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公开(公告)号:DE4416330A1
公开(公告)日:1995-11-16
申请号:DE4416330
申请日:1994-05-09
Applicant: HOECHST AG
Inventor: SCHEUNEMANN UDE DR , ALTHOFF OLAF DR , HICKEL WERNER DR , APPEL GUNTHER , BAUER JACQUELINE , GEIS GERHARD
IPC: B01D69/12 , B01D71/70 , B32B5/18 , C08J3/24 , C08J5/18 , C08L83/02 , C08L83/04 , B01D67/00 , B01D61/36 , B01D53/22
Abstract: The prodn. of composite membranes comprises spreading a soln. of a polymer (I) in a volatile solvent on water. Allowing the solvent to evaporate, crosslinking the polymer and transferring the film obtd. to a supporting membrane. Also claimed is a composite membrane with polymer layer(s) on a porous base membrane, obtd. by this process. (I) is a polysiloxane which is pref. crosslinked via OH gps. on the polymer, with the aid of a bi-, tri- or tetra-functional silane with hydrolysable SiO- gps. as crosslinker (II), pref. triacetoxy-methyl-silane (TACMS), in the presence of a catalyst, pref. a tin salt. Alternatively, (I) may be a polymer contg. olefinic double bonds, which is crosslinked by irradiation. Pref. polymer layer is a protective layer of polysiloxane, crosslinked via OH gps. to a structure contg. units of formula Si(O-)4, R-Si(O-)3 or RR Si(O-)2 (with R, R = alkyl, phenyl or vinyl), or a silicone which is crosslinked by irradiation.
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公开(公告)号:DE4225962A1
公开(公告)日:1994-02-10
申请号:DE4225962
申请日:1992-08-06
Applicant: HOECHST AG
Inventor: HICKEL WERNER DR , SCHINDLER THOMAS , TER MEER HANS-ULRICH DR
Abstract: A laminate bears on a layer substrate at least one regularly arranged monomolecular layer which contains a fullerene and a polymeric amphiphilic compound, in particular a polymethacrylate derivative. It is suitable for applications in non-linear optics.
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公开(公告)号:DE59302244D1
公开(公告)日:1996-05-23
申请号:DE59302244
申请日:1993-08-03
Applicant: HOECHST AG
Inventor: APPEL GUNTHER , BAUER JACQUELINE , HICKEL WERNER DR , LUPO DONALD DR , PRASS WERNER DR , SCHEUNEMANN UDE DR
Abstract: For the continuous production of an ultra-thin, ordered layer of amphiphilic molecules on the surface of a polar liquid, an aligned flow of the polar liquid is generated in a channel, which polar liquid contains the amphiphilic molecules, dissolved or undissolved, on the surface in spread form. In the channel, a channel section with relatively high flow rate at the surface is provided, which section has a ramp which is arranged on the channel bottom and over which the polar liquid flows. Following this there is a channel section with a relatively low flow rate at the surface, in which channel section the flow is dammed at an obstruction with the liquid level constant over time, so that an ultra-thin, ordered layer of amphiphilic molecules continuously forms, as a result of flow compression, at the polar liquid/air phase boundary in these channel sections. The ramp over which the liquid flows is arranged so as to be movable.
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公开(公告)号:DE19516908A1
公开(公告)日:1995-11-16
申请号:DE19516908
申请日:1995-05-09
Applicant: HOECHST AG
Inventor: ALTHOFF OLAF DR , FALK UWE DR , SCHEUNEMANN UDE DR , PRAS WERNER DR , HICKEL WERNER DR
IPC: B01D53/22 , B01D69/12 , B01D71/32 , B01D71/36 , B01D71/38 , B05D1/20 , B32B5/18 , B32B27/00 , B32B27/08 , B32B27/16 , B32B27/30 , B01D67/00 , B01D61/36
Abstract: A composite membrane comprises a porous base membrane (A) and a fluorine-contg. perm-selective layer (C) 10-500 nm thick consisting of a copolymer of: (a) 10-80 mole% units of a vinyl ester of formula (I); (b1) 5-40 mole% vinyl alcohol units of formula (II) or (b2) 5-50 mole% units of formula (III); and (c) at least 10 mole% fluoro-olefin, with the OH gp.-contg. chains crosslinked with one another. In the formula, R1-R3 = H, alkyl, cycloalkyl or aryl, with a total of 5-30 C atoms over all 3 gps.; R4 = OH, opt. with up to 10% of the gps. R4 replaced by -OCOR5 (with R5 = Me, Et or Pr); R6 = 1-6C linear or branched alkylene. Also claimed is a process for the prodn. of this membrane, by dissolving the above terpolymer in a solvent, mixing with a polyfunctional isocyanate, spreading the soln. on water, evaporating the solvent and transferring the layer (C) thus obtd. to a base membrane (A). Also claimed is a membrane as described above in which the copolymer in layer (C) is uncrosslinked. Preferably, R1-R3 = alkyl or cycloalkyl with a total of 7-9 C atoms, pref. with at least one of these gps. = Me; R6 = 1,4-butylene.
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公开(公告)号:BR9303225A
公开(公告)日:1994-03-08
申请号:BR9303225
申请日:1993-07-30
Applicant: HOECHST AG
Inventor: HICKEL WERNER DR , SCHINDLER THOMAS , MEER HANS-ULRICH TER
IPC: C08J5/18 , B05D1/20 , C08K3/04 , C09K3/00 , G02F1/35 , G02F1/355 , G02F1/361 , B32B27/00 , B32B31/00
Abstract: A laminate bears on a layer substrate at least one regularly arranged monomolecular layer which contains a fullerene and a polymeric amphiphilic compound, in particular a polymethacrylate derivative. It is suitable for applications in non-linear optics.
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公开(公告)号:DE4234230A1
公开(公告)日:1994-04-14
申请号:DE4234230
申请日:1992-10-10
Applicant: HOECHST AG
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公开(公告)号:DE4233987A1
公开(公告)日:1994-04-14
申请号:DE4233987
申请日:1992-10-09
Applicant: HOECHST AG
Inventor: CABRERA IVAN DR , FALK UWE DR , HICKEL WERNER DR , LUPO DONALD DR , SCHEUNEMANN UDE DR , BOLDT PETER PROF DR , RASE JENS
IPC: C07D333/34 , C07D409/06 , C07F3/14 , G02B6/12 , G02F1/35 , G02F1/355 , G02F1/361 , B05D5/06 , G01J3/45
Abstract: New thiophene cpds. are 5-alkylthiothien-2-yl-Hg acetates and 5-alkylthio-thiophene-2-aldehyde derivs. of formula (I), where R=1-22C alkyl; X=-Hg-OCOCH3 or -CH=B; and B=a substd. C or N atom. More specifically X=-CH=C(CN)2, -CH=CH-Pyr+A-, -CH=CH-Phe-R2, -CHC=NOH or -CH=N-NH-Phe-R2; Pyr+=N-R1-substd. pyridinium-4-yl; R1=1-22, esp. 12-22C alkyl; Phe=p-phenylene; R2=a substit. more negative than H; A-=an anion; R=12-22C alkyl, esp. Me. USE/ADVANTAGE - (I) and 2-(1-22C)-alkyl-thiophene-5-aldehyde (II) are used for nonlinear optical (NLO) purposes; and some (I) are used in laminates with at least a mono-mol. layer of (I) on a substrate (claimed). These laminates can be structurised to 2D waveguides. (I), which have donor and acceptor substits., have absorption max. below 500, pref. below 450, esp. below 400 nm, high stability towards the atmos., elevated temps. and light and high NLO activity.
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