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公开(公告)号：WO2011086030A2
公开(公告)日：2011-07-21
申请号：PCT/EP2011050129
申请日：2011-01-06
Applicant: BASF SE , FUESL ANDREAS , SAMPATH BANGARU , HOFMANN MAXIMILIAN , BELLIN INGO , NALAWADE SAMEER , HAHN KLAUS , KUENKEL ANDREAS , LOOS ROBERT
Inventor： FUESL ANDREAS , SAMPATH BANGARU , HOFMANN MAXIMILIAN , BELLIN INGO , NALAWADE SAMEER , HAHN KLAUS , KUENKEL ANDREAS , LOOS ROBERT
CPC classification number: C08J9/127 , C08J9/0061 , C08J9/16 , C08J9/18 , C08J2333/14 , C08J2367/02 , C08J2367/04 , C08J2463/00 , C08J2467/02 , C08L33/068 , C08L67/02 , C08L67/04 , C08L2666/02
Abstract: The invention relates to a method for producing expandable granulates containing polylactic acid, comprising the following steps: a) melting and mixing the constituents i) between 50 and 99.9 wt. %, relative to the total weight of constituents i) to iii), of polylactic acid, ii) between 0 and 49.9 wt. %, relative to the total weight of constituents i) to iii), of at least one other polymer, iii) between 0.1 and 2 wt. %, relative to the total weight of constituents i) to iii), of a diepoxide or polyepoxide, and iv) between 0 and 10 wt. % of at least one additive, b) mixing v) between 3 and 7 wt. %, relative to the total weight of constituents i) to iv), of an organic blowing agent, into the melted polymer mass, by means of a static or dynamic mixer, at a temperature of at least 40°C, c) discharging the mixture via a nozzle plate with boreholes having a maximum on the nozzle outlet diameter of 1.5 mm, and d) granulating the melted mass containing the blowing agent directly behind the nozzle plate, under water, at a pressure of between 1 and 20 bar. The invention also relates to expandable granulates containing polylactic acid, that can be obtained according to said method, and to special expandable granulates containing polylactic acid, and between 3 and 7 wt. % of an organic blowing agent, preferably n-pentane, and especially preferably iso-pentane. The invention also relates to a preferred method for producing expandable granulates containing polylactic acid and a blowing agent, with a low bulk density.
Abstract translation: 本发明涉及一种用于制备可膨胀含聚乳酸的颗粒的方法，包括步骤：a）熔化并混合各组分ⅰ）50〜99.9重量％，基于组分的总重量，I至III），聚乳酸二 ）0至49.9重量％，基于组分的总重量，i至iii）中，一种或多种其它聚合物，ⅲ）从0.1至2重量％，基于组分的总重量，i至iii）中， 二环氧化物或聚环氧化物和iv）0至10重量％的一种或多种添加剂％，b）将v）的3至7重量％，基于组分的总重量的I至IV）有机发泡剂到聚合物熔体借助于 在至少40℃的温度下的静态或动态混合器，c）通过用造粒孔，其直径在模出口至多1.5毫米，和d）的模板排出吹直接熔融超过管芯板未剂含有 在1到20巴范围内的压力下进行。 此外，本发明涉及通过该方法和特殊可膨胀含聚乳酸的颗粒与3〜7重量的有机发泡剂的重量％，优选正戊烷和更优选异戊烷的比例获得的可膨胀的含聚乳酸的颗粒。 此外，本发明涉及制备具有低堆积密度的含推进剂的可膨胀聚乳酸颗粒的优选方法。
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公开(公告)号：CA2787222C
公开(公告)日：2017-12-12
申请号：CA2787222
申请日：2011-01-06
Applicant: BASF SE
Inventor： FUESSL ANDREAS , SAMPATH BANGARU , HOFMANN MAXIMILIAN , BELLIN INGO , NALAWADE SAMEER , HAHN KLAUS , KUENKEL ANDREAS , LOOS ROBERT
Abstract: A process for producing expandable pelletized material comprising polylactic acid by: a) melting and incorporating by mixing i) 50-98.9 wt.-% of polylactic acid, ii) 1-49.9 wt.-% of at least one polyester, iii) 0.1-2 wt.-% of a copolymer comprising epoxy groups and based on styrene, acrylate and/or methacrylate, and iv) 1-5 wt.-% of a nucleating agent, b) incorporating by mixing v) 1-7 wt.-% of an organic blowing agent and 0.01-5 wt-% of a co-blowing agent, into the polymer melt at >= 140°C, c) discharging through a die plate with holes
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公开(公告)号：AU2011206716A1
公开(公告)日：2012-08-16
申请号：AU2011206716
申请日：2011-01-06
Applicant: BASF SE
Inventor： FUSSL ANDREAS , SAMPATH BANGARU , HOFMANN MAXIMILIAN , BELLIN INGO , NALAWADE SAMEER , HAHN KLAUS , KUNKEL ANDREAS , LOOS ROBERT
Abstract: The invention relates to a method for producing expandable granulates containing polylactic acid, comprising the following steps: a) melting and mixing the constituents i) between 50 and 99.9 wt. %, relative to the total weight of constituents i) to iii), of polylactic acid, ii) between 0 and 49.9 wt. %, relative to the total weight of constituents i) to iii), of at least one other polymer, iii) between 0.1 and 2 wt. %, relative to the total weight of constituents i) to iii), of a diepoxide or polyepoxide, and iv) between 0 and 10 wt. % of at least one additive, b) mixing v) between 3 and 7 wt. %, relative to the total weight of constituents i) to iv), of an organic blowing agent, into the melted polymer mass, by means of a static or dynamic mixer, at a temperature of at least 40°C, c) discharging the mixture via a nozzle plate with boreholes having a maximum on the nozzle outlet diameter of 1.5 mm, and d) granulating the melted mass containing the blowing agent directly behind the nozzle plate, under water, at a pressure of between 1 and 20 bar. The invention also relates to expandable granulates containing polylactic acid, that can be obtained according to said method, and to special expandable granulates containing polylactic acid, and between 3 and 7 wt. % of an organic blowing agent, preferably n-pentane, and especially preferably iso-pentane. The invention also relates to a preferred method for producing expandable granulates containing polylactic acid and a blowing agent, with a low bulk density.
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Patent Agency Ranking4.发明专利
公开(公告)号：ES2558062T3
公开(公告)日：2016-02-01
申请号：ES11700056
申请日：2011-01-06
Applicant: BASF SE
Inventor： FÜSSL ANDREAS , SAMPATH BANGARU , HOFMANN MAXIMILIAN , BELLIN INGO , NALAWADE SAMEER , HAHN KLAUS , KÜNKEL ANDREAS , LOOS ROBERT
Abstract: Método para la producción de granulados que contienen poliácido láctico que pueden expandirse, que incluye las etapas: a) fusión y mezcla de los componentes i) 50 a 98,9 % en peso, referido al peso total de los componentes i a iii, de poliácido láctico, ii) 1 a 49,9 % en peso, referido al peso total de los componentes i a iii, de por lo menos un poliéster a base de ácidos dicarboxílicos alifáticos y/o aromáticos y compuestos alifáticos que tienen dos grupos hidroxilo, iii) 0,1 a 2 % en peso, referido al peso total de los componentes i a iii, de un copolímero que tiene grupos epóxido a base de estireno, ésteres de ácido acrílico y/o ésteres de ácido metacrílico y iv) 0 a 10 % en peso, referido al peso total de los componentes i a iii, de uno o varios aditivos, b) incorporación mezclando de v) 3 a 7 % en peso, referido al peso total de los componentes i a iv, de un agente propelente orgánico en el fundido de polímero por medio de un mezclador estático o dinámico a una temperatura de por lo menos 140°C, c) descarga a través de una placa de toberas con perforaciones, cuyo diámetro a la salida de la tobera es de máximo 1,5 mm y d) producción de gránulos del fundido que tiene agente propelente directamente delante de la placa de toberas, bajo agua a una presión en el rango de 1 a 20 bar.
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公开(公告)号：AU2011206716B2
公开(公告)日：2014-01-30
申请号：AU2011206716
申请日：2011-01-06
Applicant: BASF SE
Inventor： FUBL ANDREAS , SAMPATH BANGARU , HOFMANN MAXIMILIAN , BELLIN INGO , NALAWADE SAMEER , HAHN KLAUS , KUNKEL ANDREAS , LOOS ROBERT
Abstract: The invention relates to a method for producing expandable granulates containing polylactic acid, comprising the following steps: a) melting and mixing the constituents i) between 50 and 99.9 wt. %, relative to the total weight of constituents i) to iii), of polylactic acid, ii) between 0 and 49.9 wt. %, relative to the total weight of constituents i) to iii), of at least one other polymer, iii) between 0.1 and 2 wt. %, relative to the total weight of constituents i) to iii), of a diepoxide or polyepoxide, and iv) between 0 and 10 wt. % of at least one additive, b) mixing v) between 3 and 7 wt. %, relative to the total weight of constituents i) to iv), of an organic blowing agent, into the melted polymer mass, by means of a static or dynamic mixer, at a temperature of at least 40°C, c) discharging the mixture via a nozzle plate with boreholes having a maximum on the nozzle outlet diameter of 1.5 mm, and d) granulating the melted mass containing the blowing agent directly behind the nozzle plate, under water, at a pressure of between 1 and 20 bar. The invention also relates to expandable granulates containing polylactic acid, that can be obtained according to said method, and to special expandable granulates containing polylactic acid, and between 3 and 7 wt. % of an organic blowing agent, preferably n-pentane, and especially preferably iso-pentane. The invention also relates to a preferred method for producing expandable granulates containing polylactic acid and a blowing agent, with a low bulk density.
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公开(公告)号：CA2787222A1
公开(公告)日：2011-07-21
申请号：CA2787222
申请日：2011-01-06
Applicant: BASF SE
Inventor： FUESSL ANDREAS , SAMPATH BANGARU , HOFMANN MAXIMILIAN , BELLIN INGO , NALAWADE SAMEER , HAHN KLAUS , KUENKEL ANDREAS , LOOS ROBERT
Abstract: The invention relates to a method for producing expandable granulates containing polylactic acid, comprising the following steps: a) melting and mixing the constituents i) between 50 and 99.9 wt. %, relative to the total weight of constituents i) to iii), of polylactic acid, ii) between 0 and 49.9 wt. %, relative to the total weight of constituents i) to iii), of at least one other polymer, iii) between 0.1 and 2 wt. %, relative to the total weight of constituents i) to iii), of a diepoxide or polyepoxide, and iv) between 0 and 10 wt. % of at least one additive, b) mixing v) between 3 and 7 wt. %, relative to the total weight of constituents i) to iv), of an organic blowing agent, into the melted polymer mass, by means of a static or dynamic mixer, at a temperature of at least 40°C, c) discharging the mixture via a nozzle plate with boreholes having a maximum on the nozzle outlet diameter of 1.5 mm, and d) granulating the melted mass containing the blowing agent directly behind the nozzle plate, under water, at a pressure of between 1 and 20 bar. The invention also relates to expandable granulates containing polylactic acid, that can be obtained according to said method, and to special expandable granulates containing polylactic acid, and between 3 and 7 wt. % of an organic blowing agent, preferably n-pentane, and especially preferably iso-pentane. The invention also relates to a preferred method for producing expandable granulates containing polylactic acid and a blowing agent, with a low bulk density.
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公开(公告)号：PL2628762T3
公开(公告)日：2019-09-30
申请号：PL13155900
申请日：2013-02-20
Applicant: BASF SE
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公开(公告)号：ES2581309T3
公开(公告)日：2016-09-05
申请号：ES13163665
申请日：2011-01-06
Applicant: BASF SE
Inventor： FÜSSL ANDREAS , SAMPATH BANGARU DHARMAPURI SRIRAMULU , HOFMANN MAXIMILIAN , BELLIN INGO , NALAWADE SAMEER , HAHN KLAUS , KÜNKEL ANDREAS , LOOS ROBERT
Abstract: Método para producir granulados expandibles que contienen poli(ácido láctico), el cual comprende las etapas de: a) fundir e incorporar en mezcla los componentes i) 50 a 99,9 % en peso, respecto del peso total de los componentes i a iii, de poli(ácido láctico), ii) 0 a 49,9 % en peso, respecto del peso total de los componentes i a iii, de uno o de varios otros polímeros iii) 0,1 a 2 % en peso, respecto del peso total de los componentes i a iii, de un diepóxido o poliepóxido y iv) 0,1 a 5 % en peso, respecto del peso total de los componentes i y iii, de un agente de nucleación, b) incorporar en mezcla v) 1 a 7 % en peso, respecto del peso total de los componentes i a iv, de un propelente orgánico y vi) 0,01 a 5 % en peso de un co-propelentes, que se selecciona del grupo de nitrógeno, dióxido de carbono, argón, helio o mezclas de los mismos, al polímero fundido por medio de un mezclador estático o dinámico a una temperatura de al menos 140 °C, c) descargar a través de una placa de toberas con perforaciones, cuyo diámetro a la salida de la tobera es de máximo 1,5 mm, y d) granular el material fundido que contiene propelente directamente después de la placa de toberas a una presión en el intervalo de 1 a 20 bar.
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