1.
    发明专利
    未知

    公开(公告)号:DE3137132A1

    公开(公告)日:1983-04-07

    申请号:DE3137132

    申请日:1981-09-18

    Applicant: BASF AG

    Abstract: For the preparation of elastic flexible polyurethane foams with improved breaking elongation and very good setting behavior as well as densities from 7 to 120 grams per liter, organic polyisocyanates are reacted in the presence of blowing agents, catalysts and, optionally, auxiliaries and/or additives with polyols based on polyoxyalkylene polyols having terminal oxyethylene blocks of a degree of oxyethlation of 1 to 13 and which have a content of primary hydroxyl groups at the corresponding degree of oxyethylation equal or exceeding the value of curve A in the Figure in which curve A describing the relationship of the content of primary hydroxyl groups with the degree of oxyethylation.

    4.
    发明专利
    未知

    公开(公告)号:DE3005034A1

    公开(公告)日:1981-08-20

    申请号:DE3005034

    申请日:1980-02-11

    Applicant: BASF AG

    Abstract: A process for coating electrically conductive objects comprising A. immersing said object as the anode of an electric current in an aqueous polyurethane dispersion prepared by (1) forming a polyurethane solution by reacting an organic polyisocyanate in the presence of an organic solvent with (a) an acrylic ester diol having a molecular weight of between 146 and 3,000; (b) an organic polyhydroxyl compound other than (a) having a molecular weight between 400 and 5,000 selected from the group consisting of polyester, polyols, polyether polyols, polycarbonates, polylactones, and mixtures thereof; and (c) a chain extender selected from the group consisting of diols, triols, diamines, aminoalcohols, having a molecular weight between 62 and 400, water, and mixtures thereof; (2) forming an anionic polyurethane addition product by reacting said polyurethane solution with a mercaptocarboxylic acid salt in the presence of a solvent; (3) adding water; and (4) removing the organic solvent, and B. passing an electric current between the anode and a cathode which is also dispersed in said dispersion, and C. irradiating said object with ultraviolet radiation or electron rays. The process can be used for coating metals such as iron, steel and aluminum.

    5.
    发明专利
    未知

    公开(公告)号:DE3005035A1

    公开(公告)日:1981-08-20

    申请号:DE3005035

    申请日:1980-02-11

    Applicant: BASF AG

    Abstract: A process for the preparation of polymerizable, primarily linear thermoplastic polyurethane elastomers with acrylate side groups comprising reacting an organic polyisocyanate with a mixture of (a) an acrylate diol having a molecular weight of 146 to 3000, (b) an organic polyhydroxyl compound other than those of paragraph (a) having a molecular weight between 400 and 5000, and (c) a chain extender selected from the group consisting of diols, diamines, aminoalcohols, and triols, having molecular weights between 61 and 400, water, and mixtures thereof wherein the ratio of isocyanate to active hydrogen containing groups is from 0.8:1 to 1.2:1 and wherein 1.4 to 1.8 moles of organic polyisocyante, 0 to 15 moles of component (c) and 0.3 to 6 moles of component (a) are used per mole of component (b). The polymerizable polyurethane elastomers may be used for the manufacture of molded parts, laminates, adhesives, coatings, magnetic tapes, and other articles.

    6.
    发明专利
    未知

    公开(公告)号:DE2909994A1

    公开(公告)日:1980-10-02

    申请号:DE2909994

    申请日:1979-03-14

    Applicant: BASF AG

    Abstract: Acylphosphine oxide compounds of the general formula where R1 is alkyl, cyclohexyl, cyclopentyl, aryl which is unsubstituted or substituted by halogen, alkyl or alkoxy, or an S-containing or N-containing five-membered or six-membered heterocyclic radical, R2 has one of the meanings of R1 (but R1 and R2 may be identical or different) or is alkoxy, aryloxy or aralkoxy, or R1 and R2 together form a ring and R3 is an at least disubstituted phenyl, pyridyl, furyl or thienyl radical which carries, at least at the two carbon atoms adjacent to the linkage point of the carbonyl group, the substituents A and B, which may be identical or different, and each of which is alkyl, alkoxy or alkylthio of 1 to 6 carbon atoms, cycloalkyl of 5 to 7 carbon atoms, phenyl or halogen, or R3 is alpha -naphthyl substituted by A and B at least in the 2- and 8-positions or is beta -naphthyl substituted by A and B at least in the 1- and 3-positions, a process for the preparation of these acylphosphine oxide compounds from acid halides of the general formula where X is chlorine or bromine, and a phosphine of the general formula and the use of these acylphosphine oxide compounds as photoinitiators in photopolymerizable surface coatings, finishes and printing inks.

    7.
    发明专利
    未知

    公开(公告)号:DE2830927A1

    公开(公告)日:1980-01-31

    申请号:DE2830927

    申请日:1978-07-14

    Applicant: BASF AG

    Abstract: Acylphosphine oxide compounds of the general formula where R1 is alkyl, cyclohexyl, cyclopentyl, aryl which is unsubstituted or substituted by halogen, alkyl or alkoxy, or an S-containing or N-containing five-membered or six-membered heterocyclic radical, R2 has one of the meanings of R1 (but R1 and R2 may be identical or different), or is alkoxy, aryloxy or aralkoxy, or R1 and R2 together from a ring, and R3 is straight-chain or branched alkyl of 2 to 18 carbon atoms, a cycloaliphatic radical of 3 to 12 carbon atoms, phenyl or naphthyl which are alkyl-, alkoxy- or thioalkoxy-substituted, or an S-containing or N-containing five-membered or six-membered heterocyclic radical, and may contain additional functional groups, or is the group where R1 and R2 have the above meanings and X is phenyl or an aliphatic or cycloaliphatic divalent radical of 2 to 6 carbon atoms, and one or more of the radicals R1 to R3 may be olefinically unsaturated, a process for the preparation of these acylphosphine oxide compounds from acid halides of the general formula where X is chlorine or bromine, and a phosphine of the general formula and the use of the acylphosphine oxides as photoinitiators in photopolymerizable compositions.

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