Abstract:
PROBLEM TO BE SOLVED: To obtain a new starting material for forming an insulating polymer which has a small dielectric constant, high-temperature stability, and chemical stability. SOLUTION: A new bis-o-aminophenol is expressed by formula I (M is a bivalent residue having a specified structure). Heat-resistant polybenzoxazole is formed out of the bis-o-aminophenol. The bis-o-aminophenol is preferably produced by nitrosating a diol which corresponds to the aminophenol to form a nitroso compound, and hydrogenating the nitroso compound with H 2 in the presence of Pd/C, so as to obtain the amino compound by reduction. COPYRIGHT: (C)2004,JPO
Abstract:
PROBLEM TO BE SOLVED: To enable the use of a new starting material that has a small dielectric constant, good high-temperature stability and good chemical stability and enables the preparation of an insulating polymer. SOLUTION: A new bis-o-aminophenol of formula I (wherein M represents a particular group) is provided. The bis-o-aminophenol enables the preparation of a heat-resistant polybenzoxazole. The bis-o-aminophenol is preferably prepared from a corresponding diol, which is first nitrosated. A nitroso compound is then reduced to an amino compound through the hydrogenation using Pd/C and H 2 . COPYRIGHT: (C)2007,JPO&INPIT
Abstract:
Bis-aminophenols are new. Bis-aminophenols of formula (I) are new. G = oxgyen or sulfur; M = formula (II)-(IX); R1, R2 = phenyl, -(CH2)nCH3, -G-(CH2)nCH3, -C(CH3)3, -GC(CH3)3, -(CF2)nCF3, -G-(CF2)nCF3, -G-CH(CH3)2, -CH(CH3)2, -CF(CF3)2, -C(CF3)3, -N(CH3)2, -N(CF3)2, -C(R1)(R2)-, -C(O)-, -O-, -S- or -N(R1)-; n = 0-5. An Independent claim is included for a process for the preparation of bis-aminophenols (I) by reaction of a diol (II) to form a nitroso compound followed by reduction to form the bis-aminophenol (I).
Abstract:
Bis-aminophenols are new. Bis-aminophenols of formula (I) are new. G = oxgyen or sulfur; M = formula (II)-(IX); R1, R2 = phenyl, -(CH2)nCH3, -G-(CH2)nCH3, -C(CH3)3, -GC(CH3)3, -(CF2)nCF3, -G-(CF2)nCF3, -G-CH(CH3)2, -CH(CH3)2, -CF(CF3)2, -C(CF3)3, -N(CH3)2, -N(CF3)2, -C(R1)(R2)-, -C(O)-, -O-, -S- or -N(R1)-; n = 0-5. An Independent claim is included for a process for the preparation of bis-aminophenols (I) by reaction of a diol (II) to form a nitroso compound followed by reduction to form the bis-aminophenol (I).
Abstract:
Bis-aminophenols are new. Bis-aminophenols of formula (I) are new. G = oxgyen or sulfur; M = formula (II)-(IX); R1, R2 = phenyl, -(CH2)nCH3, -G-(CH2)nCH3, -C(CH3)3, -GC(CH3)3, -(CF2)nCF3, -G-(CF2)nCF3, -G-CH(CH3)2, -CH(CH3)2, -CF(CF3)2, -C(CF3)3, -N(CH3)2, -N(CF3)2, -C(R1)(R2)-, -C(O)-, -O-, -S- or -N(R1)-; n = 0-5. An Independent claim is included for a process for the preparation of bis-aminophenols (I) by reaction of a diol (II) to form a nitroso compound followed by reduction to form the bis-aminophenol (I).