公开(公告)号：DE59403835D1

公开(公告)日：1997-10-02

申请号：DE59403835

申请日：1994-04-27

Applicant: HOECHST AG

Inventor： FLEISCHER DIETRICH DR ,  STRUTZ HEINZ DR ,  KULPE JUERGEN DR ,  SCHLEICHER ANDREAS DR

IPC: C08G75/02 ,  C08G75/0236 ,  C08G75/0295 ,  C08G75/06 ,  C08G75/20

Abstract: A process for the oxidation of a thioether group-containing polymer in which the polymer in solid form is oxidised using ozone in a suspension medium. The polymer obtained is suitable for the production of functional parts subjected to high stresses.

公开(公告)号：DE59403144D1

公开(公告)日：1997-07-24

申请号：DE59403144

申请日：1994-01-03

Applicant: HOECHST AG

Inventor： BELLER MATTHIAS DR ,  FISCHER HARTMUT ,  STRUTZ HEINZ DR

IPC: B01J23/44 ,  C07B37/04 ,  C07B61/00 ,  C07C37/11 ,  C07C39/19 ,  C07C47/542 ,  C07C47/55 ,  C07C67/343 ,  C07C67/347 ,  C07C69/618 ,  C07C69/76 ,  C07C69/86 ,  C07C69/92 ,  C07C201/12 ,  C07C205/06 ,  C07C233/05 ,  C07C233/11 ,  C07C233/20 ,  C07C235/34 ,  C07C237/06 ,  C07C253/30 ,  C07C255/32 ,  C07C255/50 ,  C07C255/51 ,  C07C255/54 ,  C07C255/55 ,  C07C255/57 ,  C07C255/58

Abstract: Aromatic olefins of the formula (I) in which R -R denote hydrogen, alkyl(C1-C8), alkoxy(C1-C5), phenyl, fluorine, chlorine, bromine, -OH, -NO2, -CN, -CHO, -CO(alkyl)(C1-C4), -CO phenyl, - COO alkyl(C1-C4), -OCO alkyl(C1-C4), -NHCO alkyl(C1-C4), -CF3, - NH2, -NH alkyl(C1-C4) or -N(alkyl(C1-C4))2 and R denotes hydrogen, alkyl(C1-C8), phenyl, fluorine, chlorine, bromine, -OH, -NO2, - CN, -CHO or -OCO alkyl(C1-C4), X denotes, inter alia, alkenyl (C2-C12) or cycloalkenyl(C4-C8) or the group in which R and R independently of one another are hydrogen or methyl, and Y denotes -phenyl, -CN, -COOH, -COO alkyl(C1-C12), - COO phenyl, - CON(alkyl(C1-C12))2, -CONH2, -CON(phenyl)2, -CO alkyl(C1-C12), -CO phenyl, -O alkyl(C1-C12) or - O phenyl or represents the radical in which R -R have the abovementioned meanings, are prepared by reacting an aryldiazonium salt of the formula (2) in which R -R have the meanings mentioned and Z represents the equivalent of an anion of an acid of pKa less than 7, with an olefin of the formula (3> HX (3> in which X has the meaning mentioned, in the presence of catalytic amounts of a heterogeneous palladium catalyst in an organic solvent at temperatures from -20@C to 150@C.

公开(公告)号：ES2097375T3

公开(公告)日：1997-04-01

申请号：ES93101799

申请日：1993-02-05

Applicant: HOECHST AG

Inventor： KULPE JURGEN DR ,  STRUTZ HEINZ DR

IPC: C07D301/14 ,  C07D301/19 ,  C07D303/04 ,  C07D303/06 ,  C07D303/08

Abstract: Fluoro-substituted epoxides of the general formula in which the substituents R1 to R4 independently of one another have the following meaning: R1 to R4 = H, fluorine, C1- to C18-alkyl, in which a part of all the hydrogens can be substituted by fluorine, and at least one of the substituents R1 to R4 is a completely fluorinated alkyl or an alkyl of the formula -(CH2)m-(CnF2n+1), in which m represents 1 or 2 and n represents an integer from 1 to 17, and x represents 0 or 1. A process for the preparation of fluoro-substituted epoxides is additionally given.

公开(公告)号：ES2093342T3

公开(公告)日：1996-12-16

申请号：ES93114314

申请日：1993-09-07

Applicant: HOECHST AG

Inventor： WEISSE LAURENT DR ,  STRUTZ HEINZ DR

IPC: C07B61/00 ,  C07C45/46 ,  C07C49/67 ,  C07C49/675 ,  C07C49/683 ,  C07C49/697

Abstract: 1-Indanones of the formula IV or IVa in which R to R preferably denote hydrogen or alkyl or adjacent radicals R to R form a ring are obtained in a one-step reaction by reacting a compound I with a compound of the formula II or with a compound of the formula III with boron trifluoride in anhydrous hydrogen fluoride.>

公开(公告)号：DE59301869D1

公开(公告)日：1996-04-18

申请号：DE59301869

申请日：1993-09-02

Applicant: HOECHST AG

Inventor： BELLER MATTHIAS DR ,  FISCHER HARTMUT ,  STRUTZ HEINZ DR

IPC: C07B61/00 ,  B01J31/18 ,  C07B37/04 ,  C07C2/86 ,  C07C15/46 ,  C07C15/52 ,  C07C17/266 ,  C07C25/24 ,  C07C37/18 ,  C07C39/21 ,  C07C41/24 ,  C07C43/20 ,  C07C45/68 ,  C07C59/48 ,  C07C67/347 ,  C07C205/06 ,  C07C205/56 ,  C07C253/30 ,  C07C255/50

公开(公告)号：DE4337191A1

公开(公告)日：1995-05-04

申请号：DE4337191

申请日：1993-10-30

Applicant: HOECHST AG

Inventor： KOBS UWE DR ,  STRUTZ HEINZ DR

IPC: C04B41/49 ,  C07F7/18 ,  C08F2/42 ,  C08F10/14 ,  C08G61/06 ,  C08F32/02 ,  C04B41/64 ,  C08F8/42 ,  C09K3/18 ,  E04B1/64 ,  H01B3/46

Abstract: A compound of the formula I in which x is an integer from 1 to 13, n is an integer from 1 to 100, R, R' and R'' are hydrogen, C1-C10-alkyl, C6-C20-aryl, C7-C20- aralkyl or C7-C20-alkylaryl, Z is a bond, C1-C10-alkylene, C6-C20-arylene or C6-C20-aryl-C1-C4-dialkylene, and R is hydrogen, C1-C10-alkyl, C6-C20-aryl or C7-C20- aralkyl, and in which x can be identical or different in the n structural units A, process for the preparation thereof, and the use thereof.

公开(公告)号：DE4316923A1

公开(公告)日：1994-11-24

申请号：DE4316923

申请日：1993-05-20

Applicant: HOECHST AG

Inventor： BELLER MATTHIAS DR ,  GERDAU THOMAS DR ,  STRUTZ HEINZ DR

IPC: B01J21/18 ,  B01J23/44 ,  B01J31/02 ,  C07C209/32 ,  C07C245/20 ,  C07D295/135 ,  C07C211/52 ,  C07C209/36 ,  C07C211/43 ,  C07C217/78 ,  C07D295/28 ,  C09B29/01

Abstract: A process for the preparation of aromatic amines by reducing the corresponding nitro compound with phosphorous acid in the presence of a heterogeneous palladium catalyst is characterised in that a phosphorous acid is employed which can be obtained as a by-product in the preparation of organic acid chlorides from organic acids and phosphorus trichloride. The process according to the invention allows aromatic amines to be prepared economically, in high yield, under mild conditions and in a chemoselective fashion. The process is also advantageous from the ecological point of view since it employs a waste material whose incineration or decontamination would involve high energy consumption.

公开(公告)号：BR9201627A

公开(公告)日：1992-12-15

申请号：BR9201627

申请日：1992-04-30

Applicant: HOECHST AG

Inventor： KULPE JUERGEN DR ,  STRUTZ HEINZ DR

IPC: C07C51/34 ,  C07C55/22 ,  C07C55/24 ,  C07C61/06

Abstract: The invention relates to a process for preparing polycarboxylic acids and their derivatives, the polycarboxylic acids prepared containing at least three carboxyl groups, and comprises the following steps: (A) introducing one or more organic compounds, which do not contain aromatic carbon-carbon (C-C) double bonds, into water, (B) ozonolysis of the organic compounds in water by passing in an ozone-containing carrier gas, (C) addition of aqueous hydrogen peroxide solution in order to work up the ozonolysis products formed in step (B) by oxidation, characterised in that the organic compound(s) is (are) introduced, in step (A), into water having a pH of 7 or less than 7, and in that the addition of hydrogen peroxide in step (C) in water is effected without addition of an organic solvent.

公开(公告)号：ES2110125T3

公开(公告)日：1998-02-01

申请号：ES94100015

申请日：1994-01-03

Applicant: HOECHST AG

Inventor： BELLER MATTHIAS DR ,  FISCHER HARTMUT ,  WEISSE LAURENT DR ,  FORSTINGER KLAUS DR ,  PFIRMANN RALF DR ,  STRUTZ HEINZ DR

IPC: B01J23/44 ,  C07B61/00 ,  C07C57/60 ,  C07C67/333 ,  C07C67/343 ,  C07C69/65 ,  C07C245/20

Abstract: The present invention relates to compounds of the formula in which R and R are identical or different and stand for hydrogen or an alkyl radical having 1 to 18 carbon atoms optionally containing oxygen, nitrogen or halogen, the radicals X, Y and Z are identical and stand for a fluorine, bromine or iodine atom or, if two of the radicals X, Y or Z are identical or all the radicals X, Y and Z are different from one another, X, Y and Z denote a fluorine, chlorine, bromine or iodine atom. The invention further relates to a process for the preparation of the compounds by reacting an aryldiazonium salt of the formula in which the radicals X, Y and Z are identical and stand for a fluorine, bromine or iodine atom or, if two of the radicals X, Y and Z are identical or all the radicals X, Y and Z are different from one another, X, Y and Z denote a fluorine, chlorine, bromine or iodine atom and A denotes an anion of an acid having a pKa of in which R and R are identical or different and stand for hydrogen or an alkyl radical having 1 to 18 carbon atoms optionally containing oxygen, nitrogen or halogen, in the presence of a palladium-containing catalyst, if appropriate with addition of a base, and to the aryldiazonium salts of the formula (II).

公开(公告)号：ES2099303T3

公开(公告)日：1997-05-16

申请号：ES93101685

申请日：1993-02-04

Applicant: HOECHST AG

Inventor： KULPE JURGEN DR ,  STRUTZ HEINZ DR

IPC: C07C29/10 ,  C07C29/46 ,  C07C35/48 ,  C07C35/52 ,  C08G63/682