公开(公告)号：WO2009124947A1

公开(公告)日：2009-10-15

申请号：PCT/EP2009/054170

申请日：2009-04-07

Applicant: BASF SE ,  DOBNER, Cornelia Katharina ,  DIETRICH, Ulf ,  MACKEWITZ, Thomas ,  STORCK, Sebastian ,  WILMER, Hagen ,  ROSOWSKI, Frank ,  TENTEN, Andreas

Inventor： DOBNER, Cornelia Katharina ,  DIETRICH, Ulf ,  MACKEWITZ, Thomas ,  STORCK, Sebastian ,  WILMER, Hagen ,  ROSOWSKI, Frank ,  TENTEN, Andreas

IPC: C07C51/265 ,  C07C63/16 ,  C07C63/24 ,  C07C63/26 ,  C07C63/06 ,  C07C63/40 ,  B01J23/66

CPC classification number: C07C51/265 ,  C07C63/16

Abstract: Beschrieben wird ein Verfahren zum Anfahren eines Gasphasenoxidationsreaktors, der ein Bett eines ersten Katalysators, dessen aktive Masse eine katalytisch aktive Silber-Vanadiumoxid-Bronze enthält, und wenigstens ein Bett eines zweiten Katalysators umfasst, dessen katalytisch aktive Masse Vanadiumpentoxid und Titandioxid enthält, und der mittels eines Wärmetransfermediums temperierbar ist. Im Betriebszustand leitet man einen Gasstrom, der eine Beladung C op eines Kohlenwasserstoffs und molekularen Sauerstoff umfasst, bei einer Temperatur T op des Wärmetransfermediums über das Bett des ersten und zweiten Katalysators durch den Reaktor. Zum Anfahren leitet man a) einen Gasstrom mit einer Anfangsbeladung C o , die kleiner ist als C op , und bei einer Anfangstemperatur T o des Wärmetransfermediums, die kleiner ist als T op , durch den Reaktor und bringt b) die Temperatur des Wärmetransfermediums auf T op und die Beladung des Gasstroms auf C op . Das Verfahren vereint eine kurze Anfahrzeit ohne Überschreiten von Emissions- bzw. Qualitätsvorgaben, lange Katalysatorlebensdauer, hohe Ausbeute und geringe Bildung von Nebenprodukten.

Abstract translation: 描述了一种用于启动一气相氧化反应器，其包括第一催化剂，其活性物质包含具有催化活性的银钒氧化物青铜床的过程中，和第二催化剂，其催化活性组合物中的至少一种床包括五氧化二钒和二氧化钛，和手段 传热介质可以被回火。 在操作状态下使包含一个装载警察的烃和分子氧的气体流，在一个温度Top通过反应器在第一和第二催化剂的床中的热传递介质的。 用于开始使具有有限，这是小于警察，并在初始温度To的传热介质，它是顶部的较小的，通过反应器，并带来b）该热传递介质的温度在顶部和装载的初始加载a）气体流 气流警察，该方法结合了短的启动时间不超过排放或质量规范，催化剂寿命长，高产率和低副产物形成。

公开(公告)号：EP4494197A1

公开(公告)日：2025-01-22

申请号：EP23710345.2

申请日：2023-03-10

Applicant: BASF SE

Inventor： WEBER, Martin ,  HENSCHEL, Carsten ,  STORCK, Sebastian ,  HENNENBERGER, Florian

IPC: H01M8/0213 ,  H01M8/0221 ,  H01M8/0226 ,  C25B9/60 ,  C25B9/75 ,  C08G65/40 ,  C08G75/23 ,  C08K7/14 ,  C08L81/06

公开(公告)号：EP1654211B1

公开(公告)日：2013-05-15

申请号：EP04763465.4

申请日：2004-07-23

Applicant: BASF SE

Inventor： NETO, Samuel ,  HIBST, Hartmut ,  ROSOWSKI, Frank ,  STORCK, Sebastian

IPC: C07C51/265 ,  C07C51/31 ,  B01J23/22 ,  B01J23/50

CPC classification number: C07C51/313 ,  B01J23/002 ,  B01J23/682 ,  B01J23/688 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0045 ,  B01J37/0223 ,  B01J2523/00 ,  C01G31/006 ,  C07C51/265 ,  C07C63/16 ,  B01J2523/18 ,  B01J2523/3712 ,  B01J2523/55 ,  B01J2523/72 ,  B01J2523/47

公开(公告)号：EP1735093B1

公开(公告)日：2012-08-01

申请号：EP05728204.8

申请日：2005-03-24

Applicant: BASF SE

Inventor： NETO, Samuel ,  ROSOWSKI, Frank ,  STORCK, Sebastian ,  BAUER, Stefan

IPC: B01J23/68 ,  B01J21/06 ,  B01J37/02 ,  B01J37/04 ,  C07C51/265

CPC classification number: B01J23/682 ,  B01J23/002 ,  B01J35/0006 ,  B01J37/0045 ,  B01J37/0215 ,  B01J37/0219 ,  B01J37/0223 ,  B01J2523/00 ,  C07C51/265 ,  C07C63/16 ,  B01J2523/15 ,  B01J2523/47 ,  B01J2523/55 ,  B01J2523/18

Abstract: The invention relates to a catalyst having a catalytically active substance, which contains a phase A and a phase B in the form of three-dimensionally extended delimited areas, phase A being a silver-vanadium bronze and phase B being a mixed oxide phase based on titanium dioxide and vanadium pentoxide. The catalyst is used for producing aldehydes, carboxylic acids and/or carboxylic acid anhydrides from aromatic or heteroaromatic hydrocarbons by gas-phase oxidation.

公开(公告)号：EP2012918A1

公开(公告)日：2009-01-14

申请号：EP07727844.8

申请日：2007-04-05

Applicant: BASF SE

Inventor： WILMER, Hagen ,  DOBNER, Cornelia ,  ROSOWSKI, Frank ,  ZÜHLKE, Jürgen ,  STORCK, Sebastian ,  ALLMANN, Hans-Martin ,  LAUTENSACK, Thomas

IPC: B01J23/22 ,  B01J27/198 ,  C07C51/265 ,  C07C51/31 ,  C07D307/89

CPC classification number: B01J23/002 ,  B01J23/22 ,  B01J27/198 ,  B01J35/0006 ,  B01J35/1004 ,  B01J2523/00 ,  C07C51/265 ,  C07C51/313 ,  C07D307/89 ,  C07C63/16 ,  B01J2523/15 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/53

Abstract: The present invention relates to a catalyst system for preparing carboxylic acids and/or carboxylic anhydrides, which has at least three catalyst layers arranged one on top of another in the reaction tube, with the proviso that the least active catalyst layer is preceded upstream by at least one more active catalyst layer in flow direction. The invention further relates to a process for gas phase oxidation in which a gaseous stream which comprises a hydrocarbon and molecular oxygen is passed through a plurality of catalyst layers, the least active catalyst layer being preceded upstream in flow direction by a more active catalyst layer.

公开(公告)号：EP1670741B1

公开(公告)日：2010-03-03

申请号：EP04765590.7

申请日：2004-09-24

Applicant: BASF SE

Inventor： STORCK, Sebastian ,  ZÜHLKE, Jürgen ,  NETO, Samuel ,  ROSOWSKI, Frank ,  RUMMEL, Wolfgang

IPC: C07C51/265 ,  C07C51/31 ,  B01J23/22 ,  B01J27/198 ,  B01J37/02

CPC classification number: C07C51/313 ,  B01J23/002 ,  B01J23/22 ,  B01J27/198 ,  B01J35/023 ,  B01J37/0219 ,  B01J37/0221 ,  B01J2523/00 ,  C07C51/265 ,  C07C63/16 ,  B01J2523/15 ,  B01J2523/47 ,  B01J2523/53 ,  B01J2523/55

Abstract: A method for production of a catalyst for gas phase oxidations is disclosed, whereby a suspension of Ti02 and V205 particles is applied to a fluidised inert support, wherein at least 90 vol. % of the V205 particles have a diameter of 20 μm or less and at least 95 vol. % of the V205 particles have a diameter of 30 μm or less. The defined particle size distribution of the V205 permits a high coating efficiency.

公开(公告)号：EP1487575B2

公开(公告)日：2009-04-01

申请号：EP03708212.0

申请日：2003-03-12

Applicant: BASF SE

Inventor： WEIGUNY, Jens ,  STORCK, Sebastian ,  DUDA, Mark ,  DOBNER, Cornelia ,  FELDER, Raimund

IPC: B01J27/198

CPC classification number: B01J8/10 ,  B01J8/067 ,  B01J19/22 ,  B01J27/198 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1014 ,  B01J35/1038 ,  B01J37/0009 ,  B01J37/08 ,  B01J37/14 ,  B01J37/18 ,  B01J2208/00849 ,  B01J2208/00876 ,  B01J2219/182 ,  C07C51/215 ,  C07C51/252 ,  C07C57/145

Abstract: Disclosed is a method for producing a catalyst containing vanadium, phosphorus, and oxygen, which is used for oxidizing the gas phase of a hydrocarbon having at least four carbon atoms to maleic anhydride. According to the inventive method, a corresponding catalyst precursor which contains vanadium, phosphorus, and oxygen and is provided with particles having an average diameter of at least 2 mm is converted into a catalytically active form by means of calcination, and a flow of the catalyst precursor is transported on a conveyor belt across at least one calcination area over a distance ln at an essentially steady speed in order to be calcinated. The variation over time of the gas temperature in relation to the set point value amounts to ≤ 5 °C at each position in the area of the flow of the catalyst precursor, which lies within the second half ln/2 of the calcination area, while the local difference in the gas temperature between any positions in the area of the flow of the catalyst precursor, which is located within the second half ln/2 of the calcination area, amounts to ≤ 5 °C.

公开(公告)号：EP1901843A1

公开(公告)日：2008-03-26

申请号：EP06792592.5

申请日：2006-06-30

Applicant: BASF SE

Inventor： NETO, Samuel ,  ROSOWSKI, Frank ,  STORCK, Sebastian ,  ZÜHLKE, Jürgen ,  ALLMANN, Hans-Martin ,  LAUTENSACK, Thomas ,  STEEG, Rainer

IPC: B01J23/00 ,  C07C51/21 ,  C07D307/89 ,  C07C51/265 ,  C07C51/31

CPC classification number: C07D307/34 ,  B01J23/002 ,  B01J2523/00 ,  C07C51/265 ,  C07C51/313 ,  C07C63/16 ,  B01J2523/15 ,  B01J2523/47 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/824

Abstract: The invention relates to a method for start-up of oxidation catalysts, characterised in that the catalyst is started up at a temperature of 360 °C to 400 °C, with an air supply of 1.0 to 3.5 Nm3/h and a hydrocarbon loading of 20 to 65 g/Nm3 with formation of a hot spot in the first 7 to 20 % of the catalyst bed at a temperature of 390 °C to less than 450 °C.

公开(公告)号：EP1487577B1

公开(公告)日：2009-07-01

申请号：EP03709774.8

申请日：2003-03-12

Applicant: BASF SE

Inventor： WEIGUNY, Jens ,  STORCK, Sebastian ,  DUDA, Mark ,  DOBNER, Cornelia

IPC: B01J27/198 ,  C07C51/215 ,  C07C51/25

CPC classification number: C07C51/252 ,  B01J23/002 ,  B01J27/198 ,  B01J35/002 ,  B01J35/1014 ,  B01J37/0018 ,  B01J37/031 ,  B01J2523/00 ,  C07C51/215 ,  C07C57/145 ,  B01J2523/51 ,  B01J2523/55

Abstract: The invention relates to a method for producing a catalyst-precursor containing vanadium, phosphorous and oxygen for the production of maleic acid anhydride by means of heterogeneous catalytic gas phase oxidation of a hydrocarbon having at least four hydrocarbon atoms, wherein (a) vanadium pentoxide is reacted with 102 - 110 % phosphorous acid in a temperature range of between 80 - 160 °C in the presence of a primary or secondary, non-cyclic or cyclic, non-branched or branched, saturated alcohol having 3 - 6 carbon atoms; (b) the formed deposit is isolated; (c) a content of organic carbon of = 1.1 wt. % is adjusted in the insulated deposit by tempering in a temperature range of between 250 - 350 °C, whereby the tempered product produces a powder-x ray diffraction diagram after the addition of 3.0 wt. % graphite, said diagram having a peak height ratio of the peak in the 2?-range of = 0,1 of a possibly existing pyrophosphate phase at 28.5° to the peak at 26.6° emerging from the graphite and, d) the tempered product obtained from step c) is formed to obtain particles having an average diameter of at least 2mm. The invention also relates to a catalyst-precursor obtained according to said method for producing a catalyst from the catalyst-precursor, a catalyst which can be obtained according to said method, in addition to a method for producing maleic acid anhydride on said catalyst.

公开(公告)号：EP2035138A1

公开(公告)日：2009-03-18

申请号：EP07729957.6

申请日：2007-06-06

Applicant: BASF SE

Inventor： WILMER, Hagen ,  DOBNER, Cornelia ,  EINFELD, Tina ,  STORCK, Sebastian ,  ZÜHLKE, Jürgen ,  ROSOWSKI, Frank

IPC: B01J23/22 ,  B01J27/198 ,  C07C51/265 ,  C07C51/31 ,  C07D307/89

CPC classification number: B01J23/002 ,  B01J23/22 ,  B01J27/198 ,  B01J35/0006 ,  B01J2523/00 ,  C07C51/265 ,  C07C51/313 ,  C07D307/89 ,  C07C63/16 ,  B01J2523/15 ,  B01J2523/47 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/51

Abstract: The invention relates to a catalyst system for producing carboxylic acids and/or carboxylic acid anhydrides, said system having at least three catalysts layers that are situated one above the other in the reaction tube, with the proviso that the active mass fraction, in relation to the total mass of the catalyst, of one or more of the central catalyst layers is lower than the active mass fraction of one or more of the upper catalyst layers lying on the gas inlet side and is lower than the active mass fraction of one or more of the lower catalyst layers lying on the gas outlet side. The invention also relates to a method for gas phase oxidation using said catalyst system.