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    ZIEGLER/NATTA CATALYST MODIFIED IN PROCESS OF PRODUCTION AND ITS PRODUCTION
    3.
    发明专利
    ZIEGLER/NATTA CATALYST MODIFIED IN PROCESS OF PRODUCTION AND ITS PRODUCTION 失效

    公开(公告)号：JPH10152517A

    公开(公告)日：1998-06-09

    申请号：JP24886197

    申请日：1997-09-12

    Applicant: BASF AG

    Inventor： HUEFFER STEPHAN DR ,  MOLL ULRICH DR ,  MAC KENZIE IAN DAVID DR ,  LANGHAUSER FRANZ DR ,  KOELLE PETER DR ,  HINGMANN ROLAND DR ,  SCHWEIER GUENTHER DR ,  HEMMERICH RAINER DR ,  KERTH JUERGEN DR

    IPC: C08F4/02 ,  C08F4/642 ,  C08F4/646 ,  C08F4/654 ,  C08F4/658 ,  C08F10/00

    Abstract: PROBLEM TO BE SOLVED: To provide Ziegler/Natta catalyst composition capable of providing a high productivity and stereospecificity, producible in a short time and capable of reducing the amount a titanium- or a chlorine-containing starting material. SOLUTION: This Ziegler/Natta catalyst composition comprises (a) a titanium- containing solid component, (b) an aluminum compound and, as necessary, (c) an electron donative compound. The component (a) is produced by mixing an inorganic compound as a carrier with a solution of a magnesium compound without containing chlorine in an inert solvent, then reacting the resultant mixture with a 1-8C alkanol in an excessive amount of >=1.3 times based on the magnesium compound at -20 to +80 deg.C under stirring, subsequently mixing the prepared product with a tri- or a tetravalent titanium compound and a carboxylic acid ester as an electron donor without carrying out the purification and extraction thereof, then separating a solid material by filtration, extracting the resultant solid with a solution containing >=5wt.% titanium tetrachloride in an inert solvent and further washing the solid material with a liquid alkane.

    ZIEGLER/NATTA TYPE CATALYST COMPOSITION
    4.
    发明专利
    ZIEGLER/NATTA TYPE CATALYST COMPOSITION 失效

    公开(公告)号：JPH1060040A

    公开(公告)日：1998-03-03

    申请号：JP14884897

    申请日：1997-06-06

    Applicant: BASF AG

    Inventor： HUEFFER STEPHAN DR ,  BIDELL WOLFGANG DR ,  MUELLER PATRIK DR ,  MOLL ULRICH DR ,  HINGMANN ROLAND DR ,  SCHWEIER GUENTHER DR

    IPC: C08F4/654 ,  C08F4/02 ,  C08F4/646 ,  C08F4/658 ,  C08F10/00 ,  C08F110/06

    Abstract: PROBLEM TO BE SOLVED: To obtain the subject composition comprising a specific titanium- containing solid component, a cocatalyst and an electron-donating compound and enabling the production of a polymer having a high bulk density and reduced in xylene and heptane-soluble contents. SOLUTION: This Ziegler/Natta type catalyst composition comprises (A) a Ti-containing solid component comprising a Ti compound, a Mg compound, a halogen, an inorganic oxide and a carboxylate ester as an electron-donating compound, (B) an aluminum compound as a cocatalyst, and selectively (C) one or more other electron-donating compounds. The inorganic oxide in the component A has a pH of 1-6, an average particle diameter of 5-200μm, an average primary particle diameter of 1-20μm, pore spaces and grooves of 0.1-20μm and the whole particle volume marcroshare of 5-30%. The catalyst can give polymers good in mechanical characteristics, and the polymers are suitable for producing shaped products such as films and fibers.

    6.
    发明专利
    未知

    公开(公告)号：DE19606167A1

    公开(公告)日：1997-08-21

    申请号：DE19606167

    申请日：1996-02-20

    Applicant: BASF AG

    Inventor： LYNCH JOHN DR ,  FISCHER DAVID DR ,  GOERTZ HANS-HELMUT DR ,  SCHWEIER GUENTHER DR

    IPC: C08F4/12 ,  C08F4/44 ,  C08F4/60 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/646 ,  C08F4/68 ,  C08F10/00 ,  C08F110/02

    Abstract: Supported catalyst obtainable by A) reacting an inorganic carrier material with a metal compound of the general formula (I): M (R )r(R )s(R )t(R )u in which M is an alkalyne or alkalyne earth metal or a metal of main group III or IV of the periodic system; R is hydrogen, C -C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; R to R are hydrogen, C -C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl, alkoxy or dialkylamino with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; r is a whole number from 1 to 4; and s, t and u are whole numbers from 0 to 3, where the sum r+s+t+u corresponds to the valency of M ; B) reacting the material obtained from A) with a metallocene complex in its metal dihalogenide form and a metallocenium ion-forming compound; and C) subsequent reaction with a metal compound of the general formula (II): M (R )o(R )p(R )q in which M is an alkalyne or alkalyne earth metal or a metal of main group III of the periodic system; R is hydrogen, C -C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; R to R are hydrogen, C -C10 alkyl, C6-C15 aryl, alkyl aryl, aryl alkyl or alkoxy with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; o is a whole number from 1 to 3; and p and q are whole numbers from 0 to 2 where the sum o+p+q corresponds to the valency of M .

    10.
    发明专利
    未知

    公开(公告)号：DE4416876A1

    公开(公告)日：1995-11-16

    申请号：DE4416876

    申请日：1994-05-13

    Applicant: BASF AG

    Inventor： LANGHAUSER FRANZ DR ,  MUELLER HANS-JOACHIM DR ,  KERTH JUERGEN DR ,  SCHWEIER GUENTHER DR ,  RIEGER BERNHARD DR

    IPC: C07F7/00 ,  C07F7/28 ,  C07F9/00 ,  C07F17/00 ,  C08F4/6192 ,  C08F10/00 ,  C07D203/08

    Abstract: The prodn. of bridged half-sandwich complexes of formula (I) comprises reacting cyclopentadienides of formula (II) with aziridines (III) and then reacting the ligand systems obtd. (IV) with metallating agents and MXn+2. M = Sub-gp. IV or V metal or lanthanide; X = halo, H, 1-10C alkyl, 3-10C cycloalkyl, 6-15C aryl, 7-15C alkylaryl or -OR (with R = 1-10C alkyl, 6-15C aryl, or alkaryl, aralkyl, fluoroalkyl or fluoroaryl with 1-10C alkyl gps. and 6-20C aryl gps.). n = valency of M minus 2; R = H, 1-10C alkyl, 3-10C cycloalkyl (opt. substd. with 1-10C alkyl), 6-15C aryl, (6-20C aryl)-(1-10C alkyl) or -Si(R )3 (with R = 1-10C alkyl, 6-15C aryl or 3-10C cycloalkyl); R -R = as for R , opt. with two adjacent gps. forming a 4-15C cyclic gp.

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