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公开(公告)号:CA2891687A1
公开(公告)日:2014-05-22
申请号:CA2891687
申请日:2013-11-08
Applicant: BASF SE
Inventor: YANG XIN , AUFFERMANN JORG , SINKEL CARSTEN , LOHMANN JEROME , LOOS ROBERT , SKUPIN GABRIEL , KUNKEL ANDREAS , BORGER LARS
Abstract: The invention relates to a biodegradable polyester mixture, containing: i) 45 to 95 wt%, with respect to the total weight of components i and ii, of a polyester I, which is synthesized from: a-1) 40 to 70 wt%, with respect to the total weight of components a and b, of an aliphatic C9-C18 dicarboxylic acid or a C9-C18 dicarboxylic acid derivative; b-1) 30 to 60 wt%, with respect to the total weight of components a and b, of terephthalic acid or a terephthalic acid derivative; c-1) 98 to 100 wt%, with respect to the total weight of components a and b, of a C3-C6 diol; d-1) 0 to 2 wt%, with respect to the total weight of components a and b, of an at least trivalent alcohol; e-1) 0 to 2 wt%, with respect to the total weight of components a to e, of a chain extender; and ii) 5 to 55 wt%, with respect to the total weight of components i and ii, of a polyester II, which is synthesized from: a-2) 40 to 70 wt%, with respect to the total weight of components a and b, of an aliphatic C4-C6 dicarboxylic acid or a C4-C6 dicarboxylic acid derivative; b-2) 30 to 60 wt%, with respect to the total weight of components a and b, of terephthalic acid or a terephthalic acid derivative; c-2) 98 to 100 wt%, with respect to the total weight of components a and b, of a C3-C6 diol; d-2) 0 to 2 wt%, with respect to the total weight of components a and b, of an at least trivalent alcohol; e-2) 0 to 2 wt%, with respect to the total weight of components a to e, of a chain extender. 10 to 25 wt%, with respect to the total weight of polymer mixtures i to iv, of calcium carbonate; and 3 to 15 wt%, with respect to the total weight of polymer mixtures i to iv, of talc.
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公开(公告)号:AU2013347034B2
公开(公告)日:2016-08-04
申请号:AU2013347034
申请日:2013-11-08
Applicant: BASF SE
Inventor: YANG XIN , AUFFERMANN JORG , SINKEL CARSTEN , LOHMANN JEROME , LOOS ROBERT , SKUPIN GABRIEL , KUNKEL ANDREAS , BORGER LARS
Abstract: The invention relates to a biodegradable polyester mixture, containing: i) 45 to 95 wt%, with respect to the total weight of components i and ii, of a polyester I, which is synthesized from: a-1) 40 to 70 wt%, with respect to the total weight of components a and b, of an aliphatic C
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公开(公告)号:AU2010314181B2
公开(公告)日:2014-05-01
申请号:AU2010314181
申请日:2010-11-02
Applicant: BASF SE
Inventor: AUFFERMANN JORG , SKUPIN GABRIEL , KUNKEL ANDREAS
Abstract: The present invention relates to a method for producing shrink films, comprising: A) 20 to 90 wt % of a biodegradable aliphatic aromatic polyester; B) 10 to 80 wt % of one or more polymers selected from the group comprising: polylactic acid, polypropylene carbonate, polycaprolactone, polyhydroxyalkanoate, chitosan, gluten, and one or more aliphatic/aromatic polyesters such as polybutylene succinate, polybutylene succinate-adipate, or polybutylene succinate-sebacate, polybutylene terephthalate-coadipate; and C) 0 to 2 wt % of a compatibility agent, wherein a blow up ratio of less than or equal to 4:1 is selected.
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公开(公告)号:AU2011206716B2
公开(公告)日:2014-01-30
申请号:AU2011206716
申请日:2011-01-06
Applicant: BASF SE
Inventor: FUBL ANDREAS , SAMPATH BANGARU , HOFMANN MAXIMILIAN , BELLIN INGO , NALAWADE SAMEER , HAHN KLAUS , KUNKEL ANDREAS , LOOS ROBERT
Abstract: The invention relates to a method for producing expandable granulates containing polylactic acid, comprising the following steps: a) melting and mixing the constituents i) between 50 and 99.9 wt. %, relative to the total weight of constituents i) to iii), of polylactic acid, ii) between 0 and 49.9 wt. %, relative to the total weight of constituents i) to iii), of at least one other polymer, iii) between 0.1 and 2 wt. %, relative to the total weight of constituents i) to iii), of a diepoxide or polyepoxide, and iv) between 0 and 10 wt. % of at least one additive, b) mixing v) between 3 and 7 wt. %, relative to the total weight of constituents i) to iv), of an organic blowing agent, into the melted polymer mass, by means of a static or dynamic mixer, at a temperature of at least 40°C, c) discharging the mixture via a nozzle plate with boreholes having a maximum on the nozzle outlet diameter of 1.5 mm, and d) granulating the melted mass containing the blowing agent directly behind the nozzle plate, under water, at a pressure of between 1 and 20 bar. The invention also relates to expandable granulates containing polylactic acid, that can be obtained according to said method, and to special expandable granulates containing polylactic acid, and between 3 and 7 wt. % of an organic blowing agent, preferably n-pentane, and especially preferably iso-pentane. The invention also relates to a preferred method for producing expandable granulates containing polylactic acid and a blowing agent, with a low bulk density.
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公开(公告)号:AU2013347034A1
公开(公告)日:2015-06-11
申请号:AU2013347034
申请日:2013-11-08
Applicant: BASF SE
Inventor: YANG XIN , AUFFERMANN JORG , SINKEL CARSTEN , LOHMANN JEROME , LOOS ROBERT , SKUPIN GABRIEL , KUNKEL ANDREAS , BORGER LARS
Abstract: The invention relates to a biodegradable polyester mixture, containing: i) 45 to 95 wt%, with respect to the total weight of components i and ii, of a polyester I, which is synthesized from: a-1) 40 to 70 wt%, with respect to the total weight of components a and b, of an aliphatic C
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公开(公告)号:CA2889039A1
公开(公告)日:2014-05-22
申请号:CA2889039
申请日:2013-11-08
Applicant: BASF SE
Inventor: YANG XIN , AUFFERMANN JORG , SINKEL CARSTEN , LOHMANN JEROME , LOOS ROBERT , SKUPIN GABRIEL , KUNKEL ANDREAS , BORGER LARS
Abstract: The present invention relates to a biodegradable polyester mixture comprising: i) 71 to 91 wt%, based on the total weight of components i and ii, of a polyester I synthesized from: a-1) 40 to 70 wt%, based on the total weight of components a and b, of an aliphatic C9-C18 dicarboxylic acid or a C9-C18 dicarboxylic acid derivative; b-1) 30 to 60 wt%, based on the total weight of components a and b, of terephthalic acid or a terephthalic acid derivative; c-1) 98 to 100 wt%, based on the total weight of components a and b, of a C3-C6 diol; d-1) 0 to 2 wt%, based on the total weight of components a and b, of an at least trihydric alcohol; e-1) 0 to 2 wt%, based on the total weight of components a to e, of a chain extender; and ii) 9 to 29 wt%, based on the total weight of components i and ii, of a polyester II synthesized from: a-2) 40 to 70 wt%, based on the total weight of components a and b, of an aliphatic C4-C6 dicarboxylic acid or a C4-C6 dicarboxylic acid derivative; b-2) 30 to 60 wt%, based on the total weight of components a and b, of terephthalic acid or a terephthalic acid derivative; c-2) 98 to 100 wt%, based on the total weight of components a and b, of a C3-C6 diol; d-2) 0 to 2 wt%, based on the total weight of components a and b, of an at least trihydric alcohol; e-2) 0 to 2 wt%, based on the total weight of components a to e, of a chain extender.
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公开(公告)号:AU2010314181A1
公开(公告)日:2012-05-31
申请号:AU2010314181
申请日:2010-11-02
Applicant: BASF SE
Inventor: AUFFERMANN JORG , SKUPIN GABRIEL , KUNKEL ANDREAS
Abstract: The present invention relates to a method for producing shrink films, comprising: A) 20 to 90 wt % of a biodegradable aliphatic aromatic polyester; B) 10 to 80 wt % of one or more polymers selected from the group comprising: polylactic acid, polypropylene carbonate, polycaprolactone, polyhydroxyalkanoate, chitosan, gluten, and one or more aliphatic/aromatic polyesters such as polybutylene succinate, polybutylene succinate-adipate, or polybutylene succinate-sebacate, polybutylene terephthalate-coadipate; and C) 0 to 2 wt % of a compatibility agent, wherein a blow up ratio of less than or equal to 4:1 is selected.
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公开(公告)号:BRPI0919438A2
公开(公告)日:2015-12-15
申请号:BRPI0919438
申请日:2009-09-22
Applicant: BASF SE
Inventor: KUNKEL ANDREAS , DIETRICH BJORN , SKUPIN GABRIEL , SIEGENTHALER KAI OLIVER , YAMAMOTO MOTONORI
IPC: C08G63/183 , C08G63/46 , C08G63/91 , C08K13/02 , C08L67/00
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公开(公告)号:AU2011206716A1
公开(公告)日:2012-08-16
申请号:AU2011206716
申请日:2011-01-06
Applicant: BASF SE
Inventor: FUSSL ANDREAS , SAMPATH BANGARU , HOFMANN MAXIMILIAN , BELLIN INGO , NALAWADE SAMEER , HAHN KLAUS , KUNKEL ANDREAS , LOOS ROBERT
Abstract: The invention relates to a method for producing expandable granulates containing polylactic acid, comprising the following steps: a) melting and mixing the constituents i) between 50 and 99.9 wt. %, relative to the total weight of constituents i) to iii), of polylactic acid, ii) between 0 and 49.9 wt. %, relative to the total weight of constituents i) to iii), of at least one other polymer, iii) between 0.1 and 2 wt. %, relative to the total weight of constituents i) to iii), of a diepoxide or polyepoxide, and iv) between 0 and 10 wt. % of at least one additive, b) mixing v) between 3 and 7 wt. %, relative to the total weight of constituents i) to iv), of an organic blowing agent, into the melted polymer mass, by means of a static or dynamic mixer, at a temperature of at least 40°C, c) discharging the mixture via a nozzle plate with boreholes having a maximum on the nozzle outlet diameter of 1.5 mm, and d) granulating the melted mass containing the blowing agent directly behind the nozzle plate, under water, at a pressure of between 1 and 20 bar. The invention also relates to expandable granulates containing polylactic acid, that can be obtained according to said method, and to special expandable granulates containing polylactic acid, and between 3 and 7 wt. % of an organic blowing agent, preferably n-pentane, and especially preferably iso-pentane. The invention also relates to a preferred method for producing expandable granulates containing polylactic acid and a blowing agent, with a low bulk density.
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