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    FINELY DIVIDED, CATIONIC, AQUEOUS POLYMER DISPERSIONS, METHOD FOR THE PRODUCTION THEREOF, AND THE USE THEREOF
    3.
    发明专利
    FINELY DIVIDED, CATIONIC, AQUEOUS POLYMER DISPERSIONS, METHOD FOR THE PRODUCTION THEREOF, AND THE USE THEREOF 未知

    公开(公告)号：CA3006151C

    公开(公告)日：2020-09-08

    申请号：CA3006151

    申请日：2016-12-01

    Applicant: BASF SE

    Inventor： CIMPEANU CARMEN-ELENA ,  MOELLER KLAUS ,  ARNOLD PETRA ,  GEORGIEVA KRISTINA ,  DIEING REINHOLD ,  JEHN-RENDU CHRISTIAN ,  WEN QUAN

    IPC: C08F212/08 ,  C08F2/28 ,  C08F2/30 ,  C08F26/06 ,  C08F220/14 ,  C08F220/34 ,  C08F220/44 ,  D21H17/45 ,  D21H21/16

    Abstract: Finely divided, cationic, aqueous polymer dispersion which is obtainable by emulsion polymerisation of ethylenically unsaturated monomers in an aqueous liquid containing a cationic prepolymer as a dispersant, wherein the cationic prepolymer is prepared in the presence of at least one polymerisation initiator by polymerisation of (a) from 15 to 45% by weight of at least one ethylenically unsaturated monomer comprising at least one quaternary ammonium group; (b) from 5 to 80% by weight of at least one optionally substituted styrene; (c) from 0 to 50% by weight of at least one C1-12 alkyl (meth) acrylate; (d) from 0 to 10% by weight of at least one ethylenically unsaturated monomer comprising an acid group; (e) from 0 to 10% by weight of at least one ethylenically unsaturated monomer comprising an amine group; and (f) from 0 to 20% by weight of at least one non-ionic ethylenically unsaturated monomer differing from (b), (c) and (e), the sum of (a) + (b) + (c) + (d) + (e) + (f) being 100% by weight, in a first emulsion polymerisation in the presence of at least one non-ionic emulsifier, and thereafter, in the aqueous liquid containing the cationic prepolymer, a second emulsion polymerisation is carried out, in the presence of at least one polymerisation initiator, of a monomer mixture comprising (i) from 10 to 70% by weight of at least one of an optionally substituted styrene or (meth) acrylonitrile; (ii) from 30 to 90% by weight of at least one CMS alkyl (meth) acrylate; (iii) from 0 to 30% by weight of at least one vinyl ester of linear or branched C1-30 carboxylic acids; and (iv) from 0 to 30% by weight of at least one non-ionic ethylenically unsaturated monomer differing from (i), (ii) and (iii), the sum of (i) + (ii) + (iii) + (iv) being 100% by weight, and the first emulsion polymerisation and/or the second emulsion polymerisation is optionally carried out in the presence of from 0 to 10% by weight of at least one polymerisation regulator. The polymer dispersions according to the present invention are suitable for use as sizing agents for paper, board and cardboard.

    4.
    发明专利
    未知

    公开(公告)号：DE50213398D1

    公开(公告)日：2009-05-07

    申请号：DE50213398

    申请日：2002-11-21

    Applicant: BASF SE

    Inventor： DIEING REINHOLD ,  BERGHAUS RAINER ,  CHRISSTOFFELS LYSANDER ,  SCHMIDT OSKAR ,  KOEHLE HARALD ,  GOTSCHE MICHAEL ,  KOBER REINER

    IPC: A01N25/10 ,  A01N61/00 ,  A01N25/30 ,  A01N27/00 ,  A01N37/06 ,  A01N43/88

    Abstract: The present invention relates to the use of specific amphiphilic copolymers as synergistic adjuvant for agrotechnical applications. Suitable agrotechnical compositions are also described. Thus, the addition of such copolymers makes possible an accelerated uptake of active ingredients by the plant. The copolymers or salts thereof to be used comprise monomer units (i) based on at least one olefin and/or at least one vinyl ether, (ii) based on at least one ethylenically unsaturated dicarboxylic acid and/or at least one ethylenically unsaturated dicarboxylic acid derivative, and, optionally (iii) based on at least one further copolymerizable comonomer.

    EMPLEO DE POLIMEROS QUE CONTIENEN POLISILOXANO PARA FORMULACIONES COSMETICAS.
    5.
    发明专利
    EMPLEO DE POLIMEROS QUE CONTIENEN POLISILOXANO PARA FORMULACIONES COSMETICAS. 未知

    公开(公告)号：ES2318872T3

    公开(公告)日：2009-05-01

    申请号：ES98936432

    申请日：1998-07-20

    Applicant: BASF SE

    Inventor： BLANKENBURG RAINER ,  DIEING REINHOLD ,  MULLER WOLFGANG ,  SANNER AXEL ,  SCHEHLMANN VOLKER ,  ZEITZ KATRIN

    IPC: A61K8/00 ,  A61K8/894 ,  A61K8/72 ,  A61K8/89 ,  A61K8/90 ,  A61Q5/00 ,  A61Q5/06 ,  C08F283/12 ,  C08G77/46 ,  C08L83/12

    Abstract: Empleo de polímeros que son hidrosolubles o dispersables en agua, o que, para el caso de que estén constituidos por monómeros con restos neutralizables, sean hidrosolubles o dispersables en agua en forma neutralizada, que son obtenibles polimerizándose a través de radicales ** ver fórmula** significando: R 2 = CH 3 o ** ver fórmula** R 3 = CH 3 o R 2 R 4 = H, CH3, ** ver fórmula** R 6 un resto orgánico constituido por 1 a 40 átomos de carbono, que puede contener grupos amino, ácido carboxílico o sulfonato, o para el caso c = O, también el anión de un ácido orgánico, y pudiendo ser los restos R 1 idénticos o diferentes, y ser seleccionados a partir del siguiente grupo: metilo, etilo, propilo, butilo, isobutilo, pentilo, isopentilo, hexilo, octilo, decilo, dodecilo y octadecilo, ciclohexilo, grupos aromáticos, especialmente fenilo o naftilo, bencilo, feniletilo, así como tolilo y xililo, o iguales a R5: ** ver fórmula** con la condición de que al menos uno de los restos R 1 , R 2 o R 3 sea un resto que contiene óxido de polialquileno según la definición citada anteriormente, y n sea un número entero de 1 a 6, x e y son números enteros de tal manera que el peso molecular de bloques de polisiloxanos se sitúa entre 300 y 30.000, a, b pueden ser números enteros entre 0 y 50, con la condición de que la suma de a y b sea mayor que 0, y C es 0 o 1, para formulaciones cosméticas.

    6.
    发明专利
    未知

    公开(公告)号：DE102007052412A1

    公开(公告)日：2008-06-05

    申请号：DE102007052412

    申请日：2007-11-02

    Applicant: BASF SE

    Inventor： DOBRAWA RAINER ,  WIDMAIER RALF ,  SCHNELL KLAUS ,  STRUBE KARL-HERMANN ,  NIEBERLE JUERGEN ,  DIEING REINHOLD ,  POTZOLLI BERND DE ,  GRUBER ANDREAS ,  FILGES ULRICH ,  MEISTER MARTIN ,  NEUTZNER JOSEF ,  BOUQUET WOLFGANG ,  SCHUPP EBERHARD

    IPC: C08F2/06 ,  C08F218/08 ,  C08F226/10

    Abstract: Methods of producing vinyllactam copolymers which include: providing at least one water-soluble N-vinyllactam; providing at least one hydrophobic comonomer; and subjecting the at least one water-soluble N-vinyllactam and the at least one hydrophobic comonomer to free-radical polymerization in an organic solvent in the presence of an initiator, under a combination of process measures selected from the group consisting of A and B; wherein: (A) comprises (i) polymerization under reflux, and at least two of (ii), (iii), (iv), (v), (vi), and (vii), wherein (ii) comprises an addition of at least 5 mol % of N-vinyllactam to the polymerization mixture if at least 70 mol % of the total amount of hydrophobic monomer used have completely reacted, (iii) comprises return of condensate formed in the reflux from below to the polymerization mixture, (iv) comprises introduction of the initiator in the form of a solution in an organic solvent from below into the polymerization mixture, (v) comprises addition of N-vinyllactam to the reflux, (vi) comprises distilling off a portion of the organic solvent and continuing the polymerization following conversion of 70 to 99% by weight of the N-vinyllactam used, and (vii) comprises introduction of at least one monomer from below into the polymerization mixture; and wherein (B) comprises (viii) polymerization under a superatmospheric pressure such that vaporization of the polymerization components is avoided, and at least one of (i), (ii), (iii), (iv), (v), (vi), and (vii), with the proviso that a combination of (viii) with any of (i), (iii) or (v) is carried out sequentially.

    FINELY DIVIDED, CATIONIC, AQUEOUS POLYMER DISPERSIONS, METHOD FOR THE PRODUCTION THEREOF, AND THE USE THEREOF
    8.
    发明专利
    FINELY DIVIDED, CATIONIC, AQUEOUS POLYMER DISPERSIONS, METHOD FOR THE PRODUCTION THEREOF, AND THE USE THEREOF 未知

    公开(公告)号：CA3006151A1

    公开(公告)日：2017-06-08

    申请号：CA3006151

    申请日：2016-12-01

    Applicant: BASF SE

    Inventor： CIMPEANU CARMEN-ELENA ,  MOELLER KLAUS ,  ARNOLD PETRA ,  GEORGIEVA KRISTINA ,  DIEING REINHOLD ,  JEHN-RENDU CHRISTIAN ,  WEN QUAN

    IPC: C08F212/08 ,  C08F2/28 ,  C08F2/30 ,  C08F26/06 ,  C08F220/14 ,  C08F220/34 ,  C08F220/44 ,  D21H17/45 ,  D21H21/16

    Abstract: Finely divided, cationic, aqueous polymer dispersion which is obtainable by emulsion polymerisation of ethylenically unsaturated monomers in an aqueous liquid containing a cationic prepolymer as a dispersant, wherein the cationic prepolymer is prepared in the presence of at least one polymerisation initiator by polymerisation of (a) from 15 to 45% by weight of at least one ethylenically unsaturated monomer comprising at least one quaternary ammonium group; (b) from 5 to 80% by weight of at least one optionally substituted styrene; (c) from 0 to 50% by weight of at least one C1-12 alkyl (meth) acrylate; (d) from 0 to 10% by weight of at least one ethylenically unsaturated monomer comprising an acid group; (e) from 0 to 10% by weight of at least one ethylenically unsaturated monomer comprising an amine group; and (f) from 0 to 20% by weight of at least one non-ionic ethylenically unsaturated monomer differing from (b), (c) and (e), the sum of (a) + (b) + (c) + (d) + (e) + (f) being 100% by weight, in a first emulsion polymerisation in the presence of at least one non-ionic emulsifier, and thereafter, in the aqueous liquid containing the cationic prepolymer, a second emulsion polymerisation is carried out, in the presence of at least one polymerisation initiator, of a monomer mixture comprising (i) from 10 to 70% by weight of at least one of an optionally substituted styrene or (meth) acrylonitrile; (ii) from 30 to 90% by weight of at least one CMS alkyl (meth) acrylate; (iii) from 0 to 30% by weight of at least one vinyl ester of linear or branched C1-30 carboxylic acids; and (iv) from 0 to 30% by weight of at least one non-ionic ethylenically unsaturated monomer differing from (i), (ii) and (iii), the sum of (i) + (ii) + (iii) + (iv) being 100% by weight, and the first emulsion polymerisation and/or the second emulsion polymerisation is optionally carried out in the presence of from 0 to 10% by weight of at least one polymerisation regulator. The polymer dispersions according to the present invention are suitable for use as sizing agents for paper, board and cardboard.

    9.
    发明专利
    未知

    公开(公告)号：AT426333T

    公开(公告)日：2009-04-15

    申请号：AT02803405

    申请日：2002-11-21

    Applicant: BASF SE

    Inventor： DIEING REINHOLD ,  BERGHAUS RAINER ,  CHRISSTOFFELS LYSANDER ,  SCHMIDT OSKAR ,  KIHLE HARALD ,  GOTSCHE MICHAEL ,  KOBER REINER

    IPC: A01N25/10 ,  A01N61/00 ,  A01N25/30 ,  A01N27/00 ,  A01N37/06 ,  A01N43/88

    Abstract: The present invention relates to the use of specific amphiphilic copolymers as synergistic adjuvant for agrotechnical applications. Suitable agrotechnical compositions are also described. Thus, the addition of such copolymers makes possible an accelerated uptake of active ingredients by the plant. The copolymers or salts thereof to be used comprise monomer units (i) based on at least one olefin and/or at least one vinyl ether, (ii) based on at least one ethylenically unsaturated dicarboxylic acid and/or at least one ethylenically unsaturated dicarboxylic acid derivative, and, optionally (iii) based on at least one further copolymerizable comonomer.

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