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    PRODUCTION OF TERTIARY AMINE FROM NITRILE AND SECONDARY AMINE
    1.
    发明专利
    PRODUCTION OF TERTIARY AMINE FROM NITRILE AND SECONDARY AMINE 失效

    公开(公告)号：JPH10338664A

    公开(公告)日：1998-12-22

    申请号：JP8866898

    申请日：1998-04-01

    Applicant: BASF AG

    Inventor： FUCHS EBERHARD DR ,  BECKER RAINER ,  BREITSCHEIDEL BORIS DR ,  NEUHAUSER HORST DR

    IPC: B01J23/44 ,  C07B61/00 ,  C07C209/48 ,  C07C211/09 ,  C07C211/12 ,  C07C213/02 ,  C07C215/08

    Abstract: PROBLEM TO BE SOLVED: To obtain a tertiary amine by allowing nitrile to react with a secondary amine in the presence of a specific palladium catalyst that is improved in its long-term stability and its operation hours. SOLUTION: A nitrile represented by formula I (R and R are each an alkyl, a cycloalkyl, an aryl, an aralkyl; X is an alkyl, a cycloalkyl, amino, hydroxyl; (n) is 1-4; (m) is 1-2), a secondary amine of formula II and hydrogen are allowed to react to one another at 50-250 deg.C under a pressure of 5-350 bar, thus giving the objective amine of formula III. At this time, it is preferable to use a supported palladium catalyst that has 0.1-10 wt.% of Pd, 0.01-10 wt.% of at least one of other metals selected from the group consisting of metals of the group IB, group VIII of the periodic table, cerium, and lanthanum on the support on the basis of the whole catalyst weight.

    METHOD FOR PRODUCING AMINE
    2.
    发明专利
    METHOD FOR PRODUCING AMINE 失效

    公开(公告)号：JP2001163838A

    公开(公告)日：2001-06-19

    申请号：JP2000370628

    申请日：2000-12-05

    Applicant: BASF AG

    Inventor： NOUWEN JAN ,  HOEHN ARTHUR ,  NEUHAUSER HORST DR ,  FUNKE FRANK DR ,  SCHUNK STEPHAN ANDREAS ,  MELDER JOHANN-PETER DR ,  EGER KNUT ,  HESSE MICHAEL DR ,  WULFF-DAERING JOACHIM DR

    IPC: B01J23/755 ,  C07B61/00 ,  C07C209/26 ,  C07C211/27 ,  C07C211/35 ,  C07C211/38 ,  C07C211/42 ,  C07C213/02 ,  C07C217/58

    Abstract: PROBLEM TO BE SOLVED: To provide a method for producing an amine by a reaction in the presence of a catalyst using a nitrogen compound selected from ammonia, a primary and a secondary amines and hydrogen. SOLUTION: A catalytically active composition of a catalyst after the production and prior to the treatment with hydrogen comprises 22-45 mass % of an oxygen-containing compound of zirconium, 1-30 mass % of an oxygen-containing compound of copper and 5-50 mass % of an oxygen-containing compound of nickel in >1 molar ratio of nickel to copper and further comprises 5-50 mass % of the oxygen-containing compound of cobalt calculated as CoO, 0-5 mass % an oxygen-containing compound of molybdenum and 0-10 mass % of an oxygen-containing compound of the calculated aluminum and/or manganese. Thereby, the economical efficiency of a conventional method is improved and the amine is produced by a technically simple method which can be carried out with a high aldehyde conversion rate and a high ketone conversion rate, a high yield, a high selectivity, a high catalyst useful life and a high mechanical stability of a catalyst molded product.

    REMOVAL OF HALOGENIZED SUBSTANCE FROM NITRIDE MIXTURE CONTAINING THE SAME
    3.
    发明专利
    REMOVAL OF HALOGENIZED SUBSTANCE FROM NITRIDE MIXTURE CONTAINING THE SAME 失效

    公开(公告)号：JPH10265445A

    公开(公告)日：1998-10-06

    申请号：JP4030898

    申请日：1998-02-23

    Applicant: BASF AG

    Inventor： KNEUPER HEINZ-JOSEF DR ,  WEYER HANS-JUERGEN DR ,  NEUHAUSER HORST DR ,  MELDER JOHANN-PETER DR ,  HENNE ANDREAS DR ,  ROSS KARL-HEINZ DR ,  BECKER RAINER

    IPC: B01J27/18 ,  B01J31/02 ,  C07B61/00 ,  C07C209/48 ,  C07C211/09 ,  C07C253/14 ,  C07C253/34 ,  C07C255/04

    Abstract: PROBLEM TO BE SOLVED: To remove a halogenized substance from a nitrile mixture for enabling the production of an amine from the nitrile mixture afterwards by heat/treating the nitrile mixture containing the halogenized substance, adding a base to the heat-treated nitrile mixture and removing the base from the neutral mixture. SOLUTION: This method for removing a halogenized material presenting as a form of a phase transition catalyst from a nitrile mixture, is to perform a heat-treatment the nitride mixture containing the halogenized substance at 50-350 deg.C. The heat treatment is performed by setting the pressure and temperature for distilling the nitrile in the mixture at 50 m bar pressure, and 227-230 deg.C bottom temperature and 163 deg.C top temperature. Then, after adding 5-50 wt.% concentration of a base such as NaO into the nitrile mixture while agitating, the halogenized substance is removed from the nitrile mixture. And then, by hydrogenating the obtained nitrile in the presence of a catalyst such as Ni and Co at 60-160 deg.C, especially preferably 90130 deg.C to form an amine.

    PRODUCTION OF ALKYLAMINE
    4.
    发明专利
    PRODUCTION OF ALKYLAMINE 失效

    公开(公告)号：JPH11100374A

    公开(公告)日：1999-04-13

    申请号：JP20740698

    申请日：1998-07-23

    Applicant: BASF AG

    Inventor： KNEUPER HEINZ-JOSEF DR ,  LEBKUECHER ROLF DR ,  NEUHAUSER HORST DR ,  HENNE ANDREAS DR ,  BECKER RAINER

    IPC: C07D295/02 ,  B01J23/75 ,  C07B37/04 ,  C07B61/00 ,  C07C209/26 ,  C07D295/023

    Abstract: PROBLEM TO BE SOLVED: To economically and continuously obtain an alkylamine in a simplified apparatus by preheating only an amine stream or only an aldehyde stream fed by separated stream during feed and reacting the amine with the aldehyde on a fixed bed catalyst in a reactor. SOLUTION: Only an aldehyde stream [e.g. formaldehyde aqueous solution having 50-90 wt.%, preferably 65-75 wt.% water content based on total weight of the solution] or only an amine stream (preferably 30-80 wt.% piperazine aqueous solution) fed by separated stream is preheated during a feed (a molar ratio of piperazine to formaldehyde is 1:1.0 to 1:5, preferably 1:2 to 1:2.7) is and the aldehyde is reacted with the amine in a reactor in which these compounds are mixed in a catalyst bed on a fixed bed catalyst in the presence of an isolated hydrogen to continuously provide the objective alkylamine.

    N-ALKYLATION OF AMINE
    5.
    发明专利
    N-ALKYLATION OF AMINE 失效

    公开(公告)号：JPH10279569A

    公开(公告)日：1998-10-20

    申请号：JP5196498

    申请日：1998-03-04

    Applicant: BASF AG

    Inventor： SIMON JOACHIM DIPL CHEM DR ,  BECKER RAINER ,  LEBKUECHER ROLF DR ,  NEUHAUSER HORST DR

    IPC: C07D295/02 ,  B01J23/72 ,  B01J23/78 ,  B01J23/86 ,  C07B61/00 ,  C07C209/16 ,  C07C211/03 ,  C07D295/023

    Abstract: PROBLEM TO BE SOLVED: To industrially and economically advantageously N-alkylate an amine by carrying out the reaction in the presence of a specific catalyst. SOLUTION: When (A) an alcohol (preferably an α,ω-diol) is reacted with (B) an alkylamine or a dialkylamine (preferably monomethylamine, etc.), the reaction is carried out in the presence of (C) a catalyst prepared by including 0-2 wt.% BaO, Cr2 O3 and/or ZnO in copper and magnesium silicate as a base regardless thereof for each time as the catalyst. The component C preferably contains 30-60 wt.% CuO and has preferably at least 100 m /g BET specific surface area. The reaction is preferably conducted in the liquid phase under 50-300 bars pressure.

    10.
    发明专利
    未知

    公开(公告)号：DE19713383A1

    公开(公告)日：1998-10-08

    申请号：DE19713383

    申请日：1997-04-01

    Applicant: BASF AG

    Inventor： FUCHS EBERHARD DR ,  BREITSCHEIDEL BORIS DR ,  BECKER RAINER DR ,  NEUHAUSER HORST DR

    IPC: B01J23/44 ,  C07B61/00 ,  C07C209/48 ,  C07C211/09 ,  C07C211/12 ,  C07C213/02 ,  C07C215/08 ,  C07C211/08 ,  C07C209/22 ,  C07B43/04 ,  B01J23/38 ,  B01J23/70

    Abstract: Preparation of mono- or polyfunctional tertiary amines of formula X(CH2NR1R2)n (I) involves reacting a nitrile of formula (R1R2NCH2)n-mX(CN)m (II) with a secondary amine of formula NHR1R2 (III) and hydrogen. The reaction is at 50-250 degrees C and 5-350 bars, in presence of a palladium-based catalyst (IV), comprising (based on total catalyst) 0.1-10 wt.% palladium and 0.01-10 wt.% of at least one other metal, selected from Group IB and VIII elements, cerium and lanthanum, on a carrier. In (I)-(III), R1, R2 = 1-20C alkyl, 3-8C cycloalkyl, 4-20C alkylcycloalkyl, 4-20C cycloalkylalkyl, aryl, 7-20C alkaryl, 7-20C aralkyl, 2-8C hydroxyalkyl, 2-8C mercaptoalkyl or 8-20C aryloxyalkyl; or R1 + R2 = optionally unsaturated 2-6C alkylene chain (optionally substituted by 1-3 1-4C alkyl and optionally interrupted by O); X = n-valent 1-20C alkyl, 2-20C alkenyl or 3-8C cycloalkyl group (optionally substituted by 1-20C alkyl, 3-8C cycloalkyl, 4-20C alkylcycloalkyl, 4-20C cycloalkylalkyl, 2-20C alkoxyalkyl, aryl, 7-20C alkaryl, 7-20C aralkyl, 1-20C alkoxy, OH, 1-20C hydroxyalkyl, 1-20C alkylamino, 2-20C dialkylamino, 2-12C alkenylamino, 3-8C cycloalkylamino, arylamino, diarylamino, aryl-(1-8C)alkylamino, halo, SH, 2-20C alkenyloxy, 3-8C cycloalkoxy, aryloxy or 2-8C alkoxycarbonyl); n = 1-4; and m = 1 to n. Also claimed is the use of (IV) as catalyst for the reaction of secondary amines with nitriles and hydrogen to give tertiary amines in general.

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