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公开(公告)号:JPH067677A
公开(公告)日:1994-01-18
申请号:JP9283093
申请日:1993-04-20
Applicant: DEGUSSA
Inventor: LEYRER JUERGEN , LOX EGBERT , ENGLER BERND , DOMESLE RAINER
IPC: F01N3/10 , B01D53/94 , B01J23/64 , B01J23/648 , B01J29/04 , B01J35/04 , B01J37/00 , B01J37/02 , F02B3/06 , B01D53/36
Abstract: PURPOSE: To obtain a catalyst having a high conversion rate for hydrocarbons and carbon monoxide by using doped platinum, etc., as an active component in a monolithic catalyst element with throughflow passages of ceramic etc., coated with an activity-promoting dispersion coating. CONSTITUTION: A fine particulate metal oxide is surface-modified Al oxide, titanium oxide, silicon oxide, zeolite or a mixture thereof which is obtained by mixing the fine particulate metal oxide or the mixture thereof into an alcoholic soln. of a precursor for titanium oxide and/or silicon oxide with stirring, removing the alcoholic solvent with stirring continuously, drying the residual solid at a elevated temp., and after pulverization, calcining titanium dioxide or silicon dioxide at 300-600 deg.C for 0.5-4 hours while decomposing the precursor for titanium oxide and/or silicon oxide. Platinum, Pd, Rh and/or Ir doped with V is (are), included as (an) active component(s) on the carrier.
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公开(公告)号:ES2010494A4
公开(公告)日:1989-11-16
申请号:ES89100695
申请日:1989-01-17
Applicant: DEGUSSA-HULS AG , DEGUSSA
Inventor: ENGLER BERND , KOBERSTEIN EDGAR , SCHUBERT PETER , DOMESLE RAINER
Abstract: LA INVENCION EN CUANTO A UN CATALIZADOR DE OXIDO DE ALUMINIO ACTIVO CON ADICIONES CEO2, ZRO2 Y FEO3 Y/O NIO COMO PORTADOR Y UNA FASE ACTIVA DE PLATINO, PALADIO Y/O RODIO Y UN METAL INNOBLE, QUE ESTA OBTENIDA A TRAVES DE IMPREGNAR AL PORTADOR QUE CONTIENE LAS ADICIONES, CON DISOLUCIONES DE SALES DE LOS METALES PARA LA FASE ACTIVA, CON LO CUAL EL METAL INNOBLE ESTA DE LA FASE ACTIVA CER, SECAR Y CALENTAR A 250 HASTA 650 C. EL CATALIZADOR SE PUEDE TAMBIEN UTILIZAR PARA LA OXIDACION Y/O REDUCCION DE LOS GASES PERDIDOS DE MOTORES DE COMBUSTION INTERNA.
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公开(公告)号:CA2285825C
公开(公告)日:2009-01-20
申请号:CA2285825
申请日:1999-10-12
Applicant: DEGUSSA
Inventor: STREHLAU WOLFGANG , GOBEL ULRICH , DOMESLE RAINER
IPC: B01J20/04 , B01D53/56 , B01D53/94 , B01J23/58 , B01J23/63 , B01J27/053 , B01J27/055 , B01J37/02 , B01J37/08
Abstract: The invention relates to a nitrogen oxide storage catalyst which contains at least one catalyst material and at least one nitrogen oxide storage component from the group of alkali and alkaline earth metals. The nitrogen oxide storage catalyst is characterised in that the nitrogen oxide storage component, after completing catalyst preparation, is present as finely divided barium sulfate, strontium sulfate or as a mixture or mixed crystals of the two sulfates or as their complete or incomplete decomposition product with an average particle size of less than 1 m. Barium sulfate and/or strontium sulfate act as feed materials for the active storage component barium oxide in the storage catalyst according to the invention. As a result of the reductive exhaust gas compositions occurring under normal driving conditions barium sulfate and strontium sulfate decompose to compounds which are able to store nitrogen oxides. This more or less compensates for the loss of active storage components which occurs due to ageing. There is also the possibility of decomposing barium sulfate and/or strontium sulfate during production by means of reductive calcination in order to obtain a high initial loading of the catalyst with storage compounds. In this case the sulfates mentioned are used as auxiliary agents in order to introduce the highest possible concentrations of storage compounds into the storage catalyst.
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4.
公开(公告)号:CA2280597C
公开(公告)日:2008-06-03
申请号:CA2280597
申请日:1999-08-19
Applicant: DEGUSSA
Inventor: KRAMPE WILLI , PIROTH JOSEF , DOMESLE RAINER , FOERSTER MARTIN , SCHLACHTER ULRICH
Abstract: The invention relates to a process for coating the flow channels in a monolithic, cylindrically shaped catalyst carrier with a coating dispersion, wherein the carrier has two end faces which are connected to each other by flow channels arranged parallel to the axis of the cylinder, by vertically aligning the axis of the cylindrical carrier, placing a predetermined amount of coating dispersion from a storage container on the upper end face of the carrier and drawing the dispersion through the flow channels under suction, removing excess coating dispersion from the flow channels by emptying the flow channels under suction, returning the excess dispersion to the storage container and fixing the dispersion coating by calcination. The process is characterised in that the coating dispersion is drawn through the flow channels under suction at a rate of flow of 0.1 to 1 m/s and that after completion of passage under suction the excess coating dispersion is removed from the flow channels by applying a suction impulse from below, wherein the suction air is drawn through the flow channels under suction at a rate of flow between 40 and 1 m/s and the excess coating dispersion discharged with the air stream is separated from the air stream within a time of less than 100 ms after discharge from the catalyst carrier.
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公开(公告)号:DE10024038A1
公开(公告)日:2001-11-22
申请号:DE10024038
申请日:2000-05-13
Applicant: DMC2 DEGUSSA METALS CATALYSTS
Inventor: DOMESLE RAINER , KREUZER THOMAS , LOX EGBERT
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公开(公告)号:ZA200000911B
公开(公告)日:2000-09-13
申请号:ZA200000911
申请日:2000-02-24
Applicant: DEGUSSA
Inventor: DOMESLE RAINER , MUSSMANN LOTHAR , KREUZER THOMAS , GOEBEL ULRICH , LOX EGBERT
IPC: B01D53/94 , B01J23/00 , B01J23/54 , B01J23/58 , B01J23/63 , B01J35/04 , B01J35/10 , B01J37/02 , B01J37/025 , B01J
Abstract: Powdered catalyst material contains aluminum oxide, a basic metal oxide and a precious metal as catalytically active component. Powdered catalyst material is obtained by: (a) preparing, as support material, a powdered aluminum oxide stabilized with basic oxides and having a specific surface area of more than 80 m /g; (b) impregnating the support material with a solution of a precursor compound of alkaline earth or rare earth metals; (c) drying the impregnated support material and calcining at less than 800o C; (d) repeating steps (b) and (c) until the required charge with basic oxides is reached; and (e) re-impregnating the material obtained with a solution of precursor compounds of the catalytically active precious metals; and (f) drying and calcining.
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公开(公告)号:CA2280631A1
公开(公告)日:2000-02-24
申请号:CA2280631
申请日:1999-08-23
Applicant: DEGUSSA
Inventor: STREHLAU WOLFGANG , MUSSMANN LOTHAR , DOMESLE RAINER , GOEBEL ULRICH
IPC: B01D53/86 , B01D53/94 , B01J20/04 , B01J20/30 , B01J23/02 , B01J23/10 , B01J23/58 , B01J23/63 , B01J35/02 , B01J37/03 , F01N3/08 , F02B1/04 , B01D53/56
Abstract: The invention relates to a nitrogen oxide storage material which contains at least one storage component for nitrogen oxides, in the form of an oxide, mixed oxide, carbonate or hydroxide of the alkaline earth metals magnesium, calcium, strontium and barium and the alkali metals potassium and caesium, on a high surface area support material. The storage material is characterised in that the support material is selected from the group comprising doped cerium oxide, cerium/zirconium mixed oxide, calcium titanate, strontium titanate, barium titanate, barium stannate, barium zirconate, magnesium oxide, lanthanum oxide, praseodymium oxide, samarium oxide, neodymium oxide, yttrium oxide, zirconium silicate, yttrium barium cuprate, lead titanate, tin titanate, bismuth titanate, lanthanum cobaltate, lanthanum manganate and barium cuprate, or mixtures thereof.
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8.
公开(公告)号:ZA9905303B
公开(公告)日:2000-02-21
申请号:ZA9905303
申请日:1999-08-19
Applicant: DEGUSSA
Inventor: FOERSTER MARTIN , SCHLACHTER ULRICH , KRAMPE WILLI , PIROTH JOSEF , DOMESLE RAINER
CPC classification number: B01J37/0215
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公开(公告)号:DE19821144A1
公开(公告)日:1999-11-18
申请号:DE19821144
申请日:1998-05-12
Applicant: DEGUSSA
Inventor: FOERSTER MARTIN , GUTSCH ANDREAS , DOMESLE RAINER , KEISLING RALF , STOEHR OLIVER
IPC: B01J2/00 , B01J2/04 , B01J19/08 , B01J19/12 , B01J20/02 , B01J20/30 , B01J32/00 , B01J37/00 , C01B13/34 , C03B19/00 , C04B35/622 , B01D43/00 , B01J6/00 , B01J37/08 , B01J37/02 , C04B35/626
Abstract: A powdered heterogeneous substance is produced by treating a dispersion, suspension or emulsion in a turbulent or laminar burner under specified conditions, feeding the reaction mixture into a tube where it is further treated and then feeding it to a scrubber, separator or filter for further treatment.
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公开(公告)号:ZA992323B
公开(公告)日:1999-09-30
申请号:ZA992323
申请日:1999-03-25
Applicant: DEGUSSA
Inventor: STREHLAU WOLFGANG , GOEBEL ULRICH , DOMESLE RAINER , LOX EGBERT , KREUZER THOMAS
IPC: B01D53/34 , B01D53/50 , B01D53/81 , B01D53/86 , B01D53/94 , B01J20/04 , B01J20/08 , B01J23/42 , F01N3/08 , B01D
Abstract: Storage material comprises magnesium oxide and aluminum oxide as a magnesium aluminate spinel in a mole ratio of 1.1:1. The magnesium oxide present in a stoichiometric excess is homogeneously dispersed in the storage material in a highly dispersed form. An Independent claim is also included for the production of the storage material comprising calcining a magnesium/aluminum hydrotalcite having a magnesium oxide/aluminum oxide mole ratio of 1.1:1 at a temperature of 400-600o C for 1-10 hours.
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