公开(公告)号：JP2009102348A

公开(公告)日：2009-05-14

申请号：JP2008314160

申请日：2008-12-10

Applicant: Basf Se ,  ビーエーエスエフ ソシエタス・ヨーロピアBasf Se

Inventor： FRAUENKRON MATTHIAS ,  STEIN BERND

IPC: C07D487/08 ,  B01J29/40 ,  C07B61/00

CPC classification number: C07D487/08 ,  Y02P20/582

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing triethylenediamine (TEDA) by a reaction of ethylenediamine (EDA) in the presence of a zeolite catalyst giving high yield, high selectivity, high effective catalyst life, low formation of unavoidable piperazine, high purity, high color stability and high odor quality. SOLUTION: The zeolite catalyst contains one or more metals M having an oxidation state IV as oxides, and has a molar ratio SiO 2 /MO 2 of >10:1, for M = the metal of oxidation state IV or two or more metals in the oxidation state IV, and the reaction temperature is 250 to 500°C. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 待解决的问题：提供一种通过乙二胺（EDA）在沸石催化剂存在下反应生产三亚乙基二胺（TEDA）的方法，得到高产率，高选择性，高有效催化剂寿命，低不可避免的哌嗪形成 ，纯度高，颜色稳定性高，气味高。 解决方案：沸石催化剂含有一种或多种氧化态Ⅳ作为氧化物的金属M，其摩尔比SiO 2 / MO 2 > 10： 1，对于M =氧化态Ⅳ的金属或氧化态Ⅳ中的两种或更多种金属，反应温度为250-500℃。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2009102347A

公开(公告)日：2009-05-14

申请号：JP2008314159

申请日：2008-12-10

Applicant: Basf Se ,  ビーエーエスエフ ソシエタス・ヨーロピアBasf Se

Inventor： FRAUENKRON MATTHIAS ,  STEIN BERND

IPC: C07D487/08 ,  B01J29/89 ,  C07B61/00

CPC classification number: C07D487/08 ,  Y02P20/582

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing triethylenediamine (TEDA) by a reaction of ethylenediamine (EDA) in the presence of a zeolite catalyst giving high yield, high selectivity, high effective catalyst life, low unavoidable formation of piperazine, high purity, high color stability and high odor quality. SOLUTION: The zeolite catalyst contains one or more metals M in an oxidation state III as oxides, and has a molar ratio SiO 2 /M 2 O 3 of >100:1, for M = the metal of oxidation state III or two or more metals in the oxidation state III, and the reaction temperature is 250 to 500°C. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 待解决的问题：提供一种通过乙二胺（EDA）在沸石催化剂存在下的反应生产三亚乙基二胺（TEDA）的方法，得到高产率，高选择性，高有效催化剂寿命，低不可避免地形成哌嗪 ，纯度高，颜色稳定性高，气味高。 解决方案：沸石催化剂含有氧化态III中的一种或多种金属M作为氧化物，并且摩尔比SiO / M 2 O 对于M =氧化态III的金属或氧化态III中的两种或更多种金属，反应温度为250〜500℃，3 为100：1。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：WO2010012672A3

公开(公告)日：2010-07-15

申请号：PCT/EP2009059629

申请日：2009-07-27

Applicant: BASF SE ,  ANDERS JOACHIM-THIERRY ,  STEIN BERND ,  HAUBNER MARTIN ,  MELDER JOHANN-PETER ,  BENISCH CHRISTOPH ,  HADERLEIN GERD

Inventor： ANDERS JOACHIM-THIERRY ,  STEIN BERND ,  HAUBNER MARTIN ,  MELDER JOHANN-PETER ,  BENISCH CHRISTOPH ,  HADERLEIN GERD

IPC: C07C209/50 ,  C07C211/09

CPC classification number: C07C209/50 ,  C07C211/09

Abstract: The invention relates to a method for producing 1,?-diamines by reacting lactams having at least 7 C atoms with hydrogen and ammonia in the presence of a catalyst at temperatures ranging from 20 to 600°C and a pressure ranging from 1 to 500 bar. Said method is characterized in that the catalyst is obtained by reducing a catalyst precursor.

Abstract translation: 本发明涉及一种用于为1的制备方法，？ - 通过具有在催化剂的存在下，在20的温度至600℃和1〜500巴的压力下与氢气和氨的至少7个碳原子的内酰胺的反应的二胺，其特征在于 在于该催化剂是通过还原催化剂前体获得的。

公开(公告)号：IN9263DEN2014A

公开(公告)日：2015-07-10

申请号：IN9263DEN2014

申请日：2014-11-05

Applicant: BASF SE

Inventor： BOU CHEDID ROLAND ,  MELDER JOHANN PETER ,  ABEL ULRICH ,  DOSTALEK ROMAN ,  CHALLAND NINA ,  STEIN BERND ,  JÖDECKE MICHAEL

IPC: C07D295/023 ,  C07C211/10 ,  C07C211/14

Abstract: Method for preparing piperazine of formula I by reacting diethanolamine (DEOA) of formula II with ammonia in the presence of hydrogen and a metal containing supported catalyst. Before the catalyst is reduced with hydrogen the catalytically active mass of the catalyst contains oxygen containing aluminum copper nickel and cobalt compounds and 0.2 to 5.0 wt.% oxygen containing tin compounds calculated as SnO and the reaction is carried out in the liquid phase at an absolute pressure ranging from 160 to 220 bar at a temperature ranging from 180 to 220°C ammonia is used at a molar ratio ranging from 5 to 25 in relation to the DEOA used in the process the method being carried out in the presence of 0.2 to 9.0 wt.% hydrogen relative to the total amount of DEOA and ammonia used in the process.

公开(公告)号：IN5943DEN2014A

公开(公告)日：2015-06-26

申请号：IN5943DEN2014

申请日：2014-07-16

Applicant: BASF SE

Inventor： WIGBERS CHRISTOF WILHELM ,  MELDER JOHANN PETER ,  STEIN BERND

IPC: C07C209/86 ,  C07C209/16 ,  C07C211/08

Abstract: The present application relates to a method for producing secondary amines by amination of excess primary or secondary alcohols with primary amines in the liquid phase in the presence of copper containing catalysts.

公开(公告)号：BRPI0922984A2

公开(公告)日：2016-01-26

申请号：BRPI0922984

申请日：2009-12-10

Applicant: BASF SE

Inventor： STEIN BERND ,  CAUWENBERGE GUNTHER VAN ,  MALDER JOHANN-PETER ,  MOORS JÜRGEN ,  HAHN THILO ,  FREMAU TOM

IPC: C07C213/10 ,  C07C215/12

公开(公告)号：ES2544744T3

公开(公告)日：2015-09-03

申请号：ES03009385

申请日：2001-11-30

Applicant: BASF SE

Inventor： FRAUENKRON MATTHIAS ,  STEIN BERND

IPC: C07D295/023 ,  C07B61/00 ,  C07D487/08

Abstract: Procedimiento para la preparación de trietilendiamina (TEDA) mediante reacción de etilendiamina (EDA) en presencia de un catalizador de zeolita, caracterizado porque el catalizador de zeolita contiene uno o varios metales M en la etapa de oxidación IV como óxidos, el metal M en la etapa de oxidación IV se selecciona del grupo de Ti, Zr, Ge, Hf y Sn o mezclas de los mismos, para M >= metal en la etapa de oxidación IV o M >= dos o más metales en la etapa de oxidación IV presenta una proporción molar de SiO2 / MO2 superior a 10 : 1 y la temperatura de reacción asciende a de 250 ºC a 500 ºC.

公开(公告)号：IN9198DEN2014A

公开(公告)日：2015-07-10

申请号：IN9198DEN2014

申请日：2014-11-03

Applicant: BASF SE

Inventor： BOU CHEDID ROLAND ,  MELDER JOHANN-PETER ,  ABEL ULRICH ,  DOSTALEK ROMAN ,  STEIN BERND

IPC: C07D295/088

Abstract: The invention relates to a method for producing a mono-N-alkyl piperazine of formula (I), where R1 represents Ci to — alkyl or 2-(2-hydroxy-ethoxy) ethyl, by reacting diethanolamine (DEOA) of formula (II) with a primary amine of formula H2N-R1 - (III) in the presence of hydrogen and a supported catalyst containing metal. The catalytically active mass of the catalyst, before reduction of the latter using hydrogen, contains oxygenic Compounds of aluminum, copper, nickel and cobalt and between 0.2 and - 5.0 wt. % oxygenic Compounds of tin, calculated as SnO, and the reaction is carried out in the liquid phase at an absolute pressure ranging from 95 to 145 bar.

公开(公告)号：EA020158B1

公开(公告)日：2014-09-30

申请号：EA201170840

申请日：2009-12-10

Applicant: BASF SE

Inventor： MELDER JOHANN-PETER ,  CAUWENBERGE GUNTHER VAN ,  FREMAU TOM ,  MOORS JUERGEN ,  HAHN THILO ,  STEIN BERND

IPC: C07C213/10 ,  C07C215/12

Abstract: Способполучениячистоготриэтаноламина (ТЭА) посредствомнепрерывногоразделениясмесиэтаноламина, содержащейТЭАи диэтаноламин (ДЭА), дистилляцией, причёмв однойдистилляционнойколонне (ДЭА-колонне) отгоняютДЭА, аполученныйпотокизкуба, содержащийТЭА, подаютв смежнуюколонну (ТЭА-колонну), вкоторойчистыйТЭАизвлекаютв видепотокабоковогодистиллята, причёмвремянахожденияэтаноламиновойсмесив кубеДЭА-колоннысоставляет

公开(公告)号：ES2459299T3

公开(公告)日：2014-05-08

申请号：ES09782817

申请日：2009-09-09

Applicant: BASF SE

Inventor： ERNST MARTIN ,  STEIN BERND ,  MAAS STEFFEN ,  PASTRE JÖRG ,  JOHANN THORSTEN ,  MELDER JOHANN-PETER

IPC: B01J21/04 ,  B01J23/72 ,  B01J35/02 ,  B01J37/00 ,  B01J37/02 ,  B01J37/18 ,  C07C209/16 ,  C07C209/26 ,  C07C211/08 ,  C07C211/10 ,  C07C211/12 ,  C07C211/14 ,  C07C211/35

Abstract: Procedimiento para la producción continua de una amina mediante reacción de un alcohol primario o secundario con función OH alifática, de un aldehído y/o de una cetona con hidrógeno y un compuesto de nitrógeno, seleccionado del grupo de amoniaco, aminas primarias y secundarias, a una temperatura en el intervalo de 60 a 300 °C en presencia de un catalizador que contiene óxido de aluminio y de cobre, caracterizado por que la reacción tiene lugar en la fase gaseosa y la masa catalíticamente activa del catalizador antes de su reducción con hidrógeno contiene del 20 al 75 % en peso de óxido de aluminio, del 20 al 75 % en peso de compuestos de cobre que contienen oxígeno, calculado como CuO, del 0 al 2 % en peso de compuestos de sodio que contienen oxígeno, calculado como Na2O, y menos del 1 % en peso de compuestos de níquel que contienen oxígeno, calculado como NiO, y el cuerpo moldeado de catalizador presenta una forma de comprimido, con un diámetro en el intervalo de 1,1 a 3,5 mm y una altura en el intervalo de 1,1 a 3,5 mm.