公开(公告)号：US3527797A

公开(公告)日：1970-09-08

申请号：US3527797D

申请日：1967-10-17

Applicant: BASF AG

Inventor： KRABETZ RICHARD ,  ENGELBACH HEINZ ,  ZINKE-ALLMANG HELMUT

IPC: C07C51/25 ,  C07C51/32

CPC classification number: C07C51/252 ,  C07C57/04

公开(公告)号：ES2269426T3

公开(公告)日：2007-04-01

申请号：ES01949347

申请日：2001-05-17

Applicant: BASF AG

Inventor： HOFFMANN HERWIG ,  ROPER MICHAEL ,  BLANKERTZ HEINRICH-JOSEF ,  STROHMEYER MAX ,  WALZ HELMUT ,  ZINKE-ALLMANG HELMUT

IPC: C07C29/141 ,  C07B61/00 ,  C07C31/02 ,  C07C31/10 ,  C07C31/12 ,  C07C31/125

Abstract: Procedimiento para la obtención de alcoholes saturados con 3 a 20 átomos de carbono, en el que se conduce a través de un lecho de un catalizador de hidrogenado una alimentación de hidrogenado líquida, que contiene al menos un aldehído seleccionado entre propanal, n-butanal, aldehído iso-butírico, hexanal, etilhexanal, etilhexenal, nonenal, nonanal, decanal, decenal, así como los productos de hidroformilado de propileno trímero, propileno tetrámero, buteno dímero o buteno trímero, en presencia de un gas hidrogenado a través de un lecho de un catalizador de hidrogenado, caracterizado porque se añade a la alimentación de hidrogenado una cantidad soluble de manera homogénea en la misma de una base salina [M+]n [An-], donde [M+] representa un ion metálico alcalino, o el equivalente de un ion metálico alcalinotérreo; [An-] representa un anión de un ácido con un valor de pKs de más de 2, y n representa la valencia del anión.

公开(公告)号：DE1092905B

公开(公告)日：1960-11-17

申请号：DEB0045073

申请日：1957-06-22

Applicant: BASF AG

Inventor： ZINKE-ALLMANG HELMUT ,  LEICHTLE OTTO ,  BANK GEORG V ,  KELLER RUDOLF

IPC: C07C67/60 ,  C07C69/54

公开(公告)号：DE50110706D1

公开(公告)日：2006-09-21

申请号：DE50110706

申请日：2001-05-17

Applicant: BASF AG

Inventor： HOFFMANN HERWIG ,  ROEPER MICHAEL ,  BLANKERTZ HEINRICH-JOSEF ,  STROHMEYER MAX ,  WALZ HELMUT ,  ZINKE-ALLMANG HELMUT

IPC: C07C29/141 ,  C07B61/00 ,  C07C31/02 ,  C07C31/10 ,  C07C31/12 ,  C07C31/125

Abstract: The invention relates to a process for the preparation of saturated C3-C20-alcohols in which a liquid hydrogenation feed comprising at least one C3-C20-aldehyde is passed over a bed of a hydrogenation catalyst in the presence of a hydrogen-containing gas, which comprises adding to the hydrogenation feed an amount, homogeneously soluble therein, of a salt-like base. The addition of base suppresses side reactions, such as acetalization, aldolization, Tischtschenko reaction or ether formation.

公开(公告)号：AT335715T

公开(公告)日：2006-09-15

申请号：AT01949347

申请日：2001-05-17

Applicant: BASF AG

Inventor： HOFFMANN HERWIG ,  ROEPER MICHAEL ,  BLANKERTZ HEINRICH-JOSEF ,  STROHMEYER MAX ,  WALZ HELMUT ,  ZINKE-ALLMANG HELMUT

IPC: C07B61/00 ,  C07C29/141 ,  C07C31/10 ,  C07C31/12 ,  C07C31/125 ,  C07C31/02

Abstract: The invention relates to a process for the preparation of saturated C3-C20-alcohols in which a liquid hydrogenation feed comprising at least one C3-C20-aldehyde is passed over a bed of a hydrogenation catalyst in the presence of a hydrogen-containing gas, which comprises adding to the hydrogenation feed an amount, homogeneously soluble therein, of a salt-like base. The addition of base suppresses side reactions, such as acetalization, aldolization, Tischtschenko reaction or ether formation.

公开(公告)号：CA960696A

公开(公告)日：1975-01-07

申请号：CA117560

申请日：1971-07-06

Applicant: BASF AG

Inventor： HOHENSCHUTZ HEINZ ,  DIEM HANS ,  SCHMIDT JOHANNES E ,  MATTHIAS GUENTER ,  RAUCH KONRAD ,  ZINKE-ALLMANG HELMUT

IPC: C07C45/38

公开(公告)号：AU7052701A

公开(公告)日：2001-11-26

申请号：AU7052701

申请日：2001-05-17

Applicant: BASF AG

Inventor： HOFFMANN HERWIG ,  ROPER MICHAEL ,  BLANKERTZ HEINRICH-JOSEF ,  STROHMEYER MAX ,  WALZ HELMUT ,  ZINKE-ALLMANG HELMUT

IPC: C07B61/00 ,  C07C29/141 ,  C07C31/10 ,  C07C31/12 ,  C07C31/125 ,  C07C31/02

Abstract: The invention relates to a process for the preparation of saturated C3-C20-alcohols in which a liquid hydrogenation feed comprising at least one C3-C20-aldehyde is passed over a bed of a hydrogenation catalyst in the presence of a hydrogen-containing gas, which comprises adding to the hydrogenation feed an amount, homogeneously soluble therein, of a salt-like base. The addition of base suppresses side reactions, such as acetalization, aldolization, Tischtschenko reaction or ether formation.

公开(公告)号：CA819765A

公开(公告)日：1969-08-05

申请号：CA819765D

Applicant: BASF AG

Inventor： ZINKE-ALLMANG HELMUT ,  ENGELBACH HEINZ ,  KRABETZ RICHARD ,  NONNENMACHER HELMUT

公开(公告)号：CA794387A

公开(公告)日：1968-09-10

申请号：CA794387D

Applicant: BASF AG

Inventor： KRABETZ RICHARD ,  ENGELBACH HEINZ ,  ZINKE-ALLMANG HELMUT

公开(公告)号：DE10024542A1

公开(公告)日：2001-11-22

申请号：DE10024542

申请日：2000-05-18

Applicant: BASF AG

Inventor： HOFFMANN HERWIG ,  ROEPER MICHAEL ,  BLANKERTZ HEINRICH-JOSEF ,  STROHMEYER MAX ,  WALZ HELMUT ,  ZINKE-ALLMANG HELMUT

IPC: C07B61/00 ,  C07C29/141 ,  C07C31/10 ,  C07C31/12 ,  C07C31/125 ,  C07C31/02

Abstract: Production of saturated 3-20C alcohols by feeding a liquid stream comprising at least one 3-20C aldehyde over a hydrogenation catalyst bed in the presence of a hydrogen containing gas comprises addition of a homogeneously soluble quantity of a salt-like base containing an anion of an acid having a pKa of greater than 2. A process for the production of saturated 3-20C alcohols by feeding a liquid stream comprising at least one 3-20C aldehyde over a bed of a hydrogenation catalyst in the presence of a hydrogen containing gas comprises addition of a homogeneously soluble quantity of a salt-like base (M )n(An-) to the liquid stream where (M ) is an alkali metal ion or equivalent of an alkaline earth metal ion, (An-) is an anion of an acid having a pKa of greater than 2.