and separation into at least 5 fractions by distillation including an IPDA fraction having a cis/trans ratio of greater than 73/27 and a fraction having a cis/trans ratio of less than 66/34. A process for the recovery of 3-aminomethyl-3,5,5-trimethylcyclohexylamine (isophoronediamine, IPDA) comprises; (a) preparation of IPDA having a cis/trans isomer ratio of less than 73/27; (b) introduction of IPDA to the middle region of a distillation column having inserts and distillation of IPDA at 5-300 degreesC and 10-2000 mbar; (c) optionally further purification of the IPDA from (b) by distillation in at least one further column whereby the IPDA from step (b) and (c) are separated into at least 5 fractions comprising an organic fraction (1a) containing impurities having a lower b. pt. than trans-IPDA, an aqueous fraction (1b) containing impurities having a lower b. pt. than trans-IPDA, a fraction (2) containing impurities having a higher b. pt. than cis-IPDA, an IPDA fraction (3) having a cis/trans ratio of greater than 73/27 and an IPDA fraction (4) having a cis/trans ratio of less than 66/34.

公开(公告)号：AU2003258591A1

公开(公告)日：2004-04-30

申请号：AU2003258591

申请日：2003-08-08

Applicant: BASF AG

Inventor： HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED ,  FUNKE FRANK ,  HILL THOMAS ,  WATZDORF JOBST RUDIGER VON ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG

IPC: C07C209/86 ,  B01D3/14 ,  C07C209/84 ,  C07C211/36 ,  C07C209/00

Abstract: Recovery of isophoronediamine (IPDA) comprises preparation of IPDA having a cis/trans isomer ratio of less than 73/27 and separation into at least 5 fractions by distillation including an IPDA fraction having a cis/trans ratio of greater than 73/27 and a fraction having a cis/trans ratio of less than 66/34. A process for the recovery of 3-aminomethyl-3,5,5-trimethylcyclohexylamine (isophoronediamine, IPDA) comprises; (a) preparation of IPDA having a cis/trans isomer ratio of less than 73/27; (b) introduction of IPDA to the middle region of a distillation column having inserts and distillation of IPDA at 5-300 degreesC and 10-2000 mbar; (c) optionally further purification of the IPDA from (b) by distillation in at least one further column whereby the IPDA from step (b) and (c) are separated into at least 5 fractions comprising an organic fraction (1a) containing impurities having a lower b. pt. than trans-IPDA, an aqueous fraction (1b) containing impurities having a lower b. pt. than trans-IPDA, a fraction (2) containing impurities having a higher b. pt. than cis-IPDA, an IPDA fraction (3) having a cis/trans ratio of greater than 73/27 and an IPDA fraction (4) having a cis/trans ratio of less than 66/34.

公开(公告)号：AU2003263200A1

公开(公告)日：2004-03-19

申请号：AU2003263200

申请日：2003-08-06

Applicant: BASF AG

Inventor： WATZDORF JOBST RUDIGER VON ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED ,  FUNKE FRANK ,  HILL THOMAS

IPC: C07C209/54 ,  C07B61/00 ,  C07C29/68 ,  C07C209/82 ,  C07C209/84 ,  C07C209/86 ,  C07C211/36

Abstract: Pure isophorone-diamine (IPDA) with a cis/trans isomer ratio (CTR) of at least 73/27 is obtained by (a) making crude IPDA with a CTR below 73/27, (b) purifying and separating into fractions with CTR of at least 73/27 (b1) and below 63/37 (b2), (c) isomerizing (b2) in presence of hydrogen, ammonia and catalyst to give IPDA with a CTR of 63/37-66/34 which is recycled to stage (a). A method (M1) for the production of substantially pure 3-aminomethyl-3,5,5-trimethyl cyclohexylamine (isophorone-diamine; IPDA) with a cis/trans isomer ratio (CTR) of at least 73/27 involves: (a) preparation of crude IPDA with a CTR of less than 73/27, (b) purification and separation to give fractions (b1) with a CTR of at least 73/27 and (b2) with a CTR of less than 63/27 and (c) isomerization of (b2) in presence of hydrogen, ammonia and a hydrogenation catalyst to give IPDA with a CTR of 63/37-66/34 which is then recycled to stage (a). An Independent claim is also included for a method (M2) for the production of IPDA with a CTR in the range 63/37 to 66/34 by reacting IPDA with any CTR value with hydrogen and ammonia in presence of a hydrogenation catalyst.

公开(公告)号：DE10236674A1

公开(公告)日：2004-02-19

申请号：DE10236674

申请日：2002-08-09

Applicant: BASF AG

Inventor： FUNKE FRANK ,  HILL THOMAS ,  WATZDORF JOBST RUEDIGER VON ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED

IPC: C07C209/86 ,  B01D3/14 ,  C07C209/84 ,  C07C211/36 ,  C07C209/82 ,  B01D3/00

Abstract: Recovery of isophoronediamine (IPDA) comprises preparation of IPDA having a cis/trans isomer ratio of less than 73/27 and separation into at least 5 fractions by distillation including an IPDA fraction having a cis/trans ratio of greater than 73/27 and a fraction having a cis/trans ratio of less than 66/34. A process for the recovery of 3-aminomethyl-3,5,5-trimethylcyclohexylamine (isophoronediamine, IPDA) comprises; (a) preparation of IPDA having a cis/trans isomer ratio of less than 73/27; (b) introduction of IPDA to the middle region of a distillation column having inserts and distillation of IPDA at 5-300 degreesC and 10-2000 mbar; (c) optionally further purification of the IPDA from (b) by distillation in at least one further column whereby the IPDA from step (b) and (c) are separated into at least 5 fractions comprising an organic fraction (1a) containing impurities having a lower b. pt. than trans-IPDA, an aqueous fraction (1b) containing impurities having a lower b. pt. than trans-IPDA, a fraction (2) containing impurities having a higher b. pt. than cis-IPDA, an IPDA fraction (3) having a cis/trans ratio of greater than 73/27 and an IPDA fraction (4) having a cis/trans ratio of less than 66/34.

公开(公告)号：DE50308078D1

公开(公告)日：2007-10-11

申请号：DE50308078

申请日：2003-08-06

Applicant: BASF AG

Inventor： FUNKE FRANK ,  HILL THOMAS ,  VON WATZDORF JOBST RUEDIGER ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED

IPC: C07C209/54 ,  C07C209/84 ,  C07B61/00 ,  C07C29/68 ,  C07C209/82 ,  C07C209/86 ,  C07C211/36

Abstract: Pure isophorone-diamine (IPDA) with a cis/trans isomer ratio (CTR) of at least 73/27 is obtained by (a) making crude IPDA with a CTR below 73/27, (b) purifying and separating into fractions with CTR of at least 73/27 (b1) and below 63/37 (b2), (c) isomerizing (b2) in presence of hydrogen, ammonia and catalyst to give IPDA with a CTR of 63/37-66/34 which is recycled to stage (a). A method (M1) for the production of substantially pure 3-aminomethyl-3,5,5-trimethyl cyclohexylamine (isophorone-diamine; IPDA) with a cis/trans isomer ratio (CTR) of at least 73/27 involves: (a) preparation of crude IPDA with a CTR of less than 73/27, (b) purification and separation to give fractions (b1) with a CTR of at least 73/27 and (b2) with a CTR of less than 63/27 and (c) isomerization of (b2) in presence of hydrogen, ammonia and a hydrogenation catalyst to give IPDA with a CTR of 63/37-66/34 which is then recycled to stage (a). An Independent claim is also included for a method (M2) for the production of IPDA with a CTR in the range 63/37 to 66/34 by reacting IPDA with any CTR value with hydrogen and ammonia in presence of a hydrogenation catalyst.

公开(公告)号：AT371638T

公开(公告)日：2007-09-15

申请号：AT03790870

申请日：2003-08-06

Applicant: BASF AG

Inventor： FUNKE FRANK ,  HILL THOMAS ,  VON WATZDORF JOBST ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED

IPC: C07C209/54 ,  C07C209/84 ,  C07B61/00 ,  C07C29/68 ,  C07C209/82 ,  C07C209/86 ,  C07C211/36

Abstract: Pure isophorone-diamine (IPDA) with a cis/trans isomer ratio (CTR) of at least 73/27 is obtained by (a) making crude IPDA with a CTR below 73/27, (b) purifying and separating into fractions with CTR of at least 73/27 (b1) and below 63/37 (b2), (c) isomerizing (b2) in presence of hydrogen, ammonia and catalyst to give IPDA with a CTR of 63/37-66/34 which is recycled to stage (a). A method (M1) for the production of substantially pure 3-aminomethyl-3,5,5-trimethyl cyclohexylamine (isophorone-diamine; IPDA) with a cis/trans isomer ratio (CTR) of at least 73/27 involves: (a) preparation of crude IPDA with a CTR of less than 73/27, (b) purification and separation to give fractions (b1) with a CTR of at least 73/27 and (b2) with a CTR of less than 63/27 and (c) isomerization of (b2) in presence of hydrogen, ammonia and a hydrogenation catalyst to give IPDA with a CTR of 63/37-66/34 which is then recycled to stage (a). An Independent claim is also included for a method (M2) for the production of IPDA with a CTR in the range 63/37 to 66/34 by reacting IPDA with any CTR value with hydrogen and ammonia in presence of a hydrogenation catalyst.

公开(公告)号：DE50305512D1

公开(公告)日：2006-12-07

申请号：DE50305512

申请日：2003-08-08

Applicant: BASF AG

Inventor： FUNKE FRANK ,  HILL THOMAS ,  VON WATZDORF RUEDIGER ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED

IPC: C07C209/86 ,  B01D3/14 ,  C07C209/84 ,  C07C211/36

Abstract: Recovery of isophoronediamine (IPDA) comprises preparation of IPDA having a cis/trans isomer ratio of less than 73/27 and separation into at least 5 fractions by distillation including an IPDA fraction having a cis/trans ratio of greater than 73/27 and a fraction having a cis/trans ratio of less than 66/34. A process for the recovery of 3-aminomethyl-3,5,5-trimethylcyclohexylamine (isophoronediamine, IPDA) comprises; (a) preparation of IPDA having a cis/trans isomer ratio of less than 73/27; (b) introduction of IPDA to the middle region of a distillation column having inserts and distillation of IPDA at 5-300 degreesC and 10-2000 mbar; (c) optionally further purification of the IPDA from (b) by distillation in at least one further column whereby the IPDA from step (b) and (c) are separated into at least 5 fractions comprising an organic fraction (1a) containing impurities having a lower b. pt. than trans-IPDA, an aqueous fraction (1b) containing impurities having a lower b. pt. than trans-IPDA, a fraction (2) containing impurities having a higher b. pt. than cis-IPDA, an IPDA fraction (3) having a cis/trans ratio of greater than 73/27 and an IPDA fraction (4) having a cis/trans ratio of less than 66/34.

公开(公告)号：AU2003258591A8

公开(公告)日：2004-04-30

申请号：AU2003258591

申请日：2003-08-08

Applicant: BASF AG

Inventor： HARDER WOLFGANG ,  WATZDORF JOBST RUDIGER VON ,  LITTMANN GERD ,  MATTMANN WOLFGANG ,  HILL THOMAS ,  HENKES ERHARD ,  JULIUS MANFRED ,  FUNKE FRANK

IPC: C07C209/86 ,  B01D3/14 ,  C07C209/84 ,  C07C211/36

Abstract: Recovery of isophoronediamine (IPDA) comprises preparation of IPDA having a cis/trans isomer ratio of less than 73/27 and separation into at least 5 fractions by distillation including an IPDA fraction having a cis/trans ratio of greater than 73/27 and a fraction having a cis/trans ratio of less than 66/34. A process for the recovery of 3-aminomethyl-3,5,5-trimethylcyclohexylamine (isophoronediamine, IPDA) comprises; (a) preparation of IPDA having a cis/trans isomer ratio of less than 73/27; (b) introduction of IPDA to the middle region of a distillation column having inserts and distillation of IPDA at 5-300 degreesC and 10-2000 mbar; (c) optionally further purification of the IPDA from (b) by distillation in at least one further column whereby the IPDA from step (b) and (c) are separated into at least 5 fractions comprising an organic fraction (1a) containing impurities having a lower b. pt. than trans-IPDA, an aqueous fraction (1b) containing impurities having a lower b. pt. than trans-IPDA, a fraction (2) containing impurities having a higher b. pt. than cis-IPDA, an IPDA fraction (3) having a cis/trans ratio of greater than 73/27 and an IPDA fraction (4) having a cis/trans ratio of less than 66/34.