AQUEOUS POLYMER DISPERSION OBTAINABLE BY FREE-RADICALLY INITIATED EMULSION POLYMERIZATION IN THE PRESENCE OF LIGNOSULFONATE

    公开(公告)号:CA2864370A1

    公开(公告)日:2013-08-22

    申请号:CA2864370

    申请日:2013-02-11

    Applicant: BASF SE

    Abstract: Described is an aqueous polymer dispersion comprising a chain growth addition polymer obtainable via free-radically initiated emulsion polymerization from ethylenically unsaturated, free-radically polymerizable monomers, wherein the chain growth addition polymer is formed to an extent of not less than 60 wt% from primary monomers selected from vinylaromatic compounds, conjugated aliphatic dienes, vinyl esters of saturated C1- to C20-carboxylic acids, esters of acrylic acid or of methacrylic acid with monohydric C1- to C20-alcohols, aliphatic hydrocarbons having 2 to 8 carbon atoms and one or two double bonds, or mixtures thereof, wherein the monomers are polymerized in the presence of lignosulfonate and wherein the chain growth addition polymer is branched or crosslinked. Also described is a process for preparing the aqueous polymer dispersion. The polymer dispersion is useful for preparing paper coating compositions.

    Dispersión acuosa de polímero para masas autoadhesivas

    公开(公告)号:ES2809559T3

    公开(公告)日:2021-03-04

    申请号:ES16819036

    申请日:2016-12-14

    Applicant: BASF SE

    Abstract: Uso de una dispersión acuosa para la fabricación de pegantes, en el que la dispersión acuosa de polímeros es obtenible mediante un procedimiento que comprende las siguientes etapas: A) preparación de una dispersión acuosa de al menos un poliuretano PU esencialmente no entrecruzado, en forma de partículas dispersas de poliuretano, en la que el poliuretano PU es obtenible mediante una polimerización de compuestos PU-M que forman poliuretano, que contienen al menos un diol PU-M2, que exhibe al menos un grupo polialquilen C2-C14 éter, que exhibe al menos una unidad de la fórmula (i) -O-CHRa-CH2-Rb- (i), en la que Ra representa hidrógeno o alquilo C1-C12, Rb representa un enlace o alquileno C1-C3, en la que Ra no representa hidrógeno cuando Rb es un enlace, y en la que el PU no exhibe esencialmente enlaces dobles con insaturación etilénica y exhibe una fracción de gel de

    FINELY DIVIDED, CATIONIC, AQUEOUS POLYMER DISPERSIONS, METHOD FOR THE PRODUCTION THEREOF, AND THE USE THEREOF

    公开(公告)号:CA3006151A1

    公开(公告)日:2017-06-08

    申请号:CA3006151

    申请日:2016-12-01

    Applicant: BASF SE

    Abstract: Finely divided, cationic, aqueous polymer dispersion which is obtainable by emulsion polymerisation of ethylenically unsaturated monomers in an aqueous liquid containing a cationic prepolymer as a dispersant, wherein the cationic prepolymer is prepared in the presence of at least one polymerisation initiator by polymerisation of (a) from 15 to 45% by weight of at least one ethylenically unsaturated monomer comprising at least one quaternary ammonium group; (b) from 5 to 80% by weight of at least one optionally substituted styrene; (c) from 0 to 50% by weight of at least one C1-12 alkyl (meth) acrylate; (d) from 0 to 10% by weight of at least one ethylenically unsaturated monomer comprising an acid group; (e) from 0 to 10% by weight of at least one ethylenically unsaturated monomer comprising an amine group; and (f) from 0 to 20% by weight of at least one non-ionic ethylenically unsaturated monomer differing from (b), (c) and (e), the sum of (a) + (b) + (c) + (d) + (e) + (f) being 100% by weight, in a first emulsion polymerisation in the presence of at least one non-ionic emulsifier, and thereafter, in the aqueous liquid containing the cationic prepolymer, a second emulsion polymerisation is carried out, in the presence of at least one polymerisation initiator, of a monomer mixture comprising (i) from 10 to 70% by weight of at least one of an optionally substituted styrene or (meth) acrylonitrile; (ii) from 30 to 90% by weight of at least one CMS alkyl (meth) acrylate; (iii) from 0 to 30% by weight of at least one vinyl ester of linear or branched C1-30 carboxylic acids; and (iv) from 0 to 30% by weight of at least one non-ionic ethylenically unsaturated monomer differing from (i), (ii) and (iii), the sum of (i) + (ii) + (iii) + (iv) being 100% by weight, and the first emulsion polymerisation and/or the second emulsion polymerisation is optionally carried out in the presence of from 0 to 10% by weight of at least one polymerisation regulator. The polymer dispersions according to the present invention are suitable for use as sizing agents for paper, board and cardboard.

    FINELY DIVIDED, CATIONIC, AQUEOUS POLYMER DISPERSIONS, METHOD FOR THE PRODUCTION THEREOF, AND THE USE THEREOF

    公开(公告)号:CA3006151C

    公开(公告)日:2020-09-08

    申请号:CA3006151

    申请日:2016-12-01

    Applicant: BASF SE

    Abstract: Finely divided, cationic, aqueous polymer dispersion which is obtainable by emulsion polymerisation of ethylenically unsaturated monomers in an aqueous liquid containing a cationic prepolymer as a dispersant, wherein the cationic prepolymer is prepared in the presence of at least one polymerisation initiator by polymerisation of (a) from 15 to 45% by weight of at least one ethylenically unsaturated monomer comprising at least one quaternary ammonium group; (b) from 5 to 80% by weight of at least one optionally substituted styrene; (c) from 0 to 50% by weight of at least one C1-12 alkyl (meth) acrylate; (d) from 0 to 10% by weight of at least one ethylenically unsaturated monomer comprising an acid group; (e) from 0 to 10% by weight of at least one ethylenically unsaturated monomer comprising an amine group; and (f) from 0 to 20% by weight of at least one non-ionic ethylenically unsaturated monomer differing from (b), (c) and (e), the sum of (a) + (b) + (c) + (d) + (e) + (f) being 100% by weight, in a first emulsion polymerisation in the presence of at least one non-ionic emulsifier, and thereafter, in the aqueous liquid containing the cationic prepolymer, a second emulsion polymerisation is carried out, in the presence of at least one polymerisation initiator, of a monomer mixture comprising (i) from 10 to 70% by weight of at least one of an optionally substituted styrene or (meth) acrylonitrile; (ii) from 30 to 90% by weight of at least one CMS alkyl (meth) acrylate; (iii) from 0 to 30% by weight of at least one vinyl ester of linear or branched C1-30 carboxylic acids; and (iv) from 0 to 30% by weight of at least one non-ionic ethylenically unsaturated monomer differing from (i), (ii) and (iii), the sum of (i) + (ii) + (iii) + (iv) being 100% by weight, and the first emulsion polymerisation and/or the second emulsion polymerisation is optionally carried out in the presence of from 0 to 10% by weight of at least one polymerisation regulator. The polymer dispersions according to the present invention are suitable for use as sizing agents for paper, board and cardboard.

    Tinta de impresión a base de agua que comprende un aglutinante de poliuretano disperso acuoso y un aglutinante de poli(met)acrilato disperso acuoso

    公开(公告)号:ES2747776T3

    公开(公告)日:2020-03-11

    申请号:ES16727697

    申请日:2016-06-08

    Applicant: BASF SE

    Abstract: Una tinta de impresión a base de agua que comprende al menos dos aglutinantes, al menos un pigmento, un vehículo acuoso y aditivos opcionales, en la que al menos un aglutinante es un aglutinante de dispersión de poliuretano y al menos un aglutinante es un aglutinante de dispersión de poli(met)acrilato, en el que el poliuretano está hecho de componentes que comprenden: a) al menos un diisocianato, b) al menos un diol que tiene un peso molecular promedio en número de 500 a 5000 g/mol, c) al menos un compuesto funcional monohidroxilado que tiene un peso molecular promedio en número de 500 a 5000 g/mol, d) opcionalmente, al menos un compuesto polifuncional que tiene al menos tres grupos NCO o que tiene al menos tres grupos reactivos con NCO, e) opcionalmente, al menos una diamina que no tiene grupos ácidos, f) opcionalmente, un compuesto que tiene al menos un grupo reactivo con NCO y al menos un grupo iónico o ionizable, g) opcionalmente, al menos uno o más compuestos de poliol que tienen un peso molecular promedio en número de menos de 500 g/mol, preferentemente, de 60 a 490 g/mol; y en la que el poli(met)acrilato tiene una temperatura de transición vítrea entre -20 y + 40 °C, preferentemente de -10 a +35 °C y se prepara por polimerización de componentes que comprenden: h) al menos un monómero de vinilo seleccionado del grupo que consiste en acrilatos, metacrilatos y estireno, i) de 0,1 a 4 % en peso de uno o más monómeros de vinilo con un grupo ácido, preferentemente ácido (met)acrílico, j) opcionalmente, hasta 5 % en peso de uno o más monómeros de vinilo hidrófilos no iónicos con una solubilidad en agua de más de 100 g/l a 20 °C, preferentemente, seleccionados del grupo que consiste en acrilamida, metacrilamida, acrilato de hidroxietilo y metacrilato de hidroxietilo, k) opcionalmente, uno o más monómeros adicionales diferentes de los monómeros h), i) y j). y en la que el poliuretano y el poli(met)acrilato están presentes en una relación de peso de 1:9 a 9:1, preferentemente de 1:5 a 5:1, más preferentemente de 1:3 a 3:1, en base al peso total de los polímeros.

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