Abstract:
PROBLEM TO BE SOLVED: To provide a silicon/titanium mixed oxide powder containing no dark-colored contaminants and a higher percentage of silicon dioxide or titanium dioxide than that by a conventional technology. SOLUTION: This silicon/titanium mixed oxide powder is manufactured by flame hydrolysis and comprises agglomerate of primary particles comprising an amorphous silicon dioxide, a crystalline titanium dioxide, or a silicon/titanium mixed oxide having an amorphous silicon dioxide part and a crystalline titanium dioxide part, and mainly comprising silicon/titanium mixed oxide primary particles, and the particle has a BET surface area of 20-200 m 2 /g and a titanium dioxide content of more than 10 mass% but less than 70 mass%, and its X-ray diffraction photograph shows a diffraction pattern of rutile-type and anatase-type, and the ratio of the rutile-type to the anatase-type is 2/98-98/2. COPYRIGHT: (C)2005,JPO&NCIPI
Abstract:
PROBLEM TO BE SOLVED: To provide powder overcoming defects characteristic of conventional technologies. SOLUTION: The silicon-titanium-mixed powder is manufactured by flame hydrolysis, where a silicon dioxide/titanium dioxide mass ratio at the surface of a primary particle is larger than that of whole primary particles. COPYRIGHT: (C)2003,JPO
Abstract:
Pyrogenic silicon-titanium mixed oxide powder having a BET surface area of 200 to 400 m2/g, a DBP number/BET surface area ratio of 0.5 to 1.2, a silicon dioxide content of 93.5 to 95.4% by weight and a titanium dioxide content of 4.6 to 6.5% by weight, where the sum of the contents is greater than 99.7% by weight. Dispersion comprising the pyrogenic silicon-titanium mixed oxide powder. Process for preparing a titanium-containing zeolite proceeding from powder or dispersion.
Abstract:
Aluminium oxide powder produced by flame hydrolysis and consisting of aggregates of primary particles, having a BET surface area of from 100 to 250 m /g, a dibutyl phthalate absorption of from 50 to 450 g/100 g of aluminium oxide powder, which powder shows only crystalline primary particles in high-resolution TEM pictures. It is prepared by vaporising aluminium chloride, transferring the vapour by means of a carrier gas to a mixing chamber and, separately therefrom, supplying hydrogen, air (primary air), which may optionally be enriched with oxygen and/or may optionally be pre-heated, to the mixing chamber, then igniting the mixture of aluminium chloride vapour, hydrogen, air in a burner and burning the flame into a reaction chamber that is separated from the surrounding air, subsequently separating the solid material from the gaseous substances and then treating the solid material with steam and optionally with air, the discharge rate of the reaction mixture from the mixing chamber into the reaction chamber being at least 10 m/s, and the lambda value being from 1 to 10 and the gamma value being from 1 to 15. It can be used as an ink-absorbing substance in ink-jet media.
Abstract:
Fumed silicon dioxide powder with a BET surface area of 20 to 35 m2/g, characterized in that a) the number-based median particle diameter is 60 to 150 nm, and b) the proportion of particles with a diameter of 200 nm or more is at most 10%, and c) the proportion of particles with a diameter of up to 60 nm is at most 20%, based in each case on the total number of particles.
Abstract:
High-purity pyrogenically prepared silicon dioxide having metal contents of less than 0.2 µg/g is prepared by reacting a silicon tetrachloride having a metal content of less than 30 ppb by means of flame hydrolysis. The silicon dioxide can be utilised for the manufacture of high-purity glasses by means of the sol-gel process, which show a high-homogenity. It can be used for the production of shaped articles, which can be used as preforms for the optical fiber spinning.
Abstract:
Pyrogenically produced silica powder with a BET surface of 30 to 90 m2/g, a dibutyl phthalate number of at least 80 and a tamped density of no more than 110 g/l. It is produced in that at least one vaporous silicon compound, a gas containing free oxygen and a combustible gas are mixed together in a closed burner and then burnt in a flame in the flame tube of the burner, the solid obtained is separated from the gas mixture and optionally purified, wherein the oxygen content of the gas containing free oxygen is adjusted such that the lambda value is greater than or equal to 1, and the gamma value is between 1.2 and 1.8. It can be used in toner applications.
Abstract:
Pyrogenic silicon dioxide powder with a BET surface area of 30 to 90 m2/g, a DBP index of 80 or less, a mean aggregate area of less than 25000 nm2 and a mean aggregate circumference of less than 1000 nm, wherein at least 70% of the aggregates have a circumference of less than 1300 nm. It is prepared by mixing at least one silicon compound in vapor form, a free-oxygen-containing gas and a combustible gas in a burner of known construction, igniting this gas mixture at the mouth of the burner and burning it in the flame tube of the burner, separating the solid obtained from the gas mixture and optionally purifying, wherein the oxygen content of the free-oxygen-containing gas is adjusted so that the lambda value is greater than or equal to 1, the gamma value is between 1.2 and 1.8, the throughput is between 0.1 and 0.3 kg SiO2/m3 of core gas mixture and the mean normalized rate of flow of gas in the flame tube at the level of the mouth of the burner is at least 5 m/s. The powder can be used as a filler. A dispersion containing the powder according to the invention. The powder can be used as a filler in rubber, silicone rubber and plastics. The dispersion can be used to prepare glass items.
Abstract:
Aluminium oxide doped with a divalent metal oxide, produced by flame hydrolysis and which has no spinell structures or alpha-aluminium detectable in an x-ray diffractogram. It is produced by a pyrogenic process in which, during the flame hydrolysis of aluminium halogenides, an aerosol, which contains an aqueous solution of a divalent metal salt is added to the gas mixture. The doped aluminium oxides can be used in aqueous dispersions for chemical-mechanical polishing.
Abstract:
Flame hydrolytically-produced silicon-titanium mixed oxide powders consisting of aggregates of primary particles are such that (A) the primary particles are predominantly of Si-Ti mixed oxide; and (B) the powder has a BET surface area 20-200 m 2>/g, a TiO 2fraction of 10-70 wt.% and a rutile/anatase X-ray diffraction diagram of rutile/anatase ratio 2 : 98-2 : 98. Flame hydrolytically-produced silicon-titanium mixed oxide powders consisting of aggregates of primary particles are such that: (A) the primary particles are of amorphous silicon dioxide, crystalline titanium dioxide or silicon-titanium mixed oxide with an amorphous SiO 2and crystalline TiO 2fraction so that Si-Ti mixed oxide primary particles predominate; and (B) the powder has a BET surface area 20-200 m 2>/g, a TiO 2fraction of 10-70 wt.% and a rutile/anatase X-ray diffraction diagram of rutile/anatase ratio 2 : 98-2 : 98. An independent claim is also included for preparation of the powders.