公开(公告)号：JP2010215642A

公开(公告)日：2010-09-30

申请号：JP2010112839

申请日：2010-05-17

Applicant: Basf Se ,  ビーエーエスエフ ソシエタス・ヨーロピアBasf Se

Inventor： RHEINHEIMER JOACHIM ,  VON DEYN WOLFGANG ,  GEBHARDT JOACHIM ,  RACK MICHAEL ,  LOCHTMAN RENE ,  GOETZ NORBERT ,  KEIL MICHAEL ,  WITSCHEL MATTHIAS ,  HAGEN HELMUT ,  MISSLITZ ULF ,  BAUMANN ERNST

IPC: C07C251/48 ,  C07B61/00 ,  C07C20060101 ,  C07C201/12 ,  C07C205/44 ,  C07C249/06 ,  C07C251/52 ,  C07C253/00 ,  C07C255/50 ,  C07C315/04 ,  C07C317/32 ,  C07C317/44 ,  C07C319/14 ,  C07C321/28 ,  C07C323/09 ,  C07D20060101 ,  C07D261/02 ,  C07D261/04 ,  C07D261/08 ,  C07D413/02 ,  C07D413/10

CPC classification number: C07C249/06 ,  C07C201/10 ,  C07C201/12 ,  C07C205/44 ,  C07C209/62 ,  C07C251/48 ,  C07C253/00 ,  C07C255/50 ,  C07C315/04 ,  C07C319/14 ,  C07D261/04 ,  C07D413/10 ,  C07C323/09 ,  C07C317/24 ,  C07C317/32 ,  C07C205/06 ,  C07C211/52

Abstract: PROBLEM TO BE SOLVED: To provide an intermediate of an isoxazolin-3-ylacyl benzene useful as an agricultural chemical, and a new method for producing the intermediate. SOLUTION: A benzaldoxime derivative represented by formula III (wherein R 1 is a 1-6C alkyl group) can be obtained by reacting a corresponding methylbenzene derivative with an organic nitrite in an aprotic polar solvent in the presence of a base at lower temperature than -20°C. COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 待解决的问题：提供可用作农业化学品的异恶唑啉-3-基酰基苯的中间体，以及用于制备中间体的新方法。 解决方案：通过使相应的甲基苯衍生物与有机亚硝酸盐在非质子传递极性溶剂中反应，可以得到由式III（其中R 1 为1-6C烷基）表示的苯甲醛肟衍生物 在比-20℃低的温度下存在碱。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：BRPI0612637B1

公开(公告)日：2016-08-02

申请号：BRPI0612637

申请日：2006-06-30

Applicant: BASF AG ,  BASF SE

Inventor： KUHN DAVID G ,  CULBERTSON DEBORAH L ,  ANSPAUGH DOUGLAS D ,  BRAUN FRANZ-JOSEF ,  OLOUMI-SADEGHI HASSAN ,  BASTIAANS HENRICUS MARIA MARTINUS ,  COTTER HENRY VAN TUYL ,  DICKHAUT JOACHIM ,  PUHL MICHAEL ,  RACK MICHAEL ,  SCHMIDT THOMAS ,  BUCCI TONI

IPC: C07D401/04 ,  A01N43/56

Abstract: compostos, processos para preparação de compostos, e de uma composição, uso de compostos, métodos para controle de insetos, acarídeos ou nematóides, para proteção de plantas em desenvolvimento do ataque ou infestação por insetos, acarídeos ou nematóides, e para tratamento, controle, prevenção ou proteção de animais contra a infestação ou infecção por parasitas, e, composições. compostos de n-tio-antranilemida da fórmula (i) em que a é um grupo selecionado de a1 e a2 em que as variáveis e os índice são como definidos pelo relatório descritivo, pelos processos para preparar os comostos i, pelas composições pesticidas que compreendem os compostos i, pelo uso dos compostos i para o controle de insetos, acarídeos ou nematóides, e métodos para tratar, controlar, prevenir ou proteger animais contra infestação ou infecção por parasitas através do uso dos compostos da fórmula i.

公开(公告)号：US6087542B1

公开(公告)日：2000-07-11

申请号：US14271597

申请日：1997-03-06

Applicant: BASF AG

Inventor： EICKEN KARL ,  GEBBARDT JOACHIM ,  RANG HARALD ,  RACK MICHAEL ,  SCHAEFER PETER

IPC: B01J31/24 ,  C07B37/04 ,  C07B61/00 ,  C07C201/12 ,  C07C205/06 ,  C07C205/11 ,  C07C205/12 ,  C07C205/35 ,  C07C253/30 ,  C07C205/00 ,  C07C43/00

CPC classification number: C07B37/04 ,  C07C201/12 ,  C07C253/30 ,  C07C205/11

公开(公告)号：WO2009133179A3

公开(公告)日：2010-02-25

申请号：PCT/EP2009055285

申请日：2009-04-30

Applicant: BASF SE ,  ZIERKE THOMAS ,  MAYWALD VOLKER ,  RACK MICHAEL ,  SMIDT SEBASTIAN PEER ,  KEIL MICHAEL ,  WOLF BERND ,  KORADIN CHRISTOPHER

Inventor： ZIERKE THOMAS ,  MAYWALD VOLKER ,  RACK MICHAEL ,  SMIDT SEBASTIAN PEER ,  KEIL MICHAEL ,  WOLF BERND ,  KORADIN CHRISTOPHER

IPC: C07D231/14 ,  C07D295/145

CPC classification number: C07D295/145 ,  C07D231/14

Abstract: The present invention relates to a method for producing 2- (aminomethylidene)-4,4dihalo-3-oxobutyric acid esters of the formula (I), where R1, R2, R3 are C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C3-C10-cycloalkyl or benzyl and/or R2 together with R3 and the nitrogen atom, to which both radicals are bound, are a heterocyclic radical, wherein a corresponding 3-aminoacrylic acid ester is reacted with a halogen-substituted acetyl fluoride in the presence of at least one alkali or earth alkali metal fluoride. The invention also relates to the further reaction of halogen-substituted 2-(aminomethylidene)-3-oxobutyric acid esters of the formula (1) into halomethyl-substituted pyrazole-4-ylcarboxylic acids and the esters thereof.

Abstract translation: 本发明涉及2-（氨基 - 亚甲基）的制备方法中，式-4,4-二卤代-3-氧代丁酸酯（I）其中R1，R2，R3是C1-C6烷基，C1-C6卤代烷基 ，C2-C6链烯基，C3-C10环烷基或与R 3苄基和/或R 2在一起并到两个基团连接的氮原子代表的杂环基团，其中一个相应的3-氨基丙烯酸酯是具有 卤乙酰氟取代反应是在至少一种碱金属或碱土金属氟化物的存在; 和卤素 - 取代的2-（氨基亚甲基）-3-氧代丁酸的式（I）的酯的进一步反应卤代甲基取代的吡唑-4-基甲酸和它们的酯。

公开(公告)号：WO2008152072A3

公开(公告)日：2009-02-12

申请号：PCT/EP2008057328

申请日：2008-06-11

Applicant: BASF SE ,  HUPE EIKE ,  SEITZ THOMAS ,  WITSCHEL MATTHIAS ,  SONG DSCHUN ,  MOBERG WILLIAM KARL ,  PARRA RAPADO LILIANA ,  STELZER FRANK ,  VESCOVI ANDREA ,  NEWTON TREVOR WILLIAM ,  REINHARD ROBERT ,  SIEVERNICH BERND ,  GROSSMANN KLAUS ,  EHRHARDT THOMAS ,  RACK MICHAEL ,  KIBLER ELMAR

Inventor： HUPE EIKE ,  SEITZ THOMAS ,  WITSCHEL MATTHIAS ,  SONG DSCHUN ,  MOBERG WILLIAM KARL ,  PARRA RAPADO LILIANA ,  STELZER FRANK ,  VESCOVI ANDREA ,  NEWTON TREVOR WILLIAM ,  REINHARD ROBERT ,  SIEVERNICH BERND ,  GROSSMANN KLAUS ,  EHRHARDT THOMAS ,  RACK MICHAEL ,  KIBLER ELMAR

IPC: C07D241/08 ,  A01N43/60

CPC classification number: C07D241/08 ,  A01N43/60

Abstract: The invention relates to piperazine compounds of the following defined general formula (I) and to their use as herbicides. The invention also relates to crop protection agents and to a method for combating undesired plant growth. In formula (I): R1 is selected from halogen, cyano, nitro, Z-C(=O)-R12, phenyl and a 5- or 6-membered heterocyclic group that has 1, 2, 3 or 4 heteroatoms, selected from O, N and S as ring atoms, wherein phenyl and the heterocyclic group are unsubstituted or have 1, 2, 3 or 4 substituents R1a; Z stands for a covalent bond or a CH2 group; R12 represents hydrogen, C1-C6 alkyl, C3-C6 cycloalkyl, C2-C6alkenyl, C5-C6 cycloalkenyl, C2-C6alkynyl and similar; R2 represents hydrogen, halogen, nitro, cyano, C1-C4alkyl, C1-C4 haloalkyl, C2- C4 alkenyl, C1-C4 alkoxy, C1-C4haloalkoxy, benzyl or a group S(O) nR21, wherein R21 stands for C1-C4 alkyl or C1-C4 haloalkyl and n stands for 0, 1 or 2; R3 represents hydrogen or halogen; R4 represents C1-C4 alkyl, C3- C4 alkenyl or C3-C4 alkynyl; R5 represents hydrogen, C1-C4alkyl, C3-C4 alkenyl, C3-C4 alkynyl or a group (=O)R51, wherein R51 stands for hydrogen, C1-C4alkyl, C1-C4 haloalkyl, C1-C4 alkoxy or C1-C4 haloalkoxy; R6 stands for C1-C4alkyl, C1-C4 hydroxy alkyl or C1-C4haloalkyl; R7, R8 stand, independently of one another, for hydrogen, OH, C1-C4 alkoxy, C1-C4 haloalkyoxy, C1-C4 alkyl or C1-C4 haloalkyl; R9, R10 are selected, independently of one another, from hydrogen, halogen, CN, NO2, C1-C4 alkyl, C1-C4 haloalkyl, C2-C4 alkenyl, C1-C4 alkoxy and C1-C4 haloalkoxy; and R11 represents hydrogen or C1-C4 alkyl. The invention also relates to the agriculturally suitable salts of said compounds.

Abstract translation: 本发明涉及如以下通式（I）中所定义的哌嗪化合物及其作为除草剂的用途。 本发明还涉及组合物用于作物保护和打击不需要的植物生长的方法。 R 1选自卤素，氰基，硝基，ZC（= O）-R 12，苯基和选择的5-或6-元杂环基团含有选自O，N和S的1，2，3或4个杂原子 作为环原子，其中苯基和杂环基团是未取代的或有1个，2个，3个或4个取代基R1A有; Z是共价键或CH 2基团; R12是氢，C1-C6烷基，C3-C6环烷基，C2-C6烯基，C5-C6环烯基，C2-C6炔基等; R2是氢，卤素，硝基，氰基，C1-C4烷基，C1-C4卤代烷基，C2-C4链烯基，C1-C4烷氧基，C1-C4卤代烷氧基，苄基或基团S（O）NR21， 其中R 21代表C1-C4烷基或C1-C4卤代烷基，n为0，1或2; R3是氢或卤素; R4是C1-C4烷基，C 3 -C 4 - 烯基或C 3 -C 4炔基; R5是氢，C1-C4烷基，C3-C4链烯基，C3-C4炔基或基团C（= O）R51，其中R51是氢，C1-C4烷基，C1-C4卤代烷基，C1 C4烷氧基或C1-C4卤代烷氧基; R6是C1-C4烷基，C1-C4-HydroxyalkyloderC1-C4卤代烷基; R7，R8独立地为氢，OH，C1-C4烷氧基，C1-C4 Haloalkyoxy，C1-C4烷基或C1-C4卤代烷基; R9，R10独立地选自氢，卤素，CN，NO2，C1-C4烷基，C1-C4卤代烷基，C2-C4链烯基，C1-C4烷氧基和C1-C4卤代烷氧基中选择; 和R11是氢或C1-C4烷基; 以及这些化合物的农业上适用的盐。

公开(公告)号：WO2012059441A2

公开(公告)日：2012-05-10

申请号：PCT/EP2011069072

申请日：2011-10-31

Applicant: BASF SE ,  KOERBER KARSTEN ,  KORDES MARKUS ,  RACK MICHAEL ,  DEYN WOLFGANG VON ,  KAISER FLORIAN

Inventor： KOERBER KARSTEN ,  KORDES MARKUS ,  RACK MICHAEL ,  VON DEYN WOLFGANG ,  KAISER FLORIAN

IPC: C07C249/04

CPC classification number: C07D261/04 ,  C07C249/12 ,  C07D413/12 ,  C07C251/48

Abstract: The present invention relates to a method for preparing 4-chloro-, 4-bromo- or 4- iodobenzaldehyde oximes and phenyl-substituted isoxazoline compounds prepared from these oximes.

Abstract translation: 本发明涉及由这些肟制备的4-氯代，4-溴-4-碘代苯甲醛肟和苯基取代的异恶唑啉化合物的方法。

公开(公告)号：WO2015082422A3

公开(公告)日：2015-12-03

申请号：PCT/EP2014076149

申请日：2014-12-01

Applicant: BASF SE

Inventor： KLAUBER ERIC GEORGE ,  RACK MICHAEL ,  ZIERKE THOMAS ,  HOLUB NICOLE ,  SCHMELEBECK GERALD ,  JI JUNMIN ,  CORTES DAVID

IPC: C07C67/11 ,  C07C45/46 ,  C07C51/02 ,  C07C51/09 ,  C07C51/12 ,  C07C51/41 ,  C07C67/42

CPC classification number: C07C67/42 ,  C07C37/0555 ,  C07C45/46 ,  C07C51/02 ,  C07C51/09 ,  C07C51/12 ,  C07C51/41 ,  C07C67/11 ,  C07C69/63 ,  C07C39/30 ,  C07C49/807 ,  C07C65/05 ,  C07C65/21 ,  C07C69/92

Abstract: A process for reacting chemical compounds comprising the step of oxidizing a compound of formula (II) wherein R1 and R2 are halogen, and R3 is -(C1-C4) alkyl, in the presence of a peroxy reagent to obtain a compound of formula (III).

Abstract translation: 化合物反应的方法包括在过氧化试剂存在下氧化式（II）化合物（其中R 1和R 2为卤素，且R 3为 - （C 1 -C 4）烷基）的步骤，得到式 III）。

公开(公告)号：WO2008152073A3

公开(公告)日：2009-02-12

申请号：PCT/EP2008057329

申请日：2008-06-11

Applicant: BASF SE ,  HUPE EIKE ,  SEITZ THOMAS ,  WITSCHEL MATTHIAS ,  SONG DSCHUN ,  MOBERG WILLIAM KARL ,  PARRA RAPADO LILIANA ,  STELZER FRANK ,  VESCOVI ANDREA ,  NEWTON TREVOR WILLIAM ,  REINHARD ROBERT ,  SIEVERNICH BERND ,  GROSSMANN KLAUS ,  EHRHARDT THOMAS ,  RACK MICHAEL ,  KIBLER ELMAR

Inventor： HUPE EIKE ,  SEITZ THOMAS ,  WITSCHEL MATTHIAS ,  SONG DSCHUN ,  MOBERG WILLIAM KARL ,  PARRA RAPADO LILIANA ,  STELZER FRANK ,  VESCOVI ANDREA ,  NEWTON TREVOR WILLIAM ,  REINHARD ROBERT ,  SIEVERNICH BERND ,  GROSSMANN KLAUS ,  EHRHARDT THOMAS ,  RACK MICHAEL ,  KIBLER ELMAR

IPC: C07D241/08 ,  A61K31/495 ,  C07D403/10 ,  C07D407/10 ,  C07D409/10 ,  C07D413/10 ,  C07D417/10

CPC classification number: C07D241/08 ,  C07D403/10 ,  C07D407/10 ,  C07D409/10 ,  C07D413/10 ,  C07D417/10

Abstract: The invention relates to piperazine compounds of the following defined general formula (I) and to their use as herbicides. The invention also relates to crop protection agents and to a method for combating undesired plant growth. In formula (I), the variables are defined as follows: R1 is selected from halogen, cyano, nitro, Z-C(=O)-R11, phenyl and a 5- or 6-membered heterocyclic group that has 1, 2, 3 or 4 heteroatoms, selected from O, N and S as ring atoms, wherein phenyl and the heterocyclic group are unsubstituted or have 1, 2, 3 or 4 substituents R1a; Z stands for a covalent bond or a CH2 group; R11 represents hydrogen, C1-C6 alkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C5-C6 cycloalkenyl, C2-C6 alkynyl and similar; R2 represents hydrogen, halogen, nitro, cyano, C1-C4 alkyl, C1-C4 haloalkyl, C2- C4 alkenyl, C1-C4 alkoxy, C1-C4 haloalkoxy, benzyl or a group S(O) nR21, wherein R21 stands for C1-C4 alkyl or C1-C4 haloalkyl and n stands for 0, 1 or 2; R3 represents hydrogen or halogen; R4 represents C1-C4 alkyl, C3- C4 alkenyl or C3-C4 alkynyl; R5 represents hydrogen, C1-C4 alkyl, C3-C4 alkenyl, C3-C4 alkynyl or a group (=O)R51, wherein R51 stands for hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy or C1-C4 haloalkoxy; R6 stands for C1-C4 alkyl, C1-C4 hydroxy alkyl or C1-C4 haloalkyl; R7, R8 stand, independently of one another, for hydrogen, OH, C1-C4 alkoxy, C1-C4 haloalkyoxy, C1-C4 alkyl or C1-C4 haloalkyl; R9, R10 are selected, independently of one another, from hydrogen, halogen, CN, NO2, C1-C4 alkyl, C1-C4 haloalkyl, C2-C4 alkenyl, C1-C4alkoxy and C1-C4 haloalkoxy.

Abstract translation: 本发明涉及如以下通式（I）中所定义的哌嗪化合物及其作为除草剂的用途。 本发明还涉及组合物用于作物保护和打击不需要的植物生长的方法。 在式（I）中，变量具有以下含义：R 1选自卤素，氰基，硝基，ZC（= O）-R 11，苯基中的含有1，2，3或4的5-或6-元杂环基团 由具有杂原子作为环原子，其中苯基和杂环基团是未取代的或具有O，N和S的1，2，3或4个具有取代基R1A; Z是共价键或CH 2基团; R11是氢，C1-C6烷基，C3-C6环烷基，C2-C6烯基，C5-C6环烯基，C2-C6炔基等; R2是氢，卤素，硝基，氰基，C1-C4烷基，C1-C4卤代烷基，C2-C4链烯基，C1-C4烷氧基，C1-C4卤代烷氧基，苄基或基团S（O）NR21， 其中R 21代表C1-C4烷基或C1-C4卤代烷基，n为0，1或2; R3是氢或卤素; R4是C1-C4烷基，C3-C4链烯基或C3-C4炔基; R5是氢，C1-C4烷基，C3-C4链烯基，C3-C4炔基或基团C（= O）R51，其中R51是氢，C1-C4烷基，C1-C4卤代烷基，C1 C4烷氧基或C1-C4卤代烷氧基; R6是C1-C4烷基，C1-C4羟烷基或C1-C4卤代烷基; R7，R8独立地为氢，OH，C1-C4烷氧基，C1-C4 Haloalkyoxy，C1-C4烷基或C1-C4卤代烷基; 和R9，R10独立地选自氢，卤素，CN，NO2，C1-C4烷基，C1-C4卤代烷基，C2-C4链烯基，C1-C4烷氧基和C1-C4卤代烷氧基中选择。

公开(公告)号：WO2009153285A2

公开(公告)日：2009-12-23

申请号：PCT/EP2009057531

申请日：2009-06-17

Applicant: BASF SE ,  DEYN WOLFGANG VON ,  PUHL MICHAEL ,  POHLMAN MATTHIAS ,  RACK MICHAEL ,  PARRA RAPADO LILIANA ,  LANGEWALD JUERGEN ,  ANSPAUGH DOUGLAS D ,  OLOUMI-SADEGHI HASSAN ,  CULBERTSON DEBORAH L ,  RANKL NANCY B ,  KAMP HENNICKE ,  VAN RAVENZWAAY BENNARD

Inventor： VON DEYN WOLFGANG ,  PUHL MICHAEL ,  POHLMAN MATTHIAS ,  RACK MICHAEL ,  PARRA RAPADO LILIANA ,  LANGEWALD JUERGEN ,  ANSPAUGH DOUGLAS D ,  OLOUMI-SADEGHI HASSAN ,  CULBERTSON DEBORAH L ,  RANKL NANCY B ,  KAMP HENNICKE ,  VAN RAVENZWAAY BENNARD

IPC: C07D417/06 ,  A01N43/80 ,  C07D417/14

CPC classification number: C07D417/06 ,  A01N43/80 ,  C02F1/001 ,  C02F2209/03 ,  C02F2303/16 ,  C07D417/14

Abstract: The present invention relates to sulfonamide compounds of formula (I) wherein R1 is H, halogen, CN, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylthio, C2-C6-alkenylthio, C2-C6-alkynylthio, C1-C6-haloalkyl or C1-C6-haloalkoxy; R2 and R3 are H, halogen, CN, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylthio, C2-C6-alkenylthio, C2-C6-alkynylthio, C1-C6-haloalkyl or C1-C6-haloalkoxy; or R2 together with R3 form a fused 5 or 6-membered carbocycle or heterocycle; R4 is halogen, CN, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkyl, C1-C6-haloalkoxy, C1-C6-haloalkylthio, C1-C6-haloalkylsulfinyl or C1-C6-haloalksulfonyl; n is 0, 1, 2 or 3; R5 is phenyl or a 5- or 6-membered heterocycle; X is O or NRx, wherein Rx is H, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylcarbonyl or C1-C6-alkylcarbonyloxy; Y is N or C(Ry), wherein Ry is H, halogen, CN, C1-C6-alkyl,C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C3-7-cycloalkyl- C1-C4-alkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylthio, C2-C6-alkenylthio, C2-C6-alkynylthio, C1-C6-haloalkyl and C1-C6-haloalkoxy; and Z is a chemical bond, O or N(Rz), wherein Rz is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C1-C6-alkylcarbonyl or C1-C6-alkylcarbonyloxy; as well as to the N-oxides and salts thereof. These compounds are useful for combating animal pests. The invention also relates to a process for the preparation of these compounds and to intermediate compounds used in said process. The invention further relates to a method for controlling animal pests by using the compounds of formula (I), the N-oxides or the salts thereof, to plant propagation material and to an agricultural and veterinary composition comprising said compounds, the N-oxides or the salts thereof.

Abstract translation: 本发明涉及式（I）的磺酰胺化合物，其中R1是H，卤素，CN，C1-C6-烷基，C2-C6-烯基，C2-C6-炔基，C3-C7-环烷基，C3-C7-环烷基 C 1 -C 4 - 烷基，C 1 -C 6 - 烷氧基，C 2 -C 6 - 烯氧基，C 2 -C 6 - 炔氧基，C 1 -C 6 - 烷硫基，C 2 -C 6 - 烯硫基，C 2 -C 6 - 炔硫基，C 1 -C 6 - 卤代烷基或C 1 1 -C 6 - 卤代烷氧基; R2和R3是H，卤素，CN，C1-C6-烷基，C2-C6-烯基，C2-C6-炔基，C3-C7-环烷基，C3-C7-环烷基-C1-C4-烷基，C1-C6- 烷氧基，C 2 -C 6 - 烯氧基，C 2 -C 6 - 炔氧基，C 1 -C 6 - 烷硫基，C 2 -C 6 - 烯硫基，C 2 -C 6炔硫基，C 1 -C 6卤代烷基或C 1 -C 6卤代烷氧基; 或R 2与R 3一起形成稠合的5或6元碳环或杂环; R4是卤素，CN，C1-C6-烷基，C2-C6-烯基，C2-C6-炔基，C1-C6-烷氧基，C1-C6-烷硫基，C1-C6-烷基亚磺酰基，C1-C6-烷基磺酰基，C1- C 1 -C 6卤代烷基，C 1 -C 6卤代烷硫基，C 1 -C 6卤代烷基亚磺酰基或C 1 -C 6卤代磺酰基; n为0,1,2或3; R5是苯基或5-或6-元杂环; X是O或NR x，其中Rx是H，C 1 -C 6烷基，C 2 -C 6 - 烯基，C 2 -C 6 - 炔基，C 3 -C 7 - 环烷基，C 1 -C 6 - 烷氧基，C 2 -C 6 - 烯氧基，C 2 -C 6 - 炔基氧基，C 1 -C 6 - 烷基羰基或C 1 -C 6烷基羰基氧基; Y是N或C（Ry），其中R y是H，卤素，CN，C 1 -C 6烷基，C 2 -C 6 - 烯基，C 2 -C 6炔基，C 3 -C 7 - 环烷基，C 3-7 - C 1 -C 6烷基，C 1 -C 6 - 烷氧基，C 2 -C 6 - 烯氧基，C 2 -C 6 - 炔氧基，C 1 -C 6 - 烷硫基，C 2 -C 6 - 烯硫基，C 2 -C 6 - 炔硫基， 卤代烷氧基; Z为化学键，O或N（Rz），其中Rz为C1-C6-烷基，C2-C6-烯基，C2-C6-炔基，C3-C7-环烷基，C1-C6-烷氧基，C2-C6 - 烯氧基，C1-C6-烷基羰基或C1-C6-烷基羰基氧基; 以及N-氧化物及其盐。 这些化合物可用于对抗动物害虫。 本发明还涉及制备这些化合物的方法和用于所述方法的中间体化合物。 本发明还涉及通过使用式（I）化合物，其N-氧化物或其盐来植物繁殖材料以及包含所述化合物，N-氧化物或其盐的农业和兽医组合物来控制动物害虫的方法 其盐。

公开(公告)号：WO2008113661A3

公开(公告)日：2008-12-04

申请号：PCT/EP2008052346

申请日：2008-02-27

Applicant: BASF SE ,  ZIERKE THOMAS ,  RACK MICHAEL

Inventor： ZIERKE THOMAS ,  RACK MICHAEL

IPC: C07C241/02

CPC classification number: C07C319/20 ,  C07C241/02 ,  C07C323/48 ,  C07C243/22

Abstract: This invention relates to a process for preparing substituted phenylhydrazines of the formula I wherein R has the meaning as indicated in the description, comprising reacting a dichlorofluorobenzene of the formula Il with a hydrazine source selected from hydrazine, hydrazine hydrate and acid addition salts of hydrazine and optionally being carried out in the presence of at least one organic solvent.

Abstract translation: 本发明涉及一种制备式I取代苯肼的方法，其中R具有如说明书中所述的含义，包括使式II的二氯氟苯与选自肼，水合肼和肼的酸加成盐的肼源和 任选地在至少一种有机溶剂的存在下进行。