4.
    发明专利
    未知

    公开(公告)号:DE59407901D1

    公开(公告)日:1999-04-15

    申请号:DE59407901

    申请日:1994-09-03

    Applicant: BASF AG

    Abstract: A process for the preparation of multiphase homopolymers or copolymers of C2-C10-alk-1-enes, characterised in that the polymerisation is carried out in one reaction zone in the presence of two different catalyst systems, where one of the catalyst systems contains, as active constituents, a metallocene complex of the formula (I) or (II) in which M is a metal from group IVb, Vb or VIb of the Periodic Table, R and R are identical or different and are a hydrogen atom, a C1-C10-alkyl group, a C1-C10-alkoxy group, a C6-C10-aryl group, a C6-C10-aryloxy group, a C2-C10-alkenyl group, a C7-C40-arylalkyl group, a C7-C40-alkylaryl group, a C8-C40 arylalkenyl group or a halogen atom, R and R are identical or different and are a hydrogen atom, a halogen atom, a C1-C10-alkyl group, which may be halogenated, a C6-C10-aryl group, an -NR 2, -SR , -OSiR 3, - SiR 3 or -PR 2 radical, in which R is a halogen atom, a C1-C10-alkyl group or a C6-C10-aryl group, and R and R are identical or different and are as defined for R and R with the proviso that R and R are not hydrogen.

    Prepn. of vinyl]-aromatic polymers, giving syndiotactic polymers for use in prodn. of mouldings

    公开(公告)号:DE19506554A1

    公开(公告)日:1996-08-29

    申请号:DE19506554

    申请日:1995-02-24

    Applicant: BASF AG

    Abstract: Polymers of vinylaromatic cpds. are prepd. at 0-150 deg.C, in presence of catalysts contg. as active components (A) cpds. of formula XM(Z )z1(Z )z2(Z )z3 (I) and (B) (i) open-chain or cyclic alumoxane cpds. of formula (III) or (IV), or (ii) cpds. forming metallocene ions, comprising strong neutral Lewis acids, ionic cpds. with Lewis acid cations or ionic cpds. with a Bronsted acid as cation. In the formulae, X = 1-10C alkyl or alkoxy, 5-7 member cycloalkyl, 6-15C aryl or formula (II) (where R -R = H, 1-10C alkyl (opt. with 1-5 halogen substits.), 5-7 member cycloalkyl (opt. with 1-6C alkyl substits.), 6-15C aryl or arylalkyl where 2 vicinal gps. may together form 4-15C cyclic gps., or halogen, 1-10C alkoxy, NR R or Si(R )3 (where R , R = H, 1-10C alkyl, 6-15C aryl or 3-10C cycloalkyl); M = metal of the IInd - VIIIth Sub-gps.; Z -Z = polymers of vinylaromatic cpds., dienes, and/or acrylates; z1, z2, z3 = 0-3; z1 + z2 + z3 = 1-3; R = 1-4C alkyl; m = 5-30.

    10.
    发明专利
    未知

    公开(公告)号:DE19606167A1

    公开(公告)日:1997-08-21

    申请号:DE19606167

    申请日:1996-02-20

    Applicant: BASF AG

    Abstract: Supported catalyst obtainable by A) reacting an inorganic carrier material with a metal compound of the general formula (I): M (R )r(R )s(R )t(R )u in which M is an alkalyne or alkalyne earth metal or a metal of main group III or IV of the periodic system; R is hydrogen, C -C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; R to R are hydrogen, C -C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl, alkoxy or dialkylamino with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; r is a whole number from 1 to 4; and s, t and u are whole numbers from 0 to 3, where the sum r+s+t+u corresponds to the valency of M ; B) reacting the material obtained from A) with a metallocene complex in its metal dihalogenide form and a metallocenium ion-forming compound; and C) subsequent reaction with a metal compound of the general formula (II): M (R )o(R )p(R )q in which M is an alkalyne or alkalyne earth metal or a metal of main group III of the periodic system; R is hydrogen, C -C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; R to R are hydrogen, C -C10 alkyl, C6-C15 aryl, alkyl aryl, aryl alkyl or alkoxy with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; o is a whole number from 1 to 3; and p and q are whole numbers from 0 to 2 where the sum o+p+q corresponds to the valency of M .

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