公开(公告)号：DE502004000376D1

公开(公告)日：2006-05-11

申请号：DE502004000376

申请日：2004-10-19

Applicant: DEGUSSA

Inventor： KORTH DR ,  ALBERT DR ,  KIEFER INGO

IPC: C07F7/18

Abstract: Production of mercaptoorganyl alkoxysilanes comprises reacting an alkali metal hydrogen sulfide with a mixture of haloorganyl alkoxysilane and haloorganyl halosilane in an alcohol under pressure in a sealed vessel in the absence of oxygen.

公开(公告)号：DE502004000168D1

公开(公告)日：2006-01-12

申请号：DE502004000168

申请日：2004-06-09

Applicant: DEGUSSA

Inventor： KORTH DR ,  ALBERT DR ,  PIETER DR ,  KLOCKMANN DR ,  HASSE ANDRE ,  DESCHLER DR ,  WITZSCHE SUSANN ,  KIEFER INGO

IPC: C07B61/00 ,  C07F7/18 ,  C08G77/28 ,  C08K5/5419 ,  C08K5/548 ,  C08L21/00

Abstract: New organosilicon compounds (I) are mercapto-, thiocyanato- and mono- and polysulfanyl-(ar)alkyl- and (alk)aryl-silanes, in which (each) silicon atom has 1-3 long-chain alk(en)oxy-, aryloxy, aralkoxy or tri(alk(en)yl, aralkyl or aryl)-siloxy substituents and 0-2 alkyl substituents, and mixtures of these. New organosilicon compounds are mercapto-, thiocyanato- and mono- and polysulfanyl-(ar)alkyl- and (alk)aryl-silanes of formula (I) and mixtures are claimed. [Image] R : R'O or 1-12 C alkyl; R' : 12-24 C monovalent alkyl or alkenyl, aryl, aralkyl or R''' 3Si; R''' : 1-30 C alkyl or alkenyl, aralkyl or aryl; R'' : (un)saturated aliphatic, aromatic or mixed aliphatic/aromatic divalent 1-30 C hydrocarbon group; and X : SH or SCN with n = 1 and m = 1, or S with n = 2 and m = 1-14. Independent claims are also included for the following: (1) preparation of (I); (2) rubber mixes containing rubber, filler, optionally other ancillaries and also compound(s) (I).

公开(公告)号：DE50200179D1

公开(公告)日：2004-02-05

申请号：DE50200179

申请日：2002-01-11

Applicant: DEGUSSA

Inventor： BATZ-SOHN DR ,  PANSTER DR ,  MICHEL RUDOLF ,  ALBERT DR ,  VRYENS DR

IPC: C07B61/00 ,  C07F7/08 ,  C07F7/12 ,  C07F7/14

Abstract: Production of 3-functionalized propyl silanes (I) by reacting allylic compounds (II) with silanes (III) at 0-200 degrees C and 0.8-25 bar in the presence of a platinum catalyst comprises using a (III):(II) molar ratio of 3-100. Production of 3-functionalized propyl silanes (I) by reacting allylic compounds of formula (II) with silanes of formula (III) at 0-200 degrees C and 0.8-25 bar in the presence of a platinum catalyst comprises using a (III):(II) molar ratio of 3-100:1 H2C=CH-CH2X (II) R R R SiH (III) X = Cl, Br, I, F, CN, SCN, SH, SR, OH, NRR or OR; R, R = 1-6C alkyl or 3-7C alkyl (sic); and R -R = H, halogen, 1-6C alkyl, 1-6C haloalkyl, 3-6C allyl (sic), 1-4C alkoxy, phenyl, aryl or aralkyl.

公开(公告)号：DE59509204D1

公开(公告)日：2001-05-23

申请号：DE59509204

申请日：1995-08-24

Applicant: DEGUSSA

Inventor： STANDKE DR ,  ALBERT DR ,  HORN DR ,  KOETZSCH DR ,  KROPFGANS DR ,  MONKIEWICZ DR ,  SEILER DR ,  SREBNY DR

IPC: B01J27/122 ,  C07B61/00 ,  C07F7/02 ,  C07F7/04

Abstract: In the prepn of hydridoalkoxysilanes of formula (I) by direct reaction of metallic Si with alcohols with addn of suitable catalysts contg Cu, reaction is carried out with finely-divided Si and alcohol (mixt) in a heat carrier oil of opt substd tritoluene and/or tetratoluene at 100-350 degrees C. HnSi(O(CH2)mCH3)4-n (I) n = 1, 2 or 3; m = 0, 1 or 2.