公开(公告)号：KR820001686B1

公开(公告)日：1982-09-17

申请号：KR760002570

申请日：1976-10-15

Applicant: BASF AG

Inventor： FLEIG HELMUT ,  DOCKNER TONI ,  KOHLMANN FRIEDRICH WILHELM ,  HAGEN HELMUT

IPC: A61K31/41 ,  C07D417/06

Abstract: Nitroimdazolyivinylthiadiazoles (I, R1 = C1-4 alkyl; R2 = H, CH3; R3 = H, C1-24 alkyl, substitutable ph, heteroallyl) useful agents for treating bacteria, fungi and protozoa, were prepd. by the reaction of 2-substituted-1,3,4-thiadiazole(II) and 5-nitroimidazole-2-carboxaldehyde(III) or its acetal at elevated temp. Thus, 2,5-dimethy 1-1,3,4-thiadiazole and 1-methyl-5-nitroimidazole-2-carboxy aldehyde were refluxed in glacial acetic acid and acetic anhydride in the presence of ZnCl2 for 10 hr and recrystallized with DMF to give -methyl-5-[2-(1-methyl-5-nitroimidazol-2-yl)-vinyl -1,3,4-thiadiazloe(m.p. 248≦̸C).

公开(公告)号：US3564018A

公开(公告)日：1971-02-16

申请号：US3564018D

申请日：1969-01-14

Applicant: BASF AG

Inventor： DOCKNER TONI ,  PLATZ ROLF

IPC: C07C51/235 ,  C07D7/06 ,  C07C51/24 ,  C07D9/00

CPC classification number: C07C51/235 ,  C07C53/124

Abstract: AN IMPROVED PROCESS FOR THE PRODUCTION OF LACTONES HAVING SIX TO THIRTEEN RING MEMBERS AND ISOBUTYRIC ACID BY REACTION OF A CYCLIC KETONE HAVING FROM FIVE TO TWELVE RING MEMBERS AND ISOBUTYRIC ACID BY REACTION OF A CYCLIC KETONE HAVING FROM FIVE TO TWELVE RING MEMBERS AND ISOBUTYRALDEHYDE WITH MOLECULAR OXYGEN OR A GAS CONTAINING THE SAME, THE IMPROVEMENT CONSISTING IN CARRYING OUT THE REACTION WITHOUT USING A CATALYST. LACTONES ARE USED IN THE PRODUCTION OF POLYESTOR.

公开(公告)号：JPH101454A

公开(公告)日：1998-01-06

申请号：JP2294797

申请日：1997-02-05

Applicant: BASF AG

Inventor： IFFLAND GABRIELE ,  DAMS ALBRECHT ,  WECK ALEXANDER ,  AICHINGER HEINRICH ,  HERBST HOLGER ,  NESTLER GERHARD ,  EXNER HERBERT ,  SCHMIDT WILLI ,  GEISENDOERFER MATTHIAS ,  DOCKNER TONI

IPC: B01J27/02 ,  B01J31/02 ,  C07B61/00 ,  C07C67/08 ,  C07C67/54 ,  C07C69/54

Abstract: PROBLEM TO BE SOLVED: To avoid production of ether which is a by-product from an alkanol in a method for continuously producing an alkyl ester of a (meth)acrylic acid by reacting (meth)acrylic acid with a 1-8C monohydric alkanol in a reaction zone in the presence of an acid esterification catalyst, discharging a product mixture containing the resultant alkyl (meth)acrylate, the catalyst and a by- product having higher boiling point than the alkyl (meth)acrylate and subjecting the alkyl (meth)acrylate to separation by distillation in a separation zone from the mixture. SOLUTION: A product mixture from a reaction zone is fed to a rectifier I and the product mixture discharged in the apparatus is separated into one or more products I containing an alkyl ester of (meth)acrylic acid and product II containing a catalyst by rectification and the product I is fed to other rectifier II and an alkyl ester of (meth)acrylic acid is separated by rectification in the apparatus.

公开(公告)号：JPH10182555A

公开(公告)日：1998-07-07

申请号：JP34006197

申请日：1997-12-10

Applicant: BASF AG

Inventor： DOCKNER TONI ,  NESTLER GERHARD

IPC: B01J31/02 ,  C07B61/00 ,  C07C67/03 ,  C07C67/29 ,  C07C67/297 ,  C07C69/533

Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound of high purity in high yield with suppression of the formation of by-products by treating a vinyloxy-ester of a carboxylic acid in the presence of an alcohol. SOLUTION: An α,β-unsaturated carboxylic ester of formula I (R is H, a 1-4C alkyl; R is H, methyl) is subjected to the transesterification, with a vinyloxy group-bearing alcohol of the formula: CH2 =CH-O-A-OH (A is a 2-12C alkylene) in the presence of a base catalyst to prepare a vinyloxy carboxylic ester of formula II. In addition, the compound of formula II is allowed to react with an alcohol, preferably 1,2-diol or 1,3-diol to prepare an α,β-unsaturated carboxylic ω-hydroxyester thereby giving a compound of formula III not accompanied by formation of by-products such as cyclic ethers or diesters through an environmentally acceptable and usually applicable process.

公开(公告)号：JPH09227445A

公开(公告)日：1997-09-02

申请号：JP183997

申请日：1997-01-09

Applicant: BASF AG

Inventor： MACHHAMMER OTTO ,  DOCKNER TONI ,  ENGERT GERD-JUERGEN ,  PROLL THEO

IPC: B01D9/02 ,  B01D3/00 ,  C07B61/00 ,  C07C51/235 ,  C07C51/25 ,  C07C51/43 ,  C07C51/48 ,  C07C57/04 ,  C07C57/05 ,  C07C57/055 ,  C07C57/07 ,  C07C69/54

公开(公告)号：US3928439A

公开(公告)日：1975-12-23

申请号：US45945874

申请日：1974-04-10

Applicant: BASF AG

Inventor： DOCKNER TONI ,  PLATZ ROLF

IPC: C07C231/06 ,  B01J21/00 ,  B01J23/12 ,  B01J23/84 ,  C07C67/00 ,  C07C231/00 ,  C07C233/09 ,  C07C233/65 ,  C07C103/00

CPC classification number: B01J23/12 ,  B01J23/84

Abstract: Manufacture of carboxamides by the addition of water to nitriles in the presence of a copper-containing and magnesium silicatecontaining catalyst which has been treated with a reducing gas. The carboxamides obtained by the process of the invention are valuable starting materials for the manufacture of solvents, flocculating agents, crosslinking agents, pesticides, plant protectants, textile auxiliaries such as levelling agents, waterproofing agents, foam stabilizers and detergents.

Abstract translation: 在含还原气体处理过的含铜硅酸镁催化剂存在下，通过向腈中加入水来制造甲酰胺。 通过本发明方法获得的羧酰胺是用于制造溶剂，絮凝剂，交联剂，农药，植物保护剂，纺织助剂如流平剂，防水剂，泡沫稳定剂和洗涤剂的有价值的原料。

公开(公告)号：US3642889A

公开(公告)日：1972-02-15

申请号：US3642889D

申请日：1966-11-01

Applicant: BASF AG

Inventor： PLATZ ROLF ,  NOHE HEINZ ,  DOCKNER TONI

IPC: C07C51/097 ,  C07C59/08

CPC classification number: C07C51/097 ,  C07C59/08

Abstract: PROCESS FOR PRODUCING LACTIC ACID BY THE HYDROLYSIS OF LACTIC ACID NITRATE IN WHICH THE LACTICE ACID NITRATE IS REACTED WITH MORE THAN TWICE ITS WEIGHT OF WATER. IT HAS BEEN FOUND THAT HIGH YEILDS OF LACTICE ACID CAN BE OBTAINED EITHER FROM PURE LATICE ACID NITRATE OR FROM THE REACTION PRODUCT CONTAINING IMPURITIES AS WELL AS LACTIC ACID NITRATE.

公开(公告)号：WO9957108A2

公开(公告)日：1999-11-11

申请号：PCT/EP9902701

申请日：1999-04-22

Applicant: BASF AG ,  BIRNBACH STEFAN ,  DOCKNER TONI ,  MOHR JUERGEN ,  BENFER REGINA ,  BIEG WALTER ,  PETERS JARREN ,  RUGE BERND ,  WEINLE WERNER ,  ZEHNER PETER

Inventor： BIRNBACH STEFAN ,  DOCKNER TONI ,  MOHR JUERGEN ,  BENFER REGINA ,  BIEG WALTER ,  PETERS JARREN ,  RUGE BERND ,  WEINLE WERNER ,  ZEHNER PETER

IPC: C07D317/36 ,  C07D317/38

CPC classification number: C07D317/36 ,  C07D317/38

Abstract: The invention relates to a method for continually producing 1,3-dioxolan-2-ones such as ethylene carbonate or propylene carbonate by reacting a corresponding oxirane with carbon dioxide in liquid phase in the presence of a catalyst. The reaction is carried out in a two-part reactor. In the first part of the reactor, the reaction is carried out with back-mixing until a conversion rate of oxirane II of at least 80 % has been reached. In the second part, the reaction is completed under conditions without back-mixing, the carbon dioxide being guided to the oxirane II in a counterflow throughout the reactor.

Abstract translation: 连续生产的1,3-二氧戊环-2-酮如碳酸亚乙酯或碳酸亚丙酯通过通过进行两部分的反应器中的反应与在催化剂的存在下液相二氧化碳适当的环氧乙烷进行反应，其中下返混的反应的第一部分中 高达至少80％引导的环氧乙烷II的转化，并且该反应是在第二部分的非反混的条件下，其中在整个反应器中的二氧化碳以逆流被传递给环氧乙烷II下完成。

公开(公告)号：CA2326888C

公开(公告)日：2008-01-29

申请号：CA2326888

申请日：1999-04-22

Applicant: BASF AG

Inventor： BIEG WALTER ,  BENFER REGINA ,  PETERS JARREN ,  RUGE BERND ,  MOHR JURGEN ,  BIRNBACH STEFAN ,  WEINLE WERNER ,  ZEHNER PETER ,  DOCKNER TONI

IPC: C07D317/36 ,  C07D317/38

Abstract: The invention relates to a method for continually producing 1,3-dioxolan-2- ones such as ethylene carbonate or propylene carbonate by reacting a corresponding oxirane with carbon dioxide in liquid phase in t he presence of a catalyst. The reaction is carried out in a two-part reactor. In the first part of the reactor, the reaction is carried out with back-mixing until a conversion rate of oxirane II of at least 80 % has been reached. In the second part, the reaction is completed under conditions without back-mixing, the carbon dioxide being guided to the oxirane II in a counterflow throughout the reactor.

公开(公告)号：ES2280374T3

公开(公告)日：2007-09-16

申请号：ES01936367

申请日：2001-05-16

Applicant: BASF AG

Inventor： BADER JOACHIM ,  BECHTOLSHEIMER HANS-HEINRICH ,  BRUCKER ARMIN ,  DOCKNER TONI ,  IFFLAND GABRIELE ,  KLINK HANS

IPC: C08G65/30 ,  B01J39/04 ,  B01J49/00 ,  B01J49/06 ,  B01J49/53

Abstract: Procedimiento para separar iones metálico alcalinos de alcoxilados que contienen iones metálico alcalinos, que comprende: a) dilución del alcoxilado que contiene metal alcalino con un solvente inerte, b) tratamiento de la solución de alcoxilado que contiene metal alcalino con cambiador de cationes, para obtener una solución que contenga menos de 5 ppm de iones metálico alcalino, c) eliminación del solvente de la solución esencialmente libre de metal alcalino, para obtener un alcoxilado que contenga menos de 5 ppm de iones metálico alcalinos y menos de 1 000 ppm de solvente, siendo el procedimiento uno que comprende una regeneración del cambiador de cationes que consta de las siguientes etapas: d1) eliminación de la solución de alcoxilado a partir del cambiador de cationes y elución del cambiador de cationes con un solvente inerte, d2) elución, si es necesario, del cambiador de cationes con agua desmineralizada, d3) regeneración de la resina cambiadora de cationes con un ácido, d4) relavadode la resina cambiadora de cationes con agua desmineralizada, d5) elución del agua que se encuentra en la resina cambiadora de iones con un solvente inerte, y d6) si es necesario, cargar el cambiador de cationes con el solvente inerte deseado para el tratamiento con el cambiador de cationes, eliminando en la etapa d1) la solución de alcoxilado del cambiador de cationes, presionándolo con un gas inerte.