公开(公告)号：WO2011020878A3

公开(公告)日：2011-09-15

申请号：PCT/EP2010062098

申请日：2010-08-19

Applicant: BASF SE ,  TELES JOAQUIM HENRIQUE ,  SCHELPER MICHAEL ,  GUMLICH KAI ,  CHABANAS MATHIEU ,  MUELLER CHRISTIAN ,  MEIER ANTON

Inventor： TELES JOAQUIM HENRIQUE ,  SCHELPER MICHAEL ,  GUMLICH KAI ,  CHABANAS MATHIEU ,  MUELLER CHRISTIAN ,  MEIER ANTON

IPC: C07C51/235 ,  C07C57/03

CPC classification number: C07C51/235 ,  C07C57/03

Abstract: The invention relates to a method for producing 4-pentenoic acid, at least comprising the oxidation of a mixture (G) containing 4-pentenal, 3-methyl-2-butanone and cyclopentene oxide and to the use of a mixture (G) containing 4-pentenal, 3-methyl-2-butanone and cyclopentene oxide for producing 4-pentenoic acid. The invention also relates to the mixture (G) which is obtained as an auxiliary product from the oxidation of cyclopentene to cyclopentanone by means of dinitrogen monoxide.

Abstract translation: 本发明涉及一种方法，用于4-戊烯酸的制备中，至少包含以下的混合物的含有4-戊烯醛，3-甲基-2-丁酮含有氧化（G），和环戊烯氧化物，以及使用的混合物（G）-4-戊烯醛，3- 甲基-2-丁酮和4-戊烯酸的制备环戊烯氧化物。 在本发明的上下文中，环戊烯氧化成环戊酮的副产物的混合物（G）优选通过一氧化二氮的方法而获得。

公开(公告)号：WO2009024446A3

公开(公告)日：2009-05-07

申请号：PCT/EP2008060121

申请日：2008-08-01

Applicant: BASF SE ,  TELES JOAQUIM HENRIQUE ,  GUMLICH KAI ,  SCHAEFER JOCHEN ,  OEHLENSCHLAEGER STEFFEN ,  LAMM STEPHAN ,  MERTEN ROLAND ,  SCHAEFER MARTIN ,  GROB RUEDIGER ,  EMNET UWE

Inventor： TELES JOAQUIM HENRIQUE ,  GUMLICH KAI ,  SCHAEFER JOCHEN ,  OEHLENSCHLAEGER STEFFEN ,  LAMM STEPHAN ,  MERTEN ROLAND ,  SCHAEFER MARTIN ,  GROB RUEDIGER ,  EMNET UWE

IPC: C07C51/235 ,  B01J8/22 ,  C07C53/124 ,  C07C53/126 ,  C07C53/128

CPC classification number: C07C51/235 ,  C07C53/124 ,  C07C53/128 ,  C07C53/122 ,  C07C53/126

Abstract: The invention relates to a process for the oxidation of organic compounds with oxygen in which, in a first step, the organic compound and at least some of the oxygen required for the oxidation are charged to a first reaction zone, where the first reaction zone is operated isothermally and back-mixed, and in a second step the reaction mixture from the first reaction zone is passed to a second reaction zone, where the second reaction zone is operated adiabatically. The invention further relates to a reactor for carrying out the process comprising at least one isothermal (3, 5) and one adiabatic (7) reaction zone which are arranged in a reactor jacket (8), where each isothermal reaction zone (3, 5) is configured in the form of a jet loop reactor and the adiabatic reaction zone (7) is configured as bubble column.

Abstract translation: 本发明涉及一种方法，用于与氧的有机化合物的氧化，其中在第一步骤中的有机化合物和至少所需的氧的氧化的一部分在第一反应区中添加，其中，所述第一反应区等温运行和返混，并且在 第二步骤中，从所述第二反应区绝热操作的第一反应区的反应混合物供入第二反应区。 本发明还涉及一种用于执行该方法的反应器，其包括至少一个等温（3,5）和绝热（7）反应区被布置在反应器容器（8）中，每个等温反应区（3,5）中的一个形式 喷射回路反应器被设计和绝热反应区（7）被设计为泡罩塔。

公开(公告)号：WO2009024549A3

公开(公告)日：2009-04-30

申请号：PCT/EP2008060786

申请日：2008-08-18

Applicant: BASF SE ,  TELES JOAQUIM HENRIQUE ,  OEHLENSCHLAEGER STEFFEN ,  GUMLICH KAI ,  SCHAEFER MARTIN ,  LAMM STEPHAN ,  BERG STEFAN ,  NILLES MICHAEL ,  SCHILDBERG HANS-PETER ,  JOHN TILO ,  ZEHNER PETER

Inventor： TELES JOAQUIM HENRIQUE ,  OEHLENSCHLAEGER STEFFEN ,  GUMLICH KAI ,  SCHAEFER MARTIN ,  LAMM STEPHAN ,  BERG STEFAN ,  NILLES MICHAEL ,  SCHILDBERG HANS-PETER ,  JOHN TILO ,  ZEHNER PETER

IPC: C07C51/235 ,  C07C53/122 ,  C07C53/126

CPC classification number: C07C51/235 ,  Y02P20/582 ,  C07C53/126 ,  C07C53/122

Abstract: The invention relates to a process for oxidizing at least one organic substance with oxygen, comprising the following steps: a) adding the at least one organic substance, in the form of a liquid, and an oxygen-containing gas stream to a first reaction stage, to form a reaction mixture, at least some of the oxygen reacting with the organic compound to form a reaction product, b) adding the reaction mixture from the first reaction stage to an adiabatically operated reaction stage, in which the unreacted organic substance undergoes at least partial further reaction to form the product. The invention additionally relates to an apparatus for implementing the process.

Abstract translation: 本发明涉及一种用于用氧气氧化的至少一种有机物质，所述方法包括以下步骤：a）加成作为液体和在第一反应阶段接触以形成反应混合物的含氧气体流的至少一个有机物质，其中，至少与所述的氧的一部分 反应有机化合物的反应产物，b）将来自第一反应阶段的反应混合物中的绝热操作反应阶段，其中进一步至少部分地发生反应的未反应的有机物质的产品。 此外，本发明涉及一种装置，用于执行该方法。

公开(公告)号：AU2013361819A1

公开(公告)日：2015-05-21

申请号：AU2013361819

申请日：2013-12-06

Applicant: BASF SE

Inventor： GARCIA CASTRO IVETTE ,  GUMLICH KAI ,  FRENZEL STEFAN ,  HEUKEN MARIA ,  KONRAD ROUVEN ,  NEUBECKER KARIN

IPC: C08F2/06 ,  C08F220/18 ,  C08L31/04 ,  C10L1/196

Abstract: The invention relates to polymer compositions obtainable by radical polymerization of at least two different alkyl(meth)acrylates in the presence of at least one ethylene-vinyl ester copolymer, wherein a mixture comprising alkyl(meth)acrylates with linear C

公开(公告)号：BRPI0815629A2

公开(公告)日：2015-02-18

申请号：BRPI0815629

申请日：2008-08-01

Applicant: BASF SE

Inventor： TELES JOAQUIM HENRIQUE ,  GUMLICH KAI ,  SCHAEFER JOCHEN ,  OEHLENSCHLAEGER STEFFAN ,  LAMM STEPHAN ,  MERTEN ROLAND ,  SCHAEFER MARTIN ,  GROB RUEDIGER ,  EMNET UWE

IPC: C07C51/235 ,  B01J8/22 ,  C07C53/124 ,  C07C53/126 ,  C07C53/128

Abstract: The invention relates to a process for the oxidation of organic compounds by means of oxygen, in which, in a first step, the organic compound and at least part of the oxygen required for the oxidation are introduced into a first reaction zone which is operated isothermally and with backmixing and, in a second step, the reaction mixture from the first reaction zone is introduced into a second reaction zone which is operated adiabatically. The invention further relates to a reactor for carrying out the process, which comprises at least one isothermal reaction zone (3, 5) and an adiabatic reaction zone (7) which are arranged in a reactor shell (8), with each isothermal reaction zone (3, 5) being configured in the form of a jet loop reactor and the adiabatic reaction zone (7) being configured as a bubble column.

公开(公告)号：CA2889773A1

公开(公告)日：2014-06-26

申请号：CA2889773

申请日：2013-12-06

Applicant: BASF SE

Inventor： FAUL DIETER ,  GARCIA CASTRO IVETTE ,  GUMLICH KAI ,  HEUKEN MARIA ,  KONRAD ROUVEN ,  NEUBECKER KARIN ,  FRENZEL STEFAN

IPC: C08F2/06 ,  C08F220/18 ,  C08L31/04 ,  C10L1/196

Abstract: The invention relates to polymer formulations comprising at least two different solvents with a flash point =60°C and polymer compositions obtainable by radical polymerization of at least one alkyl(meth)acrylate in the presence of at least one ethylene-vinyl ester copolymer. The invention further relates to a multistage method for producing such formulations and to the use of such formulations as pour-point depressants for crude oils, mineral oils or mineral oil products.

公开(公告)号：ES2436625T3

公开(公告)日：2014-01-03

申请号：ES10715902

申请日：2010-05-05

Applicant: BASF SE ,  DOW CHEMICAL CO

Inventor： KAMPE PHILIP ,  RESCH PETER ,  CHIN SOO YIN ,  BASLER PETER ,  MUELLER ULRICH ,  SCHINDLER GOETZ-PETER ,  GOEBBEL HANS-GEORG ,  TELES JOAQUIM HENRIQUE ,  GUMLICH KAI ,  GRASLER THOMAS ,  BARTOSCH CHRISTIAN ,  JACUBINAS RICHARD ,  WEIDENBACH MEINOLF

IPC: C07D301/12

Abstract: Un proceso para producir óxido de propileno que comprende (I) hacer reaccionar propeno con peróxido de hidrógeno en la presencia de un catalizador para dar una mezcla (GI) quecomprende óxido de propileno, propeno sin reaccionar y oxígeno; (II) separar óxido de propileno de la mezcla (GI) para dar una mezcla (GII) que comprende propeno y oxígeno; (III) agregar hidrógeno a la mezcla (GII) y reducir el oxígeno contenido en la mezcla (GII) al menos parcialmente porreacción con hidrógeno en presencia de un catalizador que comprende cobre en forma elemental y/o oxidada sobre unsoporte, en donde el cobre está presente sobre el soporte en una cantidad de 30 a 80% en peso, con base en elcatalizador completo calculado como CuO.

公开(公告)号：AT417814T

公开(公告)日：2009-01-15

申请号：AT06754896

申请日：2006-04-27

Applicant: BASF SE

Inventor： GUMLICH KAI ,  TELES JOAQUIM HENRIQUE

IPC: C07C51/31 ,  C07C55/24

Abstract: A process for preparing tetracarboxylic acids of the general formula I or salts thereof, wherein at least one compound of the general formula II a or II b (a) is first reacted with at least one epoxidation reagent and (b) then oxidized with nitric acid or at least one nitrogen oxide, where the variables are defined as follows: R1, R2 are the same or different and are selected from hydrogen, phenyl and C1-C10-alkyl.

公开(公告)号：DE102008002535A1

公开(公告)日：2009-01-02

申请号：DE102008002535

申请日：2008-06-19

Applicant: BASF SE

Inventor： CHIN SOO YIN ,  JOHANN THORSTEN ,  KOTREL STEFAN ,  GUMLICH KAI ,  TELES JOAQUIM HENRIQUE ,  WEYRAUCH JAN PHILLIPP ,  DELLA PINA CRISTINA ,  FALLETTA ERMELINDA ,  ROSSI MICHELE

IPC: C07C45/37 ,  B01J23/48 ,  C07C45/38 ,  C07C45/39 ,  C07C47/127

Abstract: Producing vicinal dioxo compounds, which exhibit a boiling point of = to the reaction temperature at reaction pressure, comprises heterogeneously catalyzed gas phase oxidation of the corresponding vicinal dihydroxy compounds, which exhibit a boiling point of = to the reaction temperature at reaction pressure, in the presence of gases containing oxygen on a catalyst comprising silver as active component and optionally gold, at a reaction temperature of 200-450[deg] C and a reaction pressure of 0.01-1 MPa. Producing vicinal dioxo compounds, which exhibit a boiling point of = to the reaction temperature at reaction pressure, comprises heterogeneously catalyzed gas phase oxidation of the corresponding vicinal dihydroxy compounds, which exhibit a boiling point of = to the reaction temperature at reaction pressure, in the presence of gases containing oxygen on a catalyst comprising silver as active component and optionally gold, at a reaction temperature of 200-450[deg] C and a reaction pressure of 0.01-1 MPa, where the catalyst exhibits a fabric, a knitted fabric or a foil as substrate and exhibits a gold/silver mass ratio in the active components applied on the substrate of 0-25, and is obtained by vapor deposition of at least 10% of silver and optionally gold containing active components on the substrate from the gas phase.

公开(公告)号：ES2769078T3

公开(公告)日：2020-06-24

申请号：ES16797890

申请日：2016-11-17

Applicant: BASF SE

Inventor： GARCIA CASTRO IVETTE ,  GUMLICH KAI ,  FRENZEL STEFAN ,  HEUKEN MARIA ,  KONRAD ROUVEN ,  NEUBECKER KARIN ,  BOHRES EDWARD ,  BLANAZS ADAM

IPC: C10L1/196 ,  C10L10/04 ,  C10L10/14 ,  C10L10/16

Abstract: Copolímero (X) que comprende como monómero por lo menos (A) del 40 al 60 % molar, referido a la cantidad de todos los monómeros, de por lo menos una olefina α (A) de la fórmula general H2C=CH-R1, en la que R1 representa por lo menos un radical hidrocarburo lineal, cíclico o ramificado, alifático y/o aromático con 14 a 50 átomos de carbono, así como (B) del 60 al 40 % molar, referido a la cantidad de todos los monómeros, ácidos dicarboxílicos con una insaturación etilénica o derivados de ellos, caracterizado porque los monómeros (B) son (B1) por lo menos un monómero (R2OOC)R5C=CR6(COOR4), (B2) por lo menos un monómero (R3OOC)R5C=CR6(COOR4) así como (B3) opcionalmente por lo menos un monómero elegido de entre el grupo de (HOOC)R5C=CR6(COOH) (B3a) y **(Ver fórmula)** en donde - R2 representa un radical alquilo lineal con 16 a 36 átomos de carbono, - R3 representa un radical elegido de entre el grupo de R3a: radicales 1-alquilo lineales con 1 a 10 átomos de carbono, R3b: radicales alquilo ramificados y/o secundarios con 4 a 36 átomos de carbono, R3c: radicales alquilo cíclicos con 5 a 18 átomos de carbono no sustituidos o sustituidos con alquilo, o R3d: radicales hidrocarburo con 6 a 36 átomos de carbono aromáticos no sustituidos o sustituidos con alquilo, - R4 representa en cada caso un radical elegido de entre el grupo de H, R2 y R3, teniendo como condición que en cada caso en por lo menos del 50 % molar de los radicales R4 se trata de H, - R5 y R6 representan en cada caso H o metilo, - la fracción de los radicales R3 respecto a la suma de los radicales R2 y R3 es del 1 % molar al 49 % molar, - la fracción de los monómeros (B1) + (B2), respecto a la suma de todos los monómeros (B), es por lo menos del 50 % molar, y - el promedio ponderado de peso molecular Mw de los copolímeros (X) es de 2.000 g/mol a 25.000 g/mol.