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公开(公告)号:DE2830969A1
公开(公告)日:1980-01-31
申请号:DE2830969
申请日:1978-07-14
Applicant: BASF AG
Inventor: KOENIG KARL-HEINZ DIPL CHEM DR , OESER HEINZ-GUENTER DIPL CHEM , FEUERHERD KARL-HEINZ DIPL CHEM
IPC: C07C271/00 , A01N47/10 , C07C20060101 , C07C53/50 , C07C67/00 , C07C239/00 , C07C271/04 , C07C125/03
Abstract: Novel alpha -haloalkylcarbamic acid halides, and a process for the preparation of alpha -haloalkylcarbamic acid halides by reacting alkenyl isocyanates with hydrogen halide. The alpha -haloalkylcarbamic acid halides obtained by the process of the invention are valuable starting materials for the preparation of surface-coating raw materials, textile coating agents, dyes, drugs and crop protection agents.
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公开(公告)号:DE3150233A1
公开(公告)日:1983-06-30
申请号:DE3150233
申请日:1981-12-18
Applicant: BASF AG
Inventor: BECKER RAINER DIPL CHEM DR , OESER HEINZ-GUENTER DIPL CHEM , ACKER ROLF-DIETER DIPL CHEM DR
IPC: C07C67/31 , C07C69/712
Abstract: 2-(Hydroxyphenoxy)-carboxylates are prepared by a process wherein a dihydroxybenzene (A) is reacted with a 2-halo-fatty acid ester (B) of an alcohol, phenol or oxime of no more than 10 carbon atoms, in a molar ratio of A:B>/=1.5, in the presence of calcium hydroxide in dimethylsulfoxide, at from 0 DEG to 100 DEG C.
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公开(公告)号:DE2924150A1
公开(公告)日:1980-12-18
申请号:DE2924150
申请日:1979-06-15
Applicant: BASF AG
Inventor: THEOBALD HANS DIPL CHEM DR , ADOLPHI HEINRICH DR , EICKEN KARL DIPL CHEM DR , OESER HEINZ-GUENTER DIPL CHEM
IPC: A01N57/16 , C07D213/64 , C07F9/58 , A01N57/30
Abstract: 6-Fluoropyridyl-(di)(thio)phosphoric acid esters, and their use for combating pests, especially from the classes of insects and Nemathelminthes. The 6-fluoropyridyl-(di)(thio)phosphoric acid esters have the formula where X is oxygen or sulfur, R1 is linear or branched alkyl of a maximum of 3 carbon atoms and R2 is linear or branched alkylthio of a maximum of 6 carbon atoms.
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公开(公告)号:DE3044904A1
公开(公告)日:1982-07-01
申请号:DE3044904
申请日:1980-11-28
Applicant: BASF AG
IPC: C07C229/56 , C07C67/00 , C07C227/00 , C07C227/02 , C07C253/00 , C07C255/58 , C07C121/78 , C07C101/52
Abstract: Fluorinated anthranilic acid and anthranilonitrile, and a novel process for their preparation by reacting 2,6-difluorobenzonitrile with ammonia and, if the acid is required, hydrolyzing the resulting 6-fluoroanthranilonitrile with a basic compound. The two novel end products are valuable intermediates for the preparation of compounds which are useful for controlling various animal pests and plant pests.
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公开(公告)号:DE3027959A1
公开(公告)日:1982-03-04
申请号:DE3027959
申请日:1980-07-24
Applicant: BASF AG
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公开(公告)号:DE2724366A1
公开(公告)日:1978-12-07
申请号:DE2724366
申请日:1977-05-28
Applicant: BASF AG
Inventor: OESER HEINZ-GUENTER DIPL CHEM , KOENIG KARL-HEINZ DIPL CHEM DR , MANGOLD DIETRICH DIPL CHEM DR
IPC: C07C201/12 , C07C205/12 , C07C79/12 , C07C121/52
Abstract: Fluorobenzenes of formula (I) are prepd. by reaction of chlorobenzenes of formula (II) with potassium fluoride in a suitable solvent. In the formulae, R1=nitro or cyano and R2=H, an aliphatic radical or halo. The reaction is effected using catalytic quantities of cesium fluoride or when (II) is a m-nitrochlorobenzene or m-cyanochlorobenzene it is not necessary to use cesium fluoride. Suitable solvents are N, N-disubstd. carboxylic acid amides, nitrobenzene, nitriles, aliphatic sulphones and/or aliphatic sulphoxides. (I) are intermediates for dyes, pharmaceuticals and parasiticides. (I) may be reduced to the corresp. aniline deriv. which are used in paints, as germicides and is welding fluxes. Compared with known processes the present process gives higher yields and purer products. The reaction is effected at low temperatures is rapid, economic and suitable for industrial scale prodn.
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公开(公告)号:DE3151589A1
公开(公告)日:1983-07-07
申请号:DE3151589
申请日:1981-12-28
Applicant: BASF AG
Inventor: BECKER RAINER DIPL CHEM DR , HOFFMANN WERNER DIPL CHEM DR , OESER HEINZ-GUENTER DIPL CHEM , ROHR WOLFGANG DIPL CHEM DR , VARWIG JUERGEN DIPL CHEM DR
IPC: C07C69/66 , B01J23/00 , B01J27/00 , C07B61/00 , C07C41/00 , C07C41/01 , C07C41/16 , C07C41/26 , C07C43/205 , C07C43/225 , C07C43/23 , C07C43/29 , C07C43/295 , C07C51/00 , C07C59/125 , C07C59/64 , C07C67/00 , C07C201/00 , C07C205/38 , C07C253/00 , C07C255/54 , C07D213/64 , C07D241/44 , C07D277/68 , C07C43/20 , C07D241/42
Abstract: 1. A process for the preparation of a diether of m- or p-hydroxyphenol, of the formula see diagramm : EP0083010,P13,F4 or a monoether of m- or p-hydroxyphenol, of the formula see diagramm : EP0083010,P13,F5 where the two hydroxyl groups are in the m- or p-position relative to one another and R**1 is an aliphatic radical or see diagramm : EP0083010,P13,F6 see diagramm : EP0083010,P13,F7 see diagramm : EP0083010,P14,F1 see diagramm : EP0083010,P14,F2 see diagramm : EP0083010,P14,F3 the individual radicals R**2 and R**3 can be identical or different and each is hydrogen or an aliphatic, araliphatic or aromatic radical, and R**3 can also in each case be halogen, nitro, cyano or alkoxy, by reacting a monoether of a dihydroxy compound with a halogen compound to form a diether and splitting off the original monoether group, wherein a) m- or p-tert.-butoxyphenol of the formula see diagramm : EP0083010,P14,F4 is reacted with a halogen compound of the formula R**1 -X where R**1 has the above meanings and X is halogen, in the presence of a hydroxide, carbonate and/or bicarbonate of an alkali metal or alkaline earth metal and an organic solvent which is inert under the reaction conditions, at from 20 to 150 degrees C, to give the end product la, and, if desired, b) the resulting end product la is reacted with a mixture of water, a water-miscible alkanol and an inorganic acid at from 30 to 100 degrees C to give the end product Ib.
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公开(公告)号:DE2940443A1
公开(公告)日:1981-04-16
申请号:DE2940443
申请日:1979-10-05
Applicant: BASF AG
Inventor: HICKMANN ECKHARD DIPL CHEM DR , OESER HEINZ-GUENTER DIPL CHEM , MOEBIUS LEANDER DIPL CHEM DR
IPC: C07D401/06 , A61K31/47 , C07D209/38 , C07D211/22 , C07D215/14 , C07D215/50
Abstract: The present invention relates to a simplified process, which avoids organo-lithium intermediates, for the preparation of erythro- alpha -piperid-2-yl-2,8-bis-(trifluoromethyl)-quinolin-4-yl-methanol, wherein 2,8-bis-(trifluoromethyl)-quinoline-4-carboxylic acid or a salt thereof is reacted with a pyrid-2-yl-magnesium halide to give pyrid-2-yl-2,8-bis-(trifluoromethyl)-quinolin-4-yl ketone in the manner of a Grignard reaction, and this product is hydrogenated, in a conventional manner, to give erythro- alpha -piperid-2-yl-2,8-bis-(trifluoromethyl)-quinolin-4-yl-methanol.
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公开(公告)号:DE2937028A1
公开(公告)日:1981-04-09
申请号:DE2937028
申请日:1979-09-13
Applicant: BASF AG
Inventor: KOENIG KARL-HEINZ DIPL CHEM DR , FEUERHERD KARL-HEINZ DIPL CHEM , OESER HEINZ-GUENTER DIPL CHEM
IPC: C07C265/06 , A01N47/40 , C07C20060101 , C07C67/00 , C07C241/00 , C07C263/04 , C07C265/04 , C07C119/042 , C07C118/00
Abstract: 1-Monohalogenated isocyanates, and a process for the preparation of mixtures of 1-monohalogenated isocyanates and 1,2-unsaturated isocyanates by reacting 1-monohalogenated carbamic acid halides or isocyanates with a halogen-free isocyanate or diisocyanate or by reacting 1,2-unsaturated isocyanates with a carbamic acid halide or a bis-carbamic acid halide. The 1,2-unsaturated isocyanates and 1-monohalogenated isocyanates prepared according to the invention are valuable starting materials for the preparation of pest control agents, dyes, drugs, water-repellent textile finishes, detergents, plastics, bleaches and adhesives.
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公开(公告)号:DE2846184A1
公开(公告)日:1980-05-08
申请号:DE2846184
申请日:1978-10-24
Applicant: BASF AG
Inventor: KOENIG KARL-HEINZ DIPL CHEM DR , OESER HEINZ-GUENTER DIPL CHEM , FEUERHERD KARL-HEINZ DIPL CHEM
IPC: C07C265/02 , A01M20060101 , A61K20060101 , C07C20060101 , C07C67/00 , C07C241/00 , C07C263/16 , C07C265/04 , C09B20060101 , C07C119/042
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