METHOD FOR PRODUCING N,N-SUBSTITUTED-3-AMINOPROPAN-1-OLS
    1.
    发明申请
    METHOD FOR PRODUCING N,N-SUBSTITUTED-3-AMINOPROPAN-1-OLS 审中-公开
    用于生产N,N-二取代-3-氨基-1- OLAND

    公开(公告)号:WO2010052181A3

    公开(公告)日:2010-09-30

    申请号:PCT/EP2009064438

    申请日:2009-11-02

    Abstract: The present invention relates to a method for producing N,N-substituted-3-aminopropan-1-ols by a) converting secondary amine with acrolein at a temperature of (-50) to 100°C and a pressure of 0.01 to 300 bar, and b) converting the reaction mixture obtained in step a) with hydrogen and ammonia in the presence of a hydrogenation catalyst at a pressure of 1 to 400 bar, characterized in that in step a) the molar ratio of secondary amine to acrolein is 1:1 or more and the temperature in step b) is in the range of (-50) to 70°C. In a preferred embodiment, an acrolein that was obtained from glycerine based on renewable raw materials is used. The invention further relates to the use of an N,N-dimethyl-3-aminopropan-1-ol (DMAPOL) based on renewable raw materials as a catalyst for producing polyurethane, as a scrubbing liquid in gas scrubbing, in the field of electronics chemicals and electroplating, as a feed material in organic synthesis, and as an intermediate product in the production of pharmaceuticals and plant protection agents.

    Abstract translation: 本发明涉及一种方法,用于制备的N,N-取代的3-氨基丙-1-醇通过a)在(-50的温度下与丙烯醛仲胺的反应)至100℃和0.01的压力 至300巴,和b))在1至400巴的压力下在步骤a)与氢气和氨在氢化催化剂的存在下反应混合物中得到的产物,其特征在于,在阶段的仲胺为丙烯醛1的摩尔比反应: 1以上且在步骤b的范围为(-50)至70℃的温度) 在一个优选的实施方案中,丙烯醛被用于已经从甘油基于可再生资源获得的。 此外,本发明涉及使用一个N,基于可再生原料的N-二甲基-3-氨基丙烷-1-醇(DMAPOL)的,作为用于聚氨酯生产的催化剂,如在气体洗涤器中的洗涤液,在电子化学品和电镀领域中,如在起始原料 有机合成并作为医药和农药的制造中间体。

    HYDROGENATING CATALYSTS, PRODUCTION AND USE THEREOF
    3.
    发明申请
    HYDROGENATING CATALYSTS, PRODUCTION AND USE THEREOF 审中-公开
    加氢催化剂,生产和使用

    公开(公告)号:WO2010089266A3

    公开(公告)日:2010-12-23

    申请号:PCT/EP2010051143

    申请日:2010-02-01

    Abstract: The invention relates to a method for improving the catalytic properties of a catalyst that exists in the form of a structured monolith and comprises one or more elements selected from the group comprising cobalt, nickel and copper, wherein the catalyst is brought into contact with one or more base compounds selected from the group of alkali, earth alkali and rare earth metals. The invention further relates to a method for hydrogenating compounds comprising at least one unsaturated carbon-carbon, carbon-nitrogen or carbon-oxygen compound, in the presence of a catalyst comprising one or more elements selected from the group comprising cobalt, nickel and copper, wherein the catalyst exists in the form of a structured monolith, characterized in that the catalyst is brought into contact with one or more base compounds selected from the group of alkali, earth alkali and rare earth metals. In addition, the invention relates to the use of a base compound selected from the group of alkali, earth alkali and rare earth metals for improving the catalytic properties of a catalyst, comprising copper and/or cobalt and/or nickel, wherein the catalyst exists in the form of a structured monolith.

    Abstract translation: 本发明涉及一种用于改善的催化剂,其存在于结构化的整料和或多种元素的选自由钴,镍的含有基团和铜中选择的形式的催化性质,其中与所述催化剂的一种或多种基本 选自碱金属,碱土金属和稀土金属的选择的化合物所接触。 本发明还涉及一种方法,用于包含在催化剂的存在下对含至少一个不饱和碳 - 碳,碳 - 氮或碳 - 氧键的化合物的氢化的组中选择的一种或多种元素自由钴,镍 和铜,其中,所述催化剂是在结构化的单块形式,其特征在于,所述催化剂与选自碱金属,碱土和在接触稀土金属中的一种或多种碱性化合物接触。 此外,本发明是使用选自碱金属,碱土金属和稀土金属中选出的碱性化合物,以提高催化剂的催化性能而言,包含铜和/或钴和/或镍,其特征在于,以结构化的形式的催化剂 整料是存在的。

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