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    METHOD FOR PRODUCING AMINE
    1.
    发明专利
    METHOD FOR PRODUCING AMINE 失效

    公开(公告)号：JP2001163838A

    公开(公告)日：2001-06-19

    申请号：JP2000370628

    申请日：2000-12-05

    Applicant: BASF AG

    Inventor： NOUWEN JAN ,  HOEHN ARTHUR ,  NEUHAUSER HORST DR ,  FUNKE FRANK DR ,  SCHUNK STEPHAN ANDREAS ,  MELDER JOHANN-PETER DR ,  EGER KNUT ,  HESSE MICHAEL DR ,  WULFF-DAERING JOACHIM DR

    IPC: B01J23/755 ,  C07B61/00 ,  C07C209/26 ,  C07C211/27 ,  C07C211/35 ,  C07C211/38 ,  C07C211/42 ,  C07C213/02 ,  C07C217/58

    Abstract: PROBLEM TO BE SOLVED: To provide a method for producing an amine by a reaction in the presence of a catalyst using a nitrogen compound selected from ammonia, a primary and a secondary amines and hydrogen. SOLUTION: A catalytically active composition of a catalyst after the production and prior to the treatment with hydrogen comprises 22-45 mass % of an oxygen-containing compound of zirconium, 1-30 mass % of an oxygen-containing compound of copper and 5-50 mass % of an oxygen-containing compound of nickel in >1 molar ratio of nickel to copper and further comprises 5-50 mass % of the oxygen-containing compound of cobalt calculated as CoO, 0-5 mass % an oxygen-containing compound of molybdenum and 0-10 mass % of an oxygen-containing compound of the calculated aluminum and/or manganese. Thereby, the economical efficiency of a conventional method is improved and the amine is produced by a technically simple method which can be carried out with a high aldehyde conversion rate and a high ketone conversion rate, a high yield, a high selectivity, a high catalyst useful life and a high mechanical stability of a catalyst molded product.

    6.
    发明专利
    未知

    公开(公告)号：DE50007278D1

    公开(公告)日：2004-09-09

    申请号：DE50007278

    申请日：2000-11-10

    Applicant: BASF AG

    Inventor： NOUWEN DR ,  HOEHN DR ,  NEUHAUSER DR ,  FUNKE DR ,  SCHUNK STEPHAN ANDREAS ,  MELDER DR ,  EGER DR ,  HESSE DR ,  WULFF-DOERING DR

    IPC: B01J23/755 ,  C07B61/00 ,  C07C209/26 ,  C07C211/27 ,  C07C211/35 ,  C07C211/38 ,  C07C211/42 ,  C07C213/02 ,  C07C217/58

    Abstract: Amines are prepared by reacting aldehydes or ketones at elevated temperature under elevated pressure with nitrogen compounds selected from the group of ammonia, primary and secondary amines, and with hydrogen in the presence of a catalyst, wherein the catalytically active mass of the catalyst contains, after its preparation and before the treatment with hydrogen,22 to 45% by weight of oxygen-containing compounds of zirconium, calculated as ZrO2,1 to 30% by weight of oxygen-containing compounds of copper, calculated as CuO,5 to 50% by weight of oxygen-containing compounds of nickel, calculated as NiO, where the molar ratio of nickel to copper is greater than 1,5 to 50% by weight of oxygen-containing compounds of cobalt, calculated as CoO,0 to 5% by weight of oxygen-containing compounds of molybdenum, calculated as MoO3, and 0 to 10% by weight of oxygen-containing compounds of aluminum and/or manganese, calculated as Al2O3 or MnO2.

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