-
公开(公告)号:CA1330871C
公开(公告)日:1994-07-26
申请号:CA590063
申请日:1989-02-03
Applicant: DEGUSSA
Inventor: DITTRICH EWALD , MANNER REINHARD , BIRTIGH GERHARD , SCHMIDT FELIX
Abstract: An apparatus and a method are disclosed for the removal and the recovery of washcoat remaining in the channels of freshly coated monolithic or honeycombed catalytic carriers. The carrier is inserted into a chamber from above and tightly fitted therein at least with the lowest part of the carrier therein. The chamber is fitted with a collection area and a runoff located thereunder. The runoff leads via a shutoff valve into a separation vessel under a vacuum. The opening and closing of the shutoff valve causes air to be aspirated through the carrier channels, which are open at the top or are gradually opened by means of a slotted slide. This action causes the washcoat remnants to he transferred into the separation vessel, where they can be collected in the sump and are then pumped off. The apparatus can be used in systems for manufacturing catalysts for cleaning exhaust gases.
-
公开(公告)号:ZA9100337B
公开(公告)日:1991-11-27
申请号:ZA9100337
申请日:1991-01-16
Applicant: DEGUSSA
Inventor: SCHMIDT FELIX , FELIX SCHMIDT , DOMESLE RAINER , RAINER DOMESLE , MERGNER BERND , BERND MERGNER
CPC classification number: B01J37/0217 , B01J37/0018 , B01J37/0219
-
公开(公告)号:DK149304C
公开(公告)日:1986-09-08
申请号:DK126075
申请日:1975-03-25
Applicant: DEGUSSA
Inventor: SCHMIDT FELIX , SPITZNAGEL KURT , WAGNER ADOLF
Abstract: Aerogel like silica is prepared having:
-
公开(公告)号:MX172603B
公开(公告)日:1994-01-03
申请号:MX2471791
申请日:1991-02-27
Applicant: DEGUSSA
Inventor: BIRTIGH GERHARD , EWALD DITTRICH , SCHMIDT FELIX , BAUMGARTNER WILFRIED , MANNER REINHARD
-
公开(公告)号:ZA91337B
公开(公告)日:1991-11-27
申请号:ZA91337
申请日:1991-01-16
Applicant: DEGUSSA
Inventor: SCHMIDT FELIX , FELIX SCHMIDT , DOMESLE RAINER , RAINER DOMESLE , MERGNER BERND , BERND MERGNER
Abstract: The thermal shock resistance of monolithic catalysts is improved by pre-coating a ceramic monolithic carrier, before the application of catalytic components, with an organic filling material which can be melted and burned out and which comprises a dispersion of very fine solid particles, by heating the carrier above the melting point of the filling material, then applying the catalytic components and then burning out the filling material.
-
6.
公开(公告)号:ZA91145B
公开(公告)日:1991-11-27
申请号:ZA91145
申请日:1991-01-08
Applicant: DEGUSSA
Inventor: DOMESLE RAINER , RAINER DOMESLE , ENGLER BERND , BERND ENGLER , SCHMIDT FELIX , FELIX SCHMIDT , SCHUBERT PETER , PETER SCHUBERT , KOBERSTEIN EDGAR , EDGAR KOBERSTEIN
IPC: B01J23/40 , B01D53/86 , B01D53/94 , B01J23/56 , B01J23/58 , B01J23/63 , B01J23/89 , B01J37/02 , F01N3/18 , F02B1/04 , B01J , F01N
Abstract: Catalyst for purifying i.c. engine exhaust gas has an Al2O3 support of the transition series, which contains 3-70 (wt.)% CeO2, 0-20% La2O3, opt. mixed with other rare earth metal oxides, 1-20% ZrO2, 0-10% Fe2O3 and 0-20% NiO as promoter, and has an active phase of 0.02-3% Pt and/or Pd and Rh, with a ratio of Pt and/or Pd and Rh of 1:2 to 15:1, pref. 1:1 to 3:1 and opt. a wt. ratio of Pt and Pd of 10:1 to 1:5. The opt. lattice-stabilised support is impregnated with a soln. of a promoter cpd. and/or mixed with a suspension of oxides, hydroxides or carbonates of the promoter elements and heated in air at 300-900 deg.C, then impregnated with a soln. of the noble metal cpds.,dried and opt. activated in a gas contg. H2, opt. under hydrothermal conditions, at 250-1050 deg.C. The catalyst contains base metal(s), i.e. Li, K, Rb, Mg, Ca, Ba, La, Ce, Pr, Nd, Sm, Fe, Co and/or Ni, in an amt. up to 5 times the total amt. of noble metal; and is prepd. by impregnating the support contg. promoter with a soln. (A) of Pt and/or Pd cpd(s). corresp. to at least 30% of the total amt. of Pt and/or Pd, drying and activation, then impregnating with a soln. (B) contg. Rh cpd. opt. the rest of the Pt and/or Pd cpd. and base metal cpd(s)., followed by drying and activation.
-
公开(公告)号:ZA9100335B
公开(公告)日:1991-11-27
申请号:ZA9100335
申请日:1991-01-16
Applicant: DEGUSSA
Inventor: SCHMIDT FELIX , FELIX SCHMIDT , MANNER REINHARD , REINHARD MANNER , DITTRICH EWALD , EWALD DITTRICH , BAUMGARTNER WILFRIED , WILFRIED BAUMGARTNER , BIRTIGH GERHARD , GERHARD BIRTIGH
IPC: B01J20060101 , B05D20060101 , C04B20060101 , C23C20060101 , C23D20060101 , C04B , B01J , B05D , C23C , C23D
-
公开(公告)号:BR9100820A
公开(公告)日:1991-11-05
申请号:BR9100820
申请日:1991-02-28
Applicant: DEGUSSA
Inventor: SCHMIDT FELIX , MERGNER BERND , DOMESLE RAINER
Abstract: The thermal shock resistance of monolithic catalysts is improved by pre-coating a ceramic monolithic carrier, before the application of catalytic components, with an organic filling material which can be melted and burned out and which comprises a dispersion of very fine solid particles, by heating the carrier above the melting point of the filling material, then applying the catalytic components and then burning out the filling material.
-
公开(公告)号:DK160289A
公开(公告)日:1989-11-08
申请号:DK160289
申请日:1989-04-03
Applicant: DEGUSSA
Inventor: KERNER DIETER , WAGNER ADOLF , SCHMIDT FELIX , BAUER DIETRICH
IPC: C01B33/187 , C01B33/193 , C09C1/30 , C09C3/10 , C09C3/12 , C09D7/00 , C09D7/12
Abstract: The finely divided high-structure precipitated silica, which has a BET surface area (DIN 60132) of between 150 and 350 m /g a compacted bulk density (DIN 53194) of between 60 and 120 g/l a DBP number of between 3.0 and 4.0 ml/g a particle size distribution of at least 70 % of 1 to 6 mu m. It can be prepared by heating a mixture of water and sodium silicate to a temperature of 70 to 80 DEG C with stirring, metering into this mixture concentrated sulphuric acid until half of the alkali present is neutralised, treating the reaction mixture by means of a shearing unit and, if desired, simultaneously increasing the temperature to 86 +/- 5 DEG C, adding concentrated sulphuric acid after a period of 30 to 120 minutes at a higher speed until the pH of the silica suspension formed is 3.0 to 3.5, diluting, if desired, the silica suspension with water, separating off, if desired, the coarse portion by means of a centrifugal pump and a hydrocyclone, filtering off the silica using a known filtering device, washing the silica filter cake free of sulphate, redispersing the silica filter cake with the addition of water and using a stirrer to give a suspension having a solids content of 80 +/- 10 g/l, adding to this suspension, if desired, alkyldimethylbenzylammonium chloride, spray drying the suspension thus obtained and, if desired, milling the dried product. The precipitated silica can be used as matting agents in paints either in uncoated or coated form.
-
公开(公告)号:DK160289D0
公开(公告)日:1989-04-03
申请号:DK160289
申请日:1989-04-03
Applicant: DEGUSSA
Inventor: KERNER DIETER , WAGNER ADOLF , SCHMIDT FELIX , BAUER DIETRICH
IPC: C01B33/187 , C01B33/193 , C09C1/30 , C09C3/10 , C09C3/12 , C09D7/00 , C09D7/12
Abstract: The finely divided high-structure precipitated silica, which has a BET surface area (DIN 60132) of between 150 and 350 m /g a compacted bulk density (DIN 53194) of between 60 and 120 g/l a DBP number of between 3.0 and 4.0 ml/g a particle size distribution of at least 70 % of 1 to 6 mu m. It can be prepared by heating a mixture of water and sodium silicate to a temperature of 70 to 80 DEG C with stirring, metering into this mixture concentrated sulphuric acid until half of the alkali present is neutralised, treating the reaction mixture by means of a shearing unit and, if desired, simultaneously increasing the temperature to 86 +/- 5 DEG C, adding concentrated sulphuric acid after a period of 30 to 120 minutes at a higher speed until the pH of the silica suspension formed is 3.0 to 3.5, diluting, if desired, the silica suspension with water, separating off, if desired, the coarse portion by means of a centrifugal pump and a hydrocyclone, filtering off the silica using a known filtering device, washing the silica filter cake free of sulphate, redispersing the silica filter cake with the addition of water and using a stirrer to give a suspension having a solids content of 80 +/- 10 g/l, adding to this suspension, if desired, alkyldimethylbenzylammonium chloride, spray drying the suspension thus obtained and, if desired, milling the dried product. The precipitated silica can be used as matting agents in paints either in uncoated or coated form.
-
-
-
-
-
-
-
-
-