公开(公告)号：ES2096396T3

公开(公告)日：1997-03-01

申请号：ES94116512

申请日：1994-10-20

Applicant: BASF AG

Inventor： LANGHAUSER FRANZ DR ,  KERTH JURGEN DR ,  SCHWEIER GUNTHER DR ,  BRINTZINGER HANS-HERBERT PROF ,  MANSEL STEFAN ,  ROELL WERNER DR

IPC: C08F4/622 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/646 ,  C08F4/68 ,  C08F10/00 ,  C08F110/06

Abstract: A process for the preparation of polymers of C2- to C10-alk-1-enes at pressures of from 0.5 to 3000 bar and temperatures of from -50 to 300 DEG C using a catalyst system, characterised in that the catalyst systems used are those containing, as active constituents, a) metallocene complexes of the formula I b) an open-chain or cyclic aluminoxane compound. lk

公开(公告)号：DE59407909D1

公开(公告)日：1999-04-15

申请号：DE59407909

申请日：1994-10-20

Applicant: BASF AG

Inventor： LANGHAUSER FRANZ DR ,  KERTH JUERGEN DR ,  SCHWEIER GUENTHER DR ,  BRINTZINGER HANS-HERBERT PROF ,  MANSEL STEFAN

IPC: C07C22/02 ,  C07F7/08 ,  C07F17/00 ,  C08F4/6192 ,  C08F4/622 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/646 ,  C08F4/68 ,  C08F10/00

Abstract: Metallocene complexes of the general formula I in which the substituents have the following meaning: M is titanium, zirconium, hafnium, vanadium, niobium or tantalum, X is fluorine, chlorine, bromine, iodine, hydrogen, C1- to C10-alkyl, C6- to C15-aryl or -OR , where R is C1- to C10-alkyl, C6- to C15-aryl, alkylaryl, arylalkyl, fluoroalkyl or fluoroaryl in each case having 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, R to R are hydrogen, C1- to C10-alkyl, 5- to 7-membered cycloalkyl which for its part can carry C1- to C10-alkyls as substituents, C6- to C15-aryl or arylalkyl, where, if appropriate, two adjacent radicals together can also stand for cyclic groups having 4 to 15 C atoms, or Si(R )3 where R is C1- to C10-alkyl, C6- to C15-aryl or C3- to C10-cycloalkyl, Z is silicon, germanium, tin or carbon, Y and Y are where R to R are hydrogen, C1- to C10-alkyl, 5- to 7-membered cycloalkyl which for its part can carry C1- to C10-alkyls as substituents, C6- to C15-aryl or arylalkyl, where, if appropriate, two adjacent radicals together can also stand for cyclic groups having 4 to 15 C atoms, or Si(R )3, where R is C1- to C10-alkyl, C6- to C15-aryl or C3- to C10-cycloalkyl, and u, v and w are integers from 0 to 7, with the proviso that the sum u + v + w >/= 2, and cyclopentadienyl compounds of the general formula II and cyclopentadienyl compounds of the general formula III as intermediates.t

公开(公告)号：ES2128486T3

公开(公告)日：1999-05-16

申请号：ES94116511

申请日：1994-10-20

Applicant: BASF AG

Inventor： LANGHAUSER FRANZ DR ,  KERTH JURGEN DR ,  SCHWEIER GUNTHER DR ,  BRINTZINGER HANS-HERBERT PROF ,  MANSEL STEFAN

IPC: C07C22/02 ,  C07F7/08 ,  C07F17/00 ,  C08F4/6192 ,  C08F4/622 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/646 ,  C08F4/68 ,  C08F10/00

Abstract: Metallocene complexes of the general formula I in which the substituents have the following meaning: M is titanium, zirconium, hafnium, vanadium, niobium or tantalum, X is fluorine, chlorine, bromine, iodine, hydrogen, C1- to C10-alkyl, C6- to C15-aryl or -OR , where R is C1- to C10-alkyl, C6- to C15-aryl, alkylaryl, arylalkyl, fluoroalkyl or fluoroaryl in each case having 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, R to R are hydrogen, C1- to C10-alkyl, 5- to 7-membered cycloalkyl which for its part can carry C1- to C10-alkyls as substituents, C6- to C15-aryl or arylalkyl, where, if appropriate, two adjacent radicals together can also stand for cyclic groups having 4 to 15 C atoms, or Si(R )3 where R is C1- to C10-alkyl, C6- to C15-aryl or C3- to C10-cycloalkyl, Z is silicon, germanium, tin or carbon, Y and Y are where R to R are hydrogen, C1- to C10-alkyl, 5- to 7-membered cycloalkyl which for its part can carry C1- to C10-alkyls as substituents, C6- to C15-aryl or arylalkyl, where, if appropriate, two adjacent radicals together can also stand for cyclic groups having 4 to 15 C atoms, or Si(R )3, where R is C1- to C10-alkyl, C6- to C15-aryl or C3- to C10-cycloalkyl, and u, v and w are integers from 0 to 7, with the proviso that the sum u + v + w >/= 2, and cyclopentadienyl compounds of the general formula II and cyclopentadienyl compounds of the general formula III as intermediates.t

公开(公告)号：DE59401703D1

公开(公告)日：1997-03-13

申请号：DE59401703

申请日：1994-10-20

Applicant: BASF AG

Inventor： LANGHAUSER FRANZ DR ,  KERTH JUERGEN DR ,  SCHWEIER GUENTHER DR ,  BRINTZINGER HANS-HERBERT PROF ,  MANSEL STEFAN ,  ROELL WERNER DR ,  KIRSTEN ROBIN

IPC: C08F4/622 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/646 ,  C08F4/68 ,  C08F10/00 ,  C08F110/06

Abstract: A process for the preparation of polymers of C2- to C10-alk-1-enes at pressures of from 0.5 to 3000 bar and temperatures of from -50 to 300 DEG C using a catalyst system, characterised in that the catalyst systems used are those containing, as active constituents, a) metallocene complexes of the formula I b) an open-chain or cyclic aluminoxane compound. lk

公开(公告)号：DE4337232A1

公开(公告)日：1995-05-04

申请号：DE4337232

申请日：1993-10-30

Applicant: BASF AG

Inventor： LANGHAUSER FRANZ DIPL CHEM DR ,  KERTH JUERGEN DIPL CHEM DR ,  SCHWEIER GUENTHER DIPL CHEM DR ,  BRINTZINGER HANS-HERBERT PROF ,  MANSEL STEFAN

IPC: C07C22/02 ,  C07F7/08 ,  C07F17/00 ,  C08F4/6192 ,  C08F4/622 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/646 ,  C08F4/68 ,  C08F10/00 ,  C08F4/76

Abstract: Metallocene complexes of the general formula I in which the substituents have the following meaning: M is titanium, zirconium, hafnium, vanadium, niobium or tantalum, X is fluorine, chlorine, bromine, iodine, hydrogen, C1- to C10-alkyl, C6- to C15-aryl or -OR , where R is C1- to C10-alkyl, C6- to C15-aryl, alkylaryl, arylalkyl, fluoroalkyl or fluoroaryl in each case having 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, R to R are hydrogen, C1- to C10-alkyl, 5- to 7-membered cycloalkyl which for its part can carry C1- to C10-alkyls as substituents, C6- to C15-aryl or arylalkyl, where, if appropriate, two adjacent radicals together can also stand for cyclic groups having 4 to 15 C atoms, or Si(R )3 where R is C1- to C10-alkyl, C6- to C15-aryl or C3- to C10-cycloalkyl, Z is silicon, germanium, tin or carbon, Y and Y are where R to R are hydrogen, C1- to C10-alkyl, 5- to 7-membered cycloalkyl which for its part can carry C1- to C10-alkyls as substituents, C6- to C15-aryl or arylalkyl, where, if appropriate, two adjacent radicals together can also stand for cyclic groups having 4 to 15 C atoms, or Si(R )3, where R is C1- to C10-alkyl, C6- to C15-aryl or C3- to C10-cycloalkyl, and u, v and w are integers from 0 to 7, with the proviso that the sum u + v + w >/= 2, and cyclopentadienyl compounds of the general formula II and cyclopentadienyl compounds of the general formula III as intermediates.t