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1.发明申请
公开(公告)号：WO2014053431A3
公开(公告)日：2015-02-26
申请号：PCT/EP2013070321
申请日：2013-09-30
Applicant: BASF SE
Inventor： BRAND RAPHAEL HEINRICH , ASPRION NORBERT , FERSTL WOLFGANG , TELLAECHE HERRANZ CARLOS , GÖTZ JOCHEN , REZAI ALIREZA
IPC: C07C7/08
CPC classification number: C07C7/08 , Y02P20/582 , C07C11/08 , C07C9/10
Abstract: The invention relates to a continuous method for separation of a mixture of hydrocarbons by extractive distillation having a mixture of a polar aprotic solvent and water as a selective solvent, in a system comprising an extractive distillation column and an outgas column, characterized in that the method is carried out under continuous measurement of the water content of the selective solvent via NIR spectroscopy, wherein the measured values from the continuous measurement of the water content of the selective solvent are compared to a specified target value and regulated to a value within a specified concentration range above and below the target value by addition or exfiltration of water or by addition of polar aprotic solvent.
Abstract translation: 本发明涉及一种连续方法用于使用极性非质子溶剂和水作为选择性溶剂的混合物通过萃取蒸馏的烃的混合物，其包括萃取蒸馏塔和脱气塔的分离，在一个系统，该系统的特征在于，下的连续测量的方法 通过近红外光谱，内进行所述选择性溶剂的水含量，其中，从与预先设定的目标值进行比较的选择性溶剂中的水含量的连续测量的测量值，并通过添加或排出的水或通过加入非质子性极性溶剂的预置为值 浓度范围之上和之下的调节设定值。
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公开(公告)号：SG11201408582QA
公开(公告)日：2015-02-27
申请号：SG11201408582Q
申请日：2013-07-12
Applicant: BASF SE
Inventor： PAZICKY MAREK , RAITH CHRISTIAN , PACIELLO ROCCO , BRAND RAPHAEL HEINRICH , HARTMANN MARCO , MÜLLER-ENGEL KLAUS JOACHIM , ZUROWSKI PETER , FISCHER WOLFGANG
Abstract: A process for preparing acrylic acid from ethylene oxide and carbon monoxide, in which ethylene oxide is carbonylated in an aprotic solvent with carbon monoxide in the presence of a cobalt catalyst system to give poly-3-hydroxypropionate, the cobalt content in the poly-3-hydroxypropionate formed is reduced with the aid of water and/or an aqueous solution as a precipitation and/or wash liquid, and the poly-3-hydroxypropionate is subsequently split by thermolysis to give acrylic acid.
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公开(公告)号：DE102012212424A1
公开(公告)日：2014-01-16
申请号：DE102012212424
申请日：2012-07-16
Applicant: BASF SE
Inventor： RAITH CHRISTIAN , PAZICKY MAREK , PACIELLO ROCCO , BRAND RAPHAEL HEINRICH , HARTMANN MARCO , MUELLER-ENGEL KLAUS-JOACHIM , ZUROWSKI PETER , FISCHER WOLFGANG
IPC: C07C57/075 , C07C57/04 , C07C211/00 , C07C217/00
Abstract: Ein Verfahren zur Herstellung von Acrylsäure durch Thermolyse von Poly-3-hydroxypropionat im Beisein eines oder mehrerer spezieller tertiärer Amine als Katalysator.
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Patent Agency Ranking
公开(公告)号：SG11201408547QA
公开(公告)日：2015-02-27
申请号：SG11201408547Q
申请日：2013-07-12
Applicant: BASF SE
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公开(公告)号：AU2013292147A1
公开(公告)日：2015-02-05
申请号：AU2013292147
申请日：2013-07-12
Applicant: BASF SE
Inventor： RAITH CHRISTIAN , PAZICKY MAREK , PACIELLO ROCCO , BRAND RAPHAEL HEINRICH , HARTMANN MARCO , MULLER-ENGEL KLAUS JOACHIM , ZUROWSKI PETER , FISCHER WOLFGANG
Abstract: A method for producing acrylic acid by thermolysis of poly-3-hydroxy propionate in the presence of one or more specific tertiary amines as catalysts.
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公开(公告)号：AU2013292147B2
公开(公告)日：2017-02-16
申请号：AU2013292147
申请日：2013-07-12
Applicant: BASF SE
Inventor： RAITH CHRISTIAN , PAZICKY MAREK , PACIELLO ROCCO , BRAND RAPHAEL HEINRICH , HARTMANN MARCO , MULLER-ENGEL KLAUS JOACHIM , ZUROWSKI PETER , FISCHER WOLFGANG
Abstract: A method for producing acrylic acid by thermolysis of poly-3-hydroxy propionate in the presence of one or more specific tertiary amines as catalysts.
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公开(公告)号：ZA201501002B
公开(公告)日：2016-05-25
申请号：ZA201501002
申请日：2015-02-12
Applicant: BASF SE
Inventor： PACIELLO ROCCO , FISCHER WOLFGANG , ZUROWSKI PETER , MÜLLER-ENGEL KLAUS JOACHIM , HARTMANN MARCO , BRAND RAPHAEL HEINRICH , RAITH CHRISTIAN , PAZICKY MAREK
Abstract: A process for preparing acrylic acid from ethylene oxide and carbon monoxide, in which ethylene oxide is carbonylated in an aprotic solvent with carbon monoxide in the presence of a cobalt catalyst system to give poly-3-hydroxypropionate, the cobalt content in the poly-3-hydroxypropionate formed is reduced with the aid of water and/or an aqueous solution as a precipitation and/or wash liquid, and the poly-3-hydroxypropionate is subsequently split by thermolysis to give acrylic acid.
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公开(公告)号：DE102012212437A1
公开(公告)日：2014-01-16
申请号：DE102012212437
申请日：2012-07-16
Applicant: BASF SE
Inventor： PAZICKY MAREK , RAITH CHRISTIAN , PACIELLO ROCCO , BRAND RAPHAEL HEINRICH , HARTMANN MARCO , MUELLER-ENGEL KLAUS-JOACHIM , ZUROWSKI PETER , FISCHER WOLFGANG
IPC: C07C57/045 , C07C57/04
Abstract: Ein Verfahren zur Herstellung von Acrylsäure aus Ethylenoxid und Kohlenmonoxid, bei dem Ethylenoxid in einem nicht protischen Lösungsmittel mit Kohlenmonoxid in Anwesenheit eines Co-haltigen Katalysatorsystems zu Poly-3-hydroxypropionat carbonyliert, der Gehalt des gebildeten Poly-3-hydroxypropionats an Co mit Hilfe von Wasser und/oder einer wässrigen Lösung als Fäll- und/oder Waschflüssigkeit vermindert und das Poly-3-hydroxypropionat nachfolgend durch Thermolyse zu Acrylsäure gespalten wird.
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