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    Method for producing 3-methylamino-1-(thien-2-yl)propan-1-ol
    1.
    发明专利
    Method for producing 3-methylamino-1-(thien-2-yl)propan-1-ol 审中-公开
    3-甲基氨基-1-（噻二-2-基）丙烷-1-醇的制备方法

    公开(公告)号：JP2011142908A

    公开(公告)日：2011-07-28

    申请号：JP2011005361

    申请日：2011-01-14

    Applicant: Basf Se ,  ビーエーエスエフ ソシエタス・ヨーロピアBasf Se

    Inventor： STUERMER RAINER ,  KESSELER MARIA ,  HAUER BERNHARD ,  FRIEDRICH THOMAS ,  BREUER MICHAEL

    IPC: C12N15/09 ,  C07B61/00 ,  C07D333/16 ,  C07D333/20 ,  C12N1/15 ,  C12N1/19 ,  C12N1/21 ,  C12N5/10 ,  C12N9/04 ,  C12N15/53 ,  C12N15/63 ,  C12P7/04 ,  C12P17/00

    CPC classification number: C07D333/16

    Abstract: PROBLEM TO BE SOLVED: To provide an enzymatic or nonenzymatic method for producing 3-methylamino-1-(thien-2-yl)propan-1-ol represented by formula (I), and further, to provide an enzyme for conducting the method, a nucleic acid sequence encoding the enzyme, an expression cassette including the nucleic acid sequence, a vector and a recombinant host organism.
    SOLUTION: The method comprises the following processes: (a) thiophene is reacted with a halogenated β-halopropionyl or halogenated acryloyl in the presence of a Lewis acid; wherein, either simultaneously or after the reaction but prior to isolating a reaction product, a hydrogen halide is passed through the reaction product to obtain a 3-halo-1-(thien-2-yl)propan-1-one; and (b) the propanone obtained in the step (a) is reduced, and subsequently, the reduced product is reacted with methylamine without isolating the reaction product as appropriate.
    COPYRIGHT: (C)2011,JPO&INPIT

    Abstract translation: 待解决的问题：提供用于制备由式（I）表示的3-甲基氨基-1-（噻吩-2-基）丙-1-醇的酶或非酶法，并且还提供用于 进行该方法，编码该酶的核酸序列，包含该核酸序列的表达盒，载体和重组宿主生物。 解决方案：该方法包括以下方法：（a）在路易斯酸存在下，噻吩与卤代β-卤代丙酰基或卤代丙烯酰基反应; 其中，在反应同时或之后但在分离反应产物之前，使卤化氢通过反应产物，得到3-卤代-1-（噻吩-2-基）丙-1-酮; 和（b）步骤（a）中获得的丙酮被还原，随后将还原产物与甲胺反应，而不适当地分离反应产物。 版权所有（C）2011，JPO＆INPIT

    ACTIVE INGREDIENT COMPOSITIONS FOR PLANT PROTECTION
    2.
    发明申请
    ACTIVE INGREDIENT COMPOSITIONS FOR PLANT PROTECTION 审中-公开
    活性化合物保护植物

    公开(公告)号：WO2008132179A3

    公开(公告)日：2009-04-30

    申请号：PCT/EP2008055101

    申请日：2008-04-25

    Applicant: BASF SE ,  DIECKMANN YVONNE ,  BRANDS MARIO ,  ISRAELS RAFEL ,  FRIEDRICH THOMAS ,  WINTER GABI ,  YAMAMOTO MOTONORI ,  DOMBO PETER ,  HUBER-MOULLIET URSULA ,  SZTOJ SILVIA

    Inventor： DIECKMANN YVONNE ,  BRANDS MARIO ,  ISRAELS RAFEL ,  FRIEDRICH THOMAS ,  WINTER GABI ,  YAMAMOTO MOTONORI ,  DOMBO PETER ,  HUBER-MOULLIET URSULA ,  SZTOJ SILVIA

    IPC: A01N25/12 ,  A01N25/10 ,  A01N63/00 ,  A01P13/00 ,  B01J13/02

    CPC classification number: B01J13/02 ,  A01N25/12 ,  A01N63/00 ,  A01N25/10 ,  A01N61/00 ,  A01N2300/00

    Abstract: The present invention relates to novel active ingredient compositions for plant protection in the form of fine active ingredient-containing particles, comprising a) at least one active plant protection agent; b) at least one polymer P, which is not soluble in water, can be decomposed by enzymatic hydrolysis and is present in a quantity of at least 20% by weight, relative to the total amount of the components of the active ingredient-containing particles, and c) at least one hydrolase (EC 3), wherein at least 90% by weight of the active ingredient-containing particles of the active ingredient composition does not exceed a diameter of 500 µm (Dgo value), wherein the components a), b) and c) constitute at least 30% by weight of the active ingredient particles. The invention further relates to a method for the production thereof and to the use of the active ingredient compositions for the treatment of plants, soils and seed.

    Abstract translation: 本发明涉及一种用于在细碎的含活性成分的颗粒，其a）至少一个作物保护剂的形式作物保护新颖活性物质组合物; b）至少一种非水溶性的，通过在至少20重量％的量，基于所述含活性成分的颗粒的组分的总量聚合物P的酶水解的可生物降解，以及c）至少含有水解酶（EC 3），其特征在于 至少90重量的活性化合物组合物的含活性成分的颗粒的％，其中所述组分a），b）和c）至少30重量％，则药物的颗粒包括直径为500微米的不超过（DGO值）。 本发明还涉及它们的制备方法和用于植物，土壤和种子处理中使用的活性物质组合物的方法。

    NUEVAS DESHIDROGENASAS, Y UN METODO PARA LA PRODUCCION DE ALCANOLES OPTICAMENTE ACTIVOS.
    9.
    发明专利
    NUEVAS DESHIDROGENASAS, Y UN METODO PARA LA PRODUCCION DE ALCANOLES OPTICAMENTE ACTIVOS. 未知

    公开(公告)号：ES2345001T3

    公开(公告)日：2010-09-13

    申请号：ES06806768

    申请日：2006-09-14

    Applicant: BASF SE

    Inventor： BREUER MICHAEL ,  FRIEDRICH THOMAS ,  KESSELER MARIA

    IPC: C12N9/04

    Abstract: Método para la producción microbiológica de alcanoles sustituidos de la fórmula I **(Ver fórmula)** donde n representa un valor numérico entero de 0 a 5; Cyc representa un anillo carbocíclico saturado o insaturado, mono o polinuclear, dado el caso caso sustituido o no sustituido, y R1representa halógeno, SH, OH, NO2, NR2R3 o NR2R3R4+X-, donde R2, R3 y R4 representan independientemente uno de otro H o un radical alquilo pequeño o alcoxi pequeño y X- representa un ion contrario, donde en un medio que contiene una alcanona de la fórmula II **(Ver fórmula)** donde n, Cyc y R1 poseen los significados arriba indicados, a) se cultiva un microorganismo productor de una deshidrogenasa con la secuencia de polipéptido SEQ ID NO:2 o NO:4, o con una secuencia de polipéptido, en la cual se ha cambiado hasta 25% de los radicales aminoácido respecto a SEQ ID NO: 2 o NO:4 mediante deleción, inserción, sustitución o una combinación de ellos, o b) se incuba una deshidrogenasa como se mencionó bajo a) donde el compuesto de la fórmula II es reducido enzimáticamente hasta el compuesto de la fórmula I, y se aísla el producto formado.

    10.
    发明专利
    未知

    公开(公告)号：DE502006006865D1

    公开(公告)日：2010-06-10

    申请号：DE502006006865

    申请日：2006-09-14

    Applicant: BASF SE

    Inventor： BREUER MICHAEL ,  FRIEDRICH THOMAS ,  KESSELER MARIA

    IPC: C12N9/04

    Abstract: The present invention relates to proteins having an enzymatic activity of reducing substituted alkanones such as 3-methylamino-1-(2-thienyl)-propan-1-one. The invention furthermore relates to nucleic acids coding for said proteins, nucleic acid constructs, vectors, genetically modified microorganisms and to methods for preparing optically active substituted alkanols, such as, for example, (S)-3-methylamino-1-(2-thienyl)-(S)-propanol.

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