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公开(公告)号:JP2003261608A
公开(公告)日:2003-09-19
申请号:JP2003039114
申请日:2003-02-18
Applicant: BASF AG
Inventor: KRISTEN MARC OLIVER DR , EIBECK PETER , GREGORIUS HEIKE , LILGE DIETER DR
IPC: C08F4/642 , B01J19/00 , C08F2/00 , C08F2/01 , C08F4/00 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/06 , C08F110/06 , C40B40/14
Abstract: PROBLEM TO BE SOLVED: To provide a method which can quickly and inexpensively evaluate the quality of a number of catalyst samples for catalyzing polymerization. SOLUTION: The method of determining the quality of polymerization catalysts comprises (a) a step of providing catalysts, (b) a step of carrying out the polymerization of a monomer using these catalysts, (c) a step of isolating polymers obtained in step (b), and (d) a step of characterizing the above polymers, and the above method is carried out in an assembly of n vessels in an essentially automated fashion, and the steps (a) to (d) are all carried out in parallel or are all carried out sequentially or some of the steps of (a) to (d) are carried out in parallel and the remainder are carried out sequentially, and n is a natural number of ≥2. COPYRIGHT: (C)2003,JPO
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公开(公告)号:JPH11310617A
公开(公告)日:1999-11-09
申请号:JP7537199
申请日:1999-03-19
Applicant: BASF AG
Inventor: KRISTEN MARC OLIVER DR , LILGE DIETER DR
IPC: C08J5/18 , C08F4/619 , C08F4/6192 , C08F4/646 , C08F210/02 , C08F210/16 , D01F6/30
Abstract: PROBLEM TO BE SOLVED: To obtain an ethylene copolymer composed of an ethylene unit and at least one kind of a 3-12C α-olefin unit, having >3 molecular weight distribution Mw /Mn and narrow comonomer distribution. SOLUTION: This ethylene copolymer is composed of an ethylene unit and at least one kind of a 3-12C α-olefin unit, has >3 molecular weight distribution Mw /Mn , and a comonomer distribution having a standard deviation σ of an averaged weighted elution temperature Ta determined by a TREF(Temperature Rising Elution Fraction) method and regulated so as to satisfy the formula σ>k4 -k1 (Ta -k0 )-k2 k3 (Ta -k0 )/(1+k3 (Ta -k0 )) [ deg.C] [k0 is 338.5 deg.C; k1 is 0.0053; k2 is 1.1318 deg.C; k3 is 0.00483 deg.C ; k4 is 0.55 deg.C; Ta is
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公开(公告)号:JPH1180245A
公开(公告)日:1999-03-26
申请号:JP17743498
申请日:1998-06-24
Applicant: BASF AG
Inventor: HUEFFER STEPHAN DR , ROESCH JOACHIM DR , LANGHAUSER FRANZ DR , LILGE DIETER DR , HINGMANN ROLAND DR
IPC: C08J5/18 , C08F4/02 , C08F4/646 , C08F6/04 , C08F10/00 , C08F10/06 , C08F210/16 , C08L23/10 , C08L23/12 , C08L23/14 , D01F6/06 , D01F6/30
Abstract: PROBLEM TO BE SOLVED: To provide a propylene polymer which has a high rigidity/strength ratio and low chlorine content, and can be produced by a process with high productivity. SOLUTION: A propylene polymer containing a matrix comprising a propylene homopolymer and a copolymer of propylene with other alkene is first dissolved in boiling xylene, the solution is cooled at a cooling rate of 10 deg.C per hr to 25 deg.C, the temperature is then raised to separate the propylene polymer into fractions of various solubilities according to the stereoregularities of polymer chains and the comonomer distributions, wherein the matrix remaining undissolved when the cooled propylene polymer solution is heated to 80 deg.C satisfies one or more of the following conditions: i) the matrix remains undissolved in an amount above 20 wt.% when further heated to 112 deg.C; ii) it remains undissolved in an amount above 8 wt.% when further heated to 117 deg.C; and iii) it remains undissolved in an amount above 1 wt.% when further heated to 122 deg.C.
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公开(公告)号:JPH10338718A
公开(公告)日:1998-12-22
申请号:JP6519798
申请日:1998-03-16
Applicant: BASF AG
Inventor: HUEFFER STEPHAN DR , ROESCH JOACHIM DR , SEELERT STEFAN DR , LANGHAUSER FRANZ DR , LILGE DIETER DR , HINGMANN ROLAND DR , SCHWEIER GUENTHER DR
Abstract: PROBLEM TO BE SOLVED: To obtain a propylene homopolymer having a very low content of xylene-soluble component, low content of chlorine and high content of long and complete isotactic polymer component. SOLUTION: This propylene homopolymer is to satisfy at least one of the following conditions when the propylene homopolymer subjected to stereoregularity is separated by dissolving the propylene homopolymer into a boiling xylene, cooling the resultant solution to 25 deg.C at a cooling rate of 10 deg.C/h, followed by separating the polymer into different fractions in stereoregularity while raising the temperature, i) an insoluble fraction of the propylene homopolymer is >20 wt.% when the cooled propylene homopolymer is heated to 112 deg.C, ii) an insoluble fraction of the propylene homopolymer is >8 wt.% when the cooled propylene homopolymer is heated to 117 deg.C, and iii) an insoluble fraction of the propylene homopolymer is >1 wt.% when the cooled propylene homopolymer is heated to 122 deg.C.
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公开(公告)号:DE19745047A1
公开(公告)日:1999-04-15
申请号:DE19745047
申请日:1997-10-11
Applicant: BASF AG
Inventor: BAUER PETER , LUX MARTIN DR , LILGE DIETER DR , FALLER UWE
Abstract: A polymer mixture with good processing properties, e.g. for blown or cast film, contains an ethylene copolymer and another ethylene copolymer with a higher density and a broader molecular weight distribution. A polymer mixture is claimed containing at least 40-85 wt% ethylene copolymer (A) with a density of 0.91-0.93 g/cm , a high-load melt flow rate (HLMFR; 190/21.6) of 5-60 g/10 mins. and a mol. wt. distribution (Mw/Mn) of not more than 3, and more than 15 but not more than 60 wt% ethylene copolymer (B) with a density of 0.93-0.945 g/cm , an HLMFR of 8-20 g/10 mins. and an Mw/Mn ratio of at least 7. Independent claims are also included for (a) a process for the production of film from this polymer mixture; (b) film produced from the polymer mixture.
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公开(公告)号:ES2096703T3
公开(公告)日:1997-03-16
申请号:ES92119651
申请日:1992-11-19
Applicant: BASF AG
Inventor: RIEGER BERNHARD DR , LILGE DIETER DR , EVERTZ KASPAR DR , KONRAD RAINER DR
IPC: C08F4/622 , C08F4/642 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F210/02 , C08F210/16
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公开(公告)号:DE19526340A1
公开(公告)日:1997-01-23
申请号:DE19526340
申请日:1995-07-19
Applicant: BASF AG
Inventor: NEUMANN PETRA DR , WEBER SIEGFRIED DR , LILGE DIETER DR , GOERTZ HANS-HELMUT DR
Abstract: Moulding compounds based on ethylene polymers of (A) 40 to 65 wt.% of an ethylene polymer with a density in the range 0.948 to 0.964 g/cm , a melt flow index (MFI) of 6 to 20 g/10 min. and a mean molar mass distribution M w/ M n in the range from 2 to 5; (B) 35 to 60 wt.% of an ethylene polymer with a density in the range from 0.935 to 0.953 g/cm , a melt flow index (MFI) of 0.1 to 0.35 g/10 min. and a mean molar mass distribution M w/ M n in the range from 6 to 20; (C) 0 to 6 wt.% of the usual thermoplast additives; in which the density of the casting compounds lies in the range from 9.948 to 0.957 g/ cm , the melt flow index in the range from 1.0 to 2.0 g/10 min., the mean mass distribution M w/ M n in the range from 3 to 10 and the difference between the densities of components (A) and (B) ( DELTA D = D(A)-D(B) is in the range from 0 to 0.029 g/cm .
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公开(公告)号:DE3719806A1
公开(公告)日:1988-12-22
申请号:DE3719806
申请日:1987-06-13
Applicant: BASF AG
Inventor: AUWETER HELMUT DR , HORN DIETER DR , LILGE DIETER DR , WORTMANN JUERGEN DR
Abstract: Optical fibre sensor for measuring the Doppler broadening of scattered laser light according to the principle of quasi-elastic light scattering (QELS), the scattered light coming from particles in motion, characterised in that the output face (7) for the laser light is bevelled at the end of a monomode or multimode optical fibre (3), which is used as an immersion probe, at an angle of inclination of 0
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公开(公告)号:DE59207990D1
公开(公告)日:1997-03-13
申请号:DE59207990
申请日:1992-11-19
Applicant: BASF AG
Inventor: RIEGER BERNHARD DR , LILGE DIETER DR , EVERTZ KASPAR DR , KONRAD RAINER DR
IPC: C08F4/622 , C08F4/642 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F210/02 , C08F210/16
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公开(公告)号:DE19710761A1
公开(公告)日:1998-09-17
申请号:DE19710761
申请日:1997-03-14
Applicant: BASF AG
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