METHOD OF DETERMINING QUALITY OF POLYMERIZATION CATALYST

    公开(公告)号:JP2003261608A

    公开(公告)日:2003-09-19

    申请号:JP2003039114

    申请日:2003-02-18

    Applicant: BASF AG

    Abstract: PROBLEM TO BE SOLVED: To provide a method which can quickly and inexpensively evaluate the quality of a number of catalyst samples for catalyzing polymerization. SOLUTION: The method of determining the quality of polymerization catalysts comprises (a) a step of providing catalysts, (b) a step of carrying out the polymerization of a monomer using these catalysts, (c) a step of isolating polymers obtained in step (b), and (d) a step of characterizing the above polymers, and the above method is carried out in an assembly of n vessels in an essentially automated fashion, and the steps (a) to (d) are all carried out in parallel or are all carried out sequentially or some of the steps of (a) to (d) are carried out in parallel and the remainder are carried out sequentially, and n is a natural number of ≥2. COPYRIGHT: (C)2003,JPO

    ETHYLENE POLYMER, ITS PRODUCTION AND ITS USE

    公开(公告)号:JPH11310617A

    公开(公告)日:1999-11-09

    申请号:JP7537199

    申请日:1999-03-19

    Applicant: BASF AG

    Abstract: PROBLEM TO BE SOLVED: To obtain an ethylene copolymer composed of an ethylene unit and at least one kind of a 3-12C α-olefin unit, having >3 molecular weight distribution Mw /Mn and narrow comonomer distribution. SOLUTION: This ethylene copolymer is composed of an ethylene unit and at least one kind of a 3-12C α-olefin unit, has >3 molecular weight distribution Mw /Mn , and a comonomer distribution having a standard deviation σ of an averaged weighted elution temperature Ta determined by a TREF(Temperature Rising Elution Fraction) method and regulated so as to satisfy the formula σ>k4 -k1 (Ta -k0 )-k2 k3 (Ta -k0 )/(1+k3 (Ta -k0 )) [ deg.C] [k0 is 338.5 deg.C; k1 is 0.0053; k2 is 1.1318 deg.C; k3 is 0.00483 deg.C ; k4 is 0.55 deg.C; Ta is

    PROPYLENE POLYMER
    3.
    发明专利

    公开(公告)号:JPH1180245A

    公开(公告)日:1999-03-26

    申请号:JP17743498

    申请日:1998-06-24

    Applicant: BASF AG

    Abstract: PROBLEM TO BE SOLVED: To provide a propylene polymer which has a high rigidity/strength ratio and low chlorine content, and can be produced by a process with high productivity. SOLUTION: A propylene polymer containing a matrix comprising a propylene homopolymer and a copolymer of propylene with other alkene is first dissolved in boiling xylene, the solution is cooled at a cooling rate of 10 deg.C per hr to 25 deg.C, the temperature is then raised to separate the propylene polymer into fractions of various solubilities according to the stereoregularities of polymer chains and the comonomer distributions, wherein the matrix remaining undissolved when the cooled propylene polymer solution is heated to 80 deg.C satisfies one or more of the following conditions: i) the matrix remains undissolved in an amount above 20 wt.% when further heated to 112 deg.C; ii) it remains undissolved in an amount above 8 wt.% when further heated to 117 deg.C; and iii) it remains undissolved in an amount above 1 wt.% when further heated to 122 deg.C.

    Polymer mixture, especially for production of film

    公开(公告)号:DE19745047A1

    公开(公告)日:1999-04-15

    申请号:DE19745047

    申请日:1997-10-11

    Applicant: BASF AG

    Abstract: A polymer mixture with good processing properties, e.g. for blown or cast film, contains an ethylene copolymer and another ethylene copolymer with a higher density and a broader molecular weight distribution. A polymer mixture is claimed containing at least 40-85 wt% ethylene copolymer (A) with a density of 0.91-0.93 g/cm , a high-load melt flow rate (HLMFR; 190/21.6) of 5-60 g/10 mins. and a mol. wt. distribution (Mw/Mn) of not more than 3, and more than 15 but not more than 60 wt% ethylene copolymer (B) with a density of 0.93-0.945 g/cm , an HLMFR of 8-20 g/10 mins. and an Mw/Mn ratio of at least 7. Independent claims are also included for (a) a process for the production of film from this polymer mixture; (b) film produced from the polymer mixture.

    7.
    发明专利
    未知

    公开(公告)号:DE19526340A1

    公开(公告)日:1997-01-23

    申请号:DE19526340

    申请日:1995-07-19

    Applicant: BASF AG

    Abstract: Moulding compounds based on ethylene polymers of (A) 40 to 65 wt.% of an ethylene polymer with a density in the range 0.948 to 0.964 g/cm , a melt flow index (MFI) of 6 to 20 g/10 min. and a mean molar mass distribution M w/ M n in the range from 2 to 5; (B) 35 to 60 wt.% of an ethylene polymer with a density in the range from 0.935 to 0.953 g/cm , a melt flow index (MFI) of 0.1 to 0.35 g/10 min. and a mean molar mass distribution M w/ M n in the range from 6 to 20; (C) 0 to 6 wt.% of the usual thermoplast additives; in which the density of the casting compounds lies in the range from 9.948 to 0.957 g/ cm , the melt flow index in the range from 1.0 to 2.0 g/10 min., the mean mass distribution M w/ M n in the range from 3 to 10 and the difference between the densities of components (A) and (B) ( DELTA D = D(A)-D(B) is in the range from 0 to 0.029 g/cm .

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