公开(公告)号：WO9957108A2

公开(公告)日：1999-11-11

申请号：PCT/EP9902701

申请日：1999-04-22

Applicant: BASF AG ,  BIRNBACH STEFAN ,  DOCKNER TONI ,  MOHR JUERGEN ,  BENFER REGINA ,  BIEG WALTER ,  PETERS JARREN ,  RUGE BERND ,  WEINLE WERNER ,  ZEHNER PETER

Inventor： BIRNBACH STEFAN ,  DOCKNER TONI ,  MOHR JUERGEN ,  BENFER REGINA ,  BIEG WALTER ,  PETERS JARREN ,  RUGE BERND ,  WEINLE WERNER ,  ZEHNER PETER

IPC: C07D317/36 ,  C07D317/38

CPC classification number: C07D317/36 ,  C07D317/38

Abstract: The invention relates to a method for continually producing 1,3-dioxolan-2-ones such as ethylene carbonate or propylene carbonate by reacting a corresponding oxirane with carbon dioxide in liquid phase in the presence of a catalyst. The reaction is carried out in a two-part reactor. In the first part of the reactor, the reaction is carried out with back-mixing until a conversion rate of oxirane II of at least 80 % has been reached. In the second part, the reaction is completed under conditions without back-mixing, the carbon dioxide being guided to the oxirane II in a counterflow throughout the reactor.

Abstract translation: 连续生产的1,3-二氧戊环-2-酮如碳酸亚乙酯或碳酸亚丙酯通过通过进行两部分的反应器中的反应与在催化剂的存在下液相二氧化碳适当的环氧乙烷进行反应，其中下返混的反应的第一部分中 高达至少80％引导的环氧乙烷II的转化，并且该反应是在第二部分的非反混的条件下，其中在整个反应器中的二氧化碳以逆流被传递给环氧乙烷II下完成。

公开(公告)号：DE59906105D1

公开(公告)日：2003-07-31

申请号：DE59906105

申请日：1999-04-22

Applicant: BASF AG

Inventor： BIRNBACH STEFAN ,  DOCKNER TONI ,  MOHR JUERGEN ,  BENFER REGINA ,  BIEG WALTER ,  PETERS JARREN ,  RUGE BERND ,  WEINLE WERNER ,  ZEHNER PETER

IPC: C07D317/36 ,  C07D317/38

Abstract: A process for the continuous production of 1,3-dioxolan-2-ones such as ethylene carbonate or propylene carbonate by reacting a corresponding oxirane with carbon dioxide in the liquid phase in the presence of a catalyst comprises conducting the reaction in a two-part reactor in whose first part the reaction is taken with backmixing to a conversion of not less than 80% of the oxirane II and in whose second part the reaction is completed under nonbackmixing conditions, and passing the carbon dioxide in countercurrent to the oxirane II in the entire reactor.

公开(公告)号：ID26310A

公开(公告)日：2000-12-14

申请号：ID20002218

申请日：1999-04-22

Applicant: BASF AG

Inventor： BIRNBACH STEFAN ,  DOCKNER TONI ,  MOHR JURGEN ,  BENFER REGINA ,  BIEG WALTER ,  PETERS JARREN ,  RUGE BERND ,  WEINLE WERNER ,  ZEHNER PETER

IPC: C07D317/36 ,  C07D317/38

Abstract: A process for the continuous production of 1,3-dioxolan-2-ones such as ethylene carbonate or propylene carbonate by reacting a corresponding oxirane with carbon dioxide in the liquid phase in the presence of a catalyst comprises conducting the reaction in a two-part reactor in whose first part the reaction is taken with backmixing to a conversion of not less than 80% of the oxirane II and in whose second part the reaction is completed under nonbackmixing conditions, and passing the carbon dioxide in countercurrent to the oxirane II in the entire reactor.

公开(公告)号：CA2326888C

公开(公告)日：2008-01-29

申请号：CA2326888

申请日：1999-04-22

Applicant: BASF AG

Inventor： BIEG WALTER ,  BENFER REGINA ,  PETERS JARREN ,  RUGE BERND ,  MOHR JURGEN ,  BIRNBACH STEFAN ,  WEINLE WERNER ,  ZEHNER PETER ,  DOCKNER TONI

IPC: C07D317/36 ,  C07D317/38

Abstract: The invention relates to a method for continually producing 1,3-dioxolan-2- ones such as ethylene carbonate or propylene carbonate by reacting a corresponding oxirane with carbon dioxide in liquid phase in t he presence of a catalyst. The reaction is carried out in a two-part reactor. In the first part of the reactor, the reaction is carried out with back-mixing until a conversion rate of oxirane II of at least 80 % has been reached. In the second part, the reaction is completed under conditions without back-mixing, the carbon dioxide being guided to the oxirane II in a counterflow throughout the reactor.

公开(公告)号：CA2326888A1

公开(公告)日：1999-11-11

申请号：CA2326888

申请日：1999-04-22

Applicant: BASF AG

Inventor： PETERS JARREN ,  DOCKNER TONI ,  BENFER REGINA ,  BIRNBACH STEFAN ,  MOHR JURGEN ,  ZEHNER PETER ,  BIEG WALTER ,  WEINLE WERNER ,  RUGE BERND

IPC: C07D317/36 ,  C07D317/38

Abstract: The invention relates to a method for continually producing 1,3-dioxolan-2- ones such as ethylene carbonate or propylene carbonate by reacting a corresponding oxirane with carbon dioxide in liquid phase in the presence of a catalyst. The reaction is carried out in a two-part reactor. In the first pa rt of the reactor, the reaction is carried out with back-mixing until a conversion rate of oxirane II of at least 80 % has been reached. In the seco nd part, the reaction is completed under conditions without back-mixing, the carbon dioxide being guided to the oxirane II in a counterflow throughout th e reactor.

公开(公告)号：DE19819586A1

公开(公告)日：1999-11-04

申请号：DE19819586

申请日：1998-04-30

Applicant: BASF AG

Inventor： BIRNBACH STEFAN ,  DOCKNER TONI ,  MOHR JUERGEN ,  BENFER REGINA ,  BIEG WALTER ,  PETERS JARREN ,  RUGE BERND ,  WEINLE WERNER ,  ZEHNER PETER

IPC: C07D317/36 ,  C07D317/38 ,  C07D317/44

Abstract: The invention relates to a method for continually producing 1,3-dioxolan-2-ones such as ethylene carbonate or propylene carbonate by reacting a corresponding oxirane with carbon dioxide in liquid phase in the presence of a catalyst. The reaction is carried out in a two-part reactor. In the first part of the reactor, the reaction is carried out with back-mixing until a conversion rate of oxirane II of at least 80 % has been reached. In the second part, the reaction is completed under conditions without back-mixing, the carbon dioxide being guided to the oxirane II in a counterflow throughout the reactor.