公开(公告)号：CA2828369A1

公开(公告)日：2012-09-13

申请号：CA2828369

申请日：2012-03-06

Applicant: KANEKA CORP

Inventor： KAWAI YOSHIKAZU ,  SUZUKI YASUYUKI ,  MORIO KENICHIRO ,  HIRANO MASARU

IPC: C08B1/08 ,  B01J2/06 ,  B01J20/24 ,  B01J20/30 ,  C08B15/10 ,  G01N30/88

Abstract: The purpose of the present invention is to provide a method for simply and easily producing porous cellulose beads having high mechanical strength without using a toxic and highly corrosive auxiliary starting material and without including a complicated process that is commercially disadvantageous. A method for producing porous cellulose beads of the present invention is characterized in that a cellulose dispersion liquid, which is obtained by mixing an alkaline aqueous solution at a low temperature with cellulose, is brought into contact with a coagulation solvent.

公开(公告)号：SG192992A1

公开(公告)日：2013-10-30

申请号：SG2013065180

申请日：2012-03-06

Applicant: KANEKA CORP

Inventor： KAWAI YOSHIKAZU ,  SUZUKI YASUYUKI ,  MORIO KENICHIRO ,  HIRANO MASARU

Abstract: The objective of the present invention is to provide a convenient method for producing porous cellulose beads having high mechanical strength without using an auxiliary material which is5 highly toxic and corrosive and without a cumbersome and industrially adverse step. The method for producing porous cellulose beads according to the present invention is characterized in comprising the steps of mixing a cold alkaline aqueous solution and cellulose to prepare a cellulose dispersion and bringing the cellulose10 dispersion into contact with a coagulating solvent.

公开(公告)号：EP2165758A4

公开(公告)日：2016-08-03

申请号：EP08764904

申请日：2008-05-30

Applicant: KANEKA CORP

Inventor： KAWAI YOSHIKAZU ,  KAWAHARA NAOMI

IPC: B01J20/24 ,  A61M1/18 ,  C07K1/22 ,  C07K17/02 ,  G01N30/88

CPC classification number: C07K1/16 ,  B01D15/00 ,  B01J20/289 ,  B01J20/3212 ,  B01J20/3219 ,  B01J20/3242 ,  B01J20/3274 ,  C07K1/22

Abstract: The present invention relates to a porous base matrix having formyl group, which base matrix has a structure represented by the formula (2) as a spacer, which structure is obtained by cleaving a group represented by the formula (1): wherein, R 1 represents a group forming a five-membered ring or a six-membered ring with -CH (OH) -CH (OH) -; a method for producing the porous base matrix; and an adsorbent obtained by binding a ligand on the porous base matrix. By the present invention, a high-intensity base matrix for an adsorbent and an adsorbent are provided. The amount of a ligand leaked from the adsorbend is small.

公开(公告)号：EP2383035A4

公开(公告)日：2017-11-22

申请号：EP09830207

申请日：2009-12-03

Applicant: KANEKA CORP ,  JNC CORP

Inventor： KAWAI YOSHIKAZU ,  KAWASAKI HIROAKI ,  KAWAHARA NAOMI

IPC: B01J20/24 ,  B01D15/08 ,  B01J20/32 ,  G01N30/88

CPC classification number: C08B37/00 ,  B01J20/289 ,  B01J20/3212 ,  B01J20/3219 ,  B01J20/3229 ,  B01J20/3244 ,  B01J20/3248

Abstract: The present invention relates to a method for producing a formyl group-containing porous base matrix, comprising the steps of introducing a spacer in a formyl group-containing porous particle; and then oxidizing the spacer with periodic acid and/or a periodate, to transform the part of the spacer into a formyl group; wherein the formyl group content in the porous particle after introduction of the spacer is not more than 3 µmol per 1 mL of the porous particle. Also, the present invention relates to a method for producing an adsorbent, comprising the step of immobilizing an amino group-containing ligand on the formyl group-containing porous base matrix. According to the present invention, a formyl-group containing porous base matrix and an adsorbent produced from the porous base matrix of which adsorption amount is high and which is has high strength and of which ligand is difficult to be leaked are provided.

公开(公告)号：EP3059320A4

公开(公告)日：2017-06-21

申请号：EP14853421

申请日：2014-10-14

Applicant: KANEKA CORP

Inventor： KANAYA KENTO ,  KAWAI YOSHIKAZU ,  OKUBO TAKAHIRO ,  MORIO KEN-ICHIRO

IPC: C12P19/14 ,  B01J20/24 ,  B01J20/30 ,  C07K1/22 ,  C08B15/10 ,  G01N30/88

CPC classification number: C07K1/22 ,  B01J20/24 ,  B01J20/267 ,  B01J20/28016 ,  B01J20/285 ,  B01J20/286 ,  B01J20/3085 ,  B01J20/3212 ,  B01J20/3274 ,  B01J2220/54 ,  B01J2220/82 ,  C08J9/00 ,  C08J9/26 ,  C08J2201/026 ,  C08J2201/046 ,  C08J2301/02 ,  C12P19/14 ,  G01N2030/525

Abstract: The objective of the present invention is to provide to a method for easily producing high-performance porous cellulose beads having high mechanical strength. Also, the objective of the present invention is to provide an adsorbent produced from the high-performance porous cellulose beads. According to the present invention, high-performance porous cellulose beads can be easily produced from porous cellulose beads, and an adsorbent having high strength and high adsorption amount can be easily produced from the high-performance porous cellulose beads.

Abstract translation: 本发明的目的是提供一种易于生产具有高机械强度的高性能多孔纤维素珠粒的方法。 而且，本发明的目的是提供一种由高性能多孔纤维素珠粒生产的吸附剂。 根据本发明，可以容易地由多孔纤维素珠制造高性能多孔纤维素珠，并且可以容易地由高性能多孔纤维素珠制造具有高强度和高吸附量的吸附剂。

公开(公告)号：EP3059252A4

公开(公告)日：2017-08-09

申请号：EP14853802

申请日：2014-10-14

Applicant: KANEKA CORP

Inventor： HAYASHI ASUKA ,  KAWAI YOSHIKAZU ,  MORIO KEN-ICHIRO

IPC: C08B1/10 ,  B01J2/06 ,  B01J20/24 ,  B01J20/30 ,  C07K1/22 ,  C08B15/10 ,  C08J9/28 ,  G01N30/88

CPC classification number: B01J20/24 ,  B01J20/285 ,  B01J20/286 ,  B01J20/305 ,  B01J20/3085 ,  B01J20/3212 ,  B01J20/3217 ,  B01J20/3274 ,  B01J20/3293 ,  C07K1/145 ,  C07K1/22 ,  C07K17/12 ,  C08B15/10 ,  C08J9/16 ,  C08J9/28 ,  C08J2201/026 ,  C08J2201/0547 ,  C08J2301/00

Abstract: The objective of the present invention is to provide a method for easily and efficiently producing cellulose beads which have pore shape suitable for an adsorbent and of which adsorption performance is excellent without using highly toxic and highly corrosive auxiliary raw material and without industrially disadvantageous cumbersome step. The method for producing porous cellulose beads according to the present invention is characterized in comprising (a) the step of preparing a fine cellulose dispersion by mixing a low temperature alkaline aqueous solution and cellulose, (b) the step of preparing a mixed liquid by adding a crosslinking agent to the fine cellulose dispersion, (c) the step of preparing an emulsion by dispersing the mixed liquid in a dispersion medium, (d) the step of contacting the emulsion with a coagulating solvent.

Abstract translation: 本发明的目的在于提供一种不使用高毒性且高腐蚀性的辅助原料，且不存在工业上不利的繁琐工序，且容易且高效地制造具有适合于吸附剂的孔形状且吸附性能优异的纤维素珠粒的方法。 本发明的多孔性纤维素珠的制造方法的特征在于，包括：（a）将低温碱性水溶液与纤维素混合而制备微细纤维素分散液的工序;（b）通过添加混合液 （c）通过将该混合液分散在分散介质中来制备乳液的步骤，（d）使该乳液与凝结溶剂接触的步骤。

公开(公告)号：EP2894171A4

公开(公告)日：2016-05-25

申请号：EP13834932

申请日：2013-09-09

Applicant: KANEKA CORP

Inventor： KAWAI YOSHIKAZU ,  MORIO KEN-ICHIRO ,  KONOIKE FUMINORI ,  WATANABE KANA ,  SUZUKI YASUYUKI ,  HIRANO MASARU

IPC: C08B15/10 ,  A61K35/14 ,  A61P3/06 ,  A61P7/04 ,  A61P7/08 ,  A61P9/10 ,  A61P29/00 ,  C08B15/08 ,  C08J3/16 ,  C08L1/02

CPC classification number: A61M1/3679 ,  A61K9/1652 ,  C08B15/10 ,  C08B16/00 ,  C08J3/126 ,  C08J3/16 ,  C08J2301/02 ,  C08J2405/02 ,  C08J2489/00 ,  C08L1/02 ,  C08L5/02 ,  C08L89/00

公开(公告)号：EP3050902A4

公开(公告)日：2017-02-15

申请号：EP14849556

申请日：2014-09-26

Applicant: KANEKA CORP

Inventor： OKUBO TAKAHIRO ,  KAWAI YOSHIKAZU ,  HIRANO MASARU ,  KONOIKE FUMINORI ,  KARASUGI KEIICHI ,  HONDA TATSUYA

IPC: C08B1/08 ,  B01D15/08 ,  B01J20/24 ,  C07K1/22 ,  C08B15/08 ,  C08B15/10 ,  C08B37/12 ,  G01N30/88

CPC classification number: C07K1/22 ,  B01D15/3809 ,  B01J20/24 ,  B01J20/267 ,  B01J20/28004 ,  B01J20/28016 ,  B01J20/285 ,  B01J20/286 ,  B01J20/3071 ,  B01J20/3085 ,  B01J20/3212 ,  B01J20/3219 ,  B01J20/3274 ,  B01J20/3293 ,  B01J2220/52 ,  C07K16/00 ,  C08B1/08 ,  C08B3/06 ,  C08B15/005 ,  C08B15/08 ,  C08B15/10 ,  C08B16/00 ,  C08J3/16 ,  C08J9/00 ,  C08J2301/02 ,  C08J2301/04 ,  C08J2301/12 ,  C08L1/02 ,  C08L1/04 ,  C08L1/12 ,  C08L2205/18

Abstract: A process for producing porous cellulose beads of the present invention is characterized by comprising the steps of: a) mixing an alkali aqueous solution and cellulose to prepare cellulose micro dispersion at low temperature, b) adding water to the cellulose micro dispersion to prepare cellulose slurry, and d) bringing the cellulose slurry into contact with coagulation solvent. A carrier for ligand immobilization of the present invention is characterized by being by shrinking polysaccharide porous beads not less than 10% by a shrinkage rate defined by the following formula, and crosslinking the polysaccharide porous beads: Shrinkage rate % = 1 ˆ’ V 2 / V 1 × 100 (wherein, V 1 indicates the gel volume of polysaccharide porous beads before shrinkage, and V 2 indicates the gel volume of polysaccharide porous beads after shrinkage).

公开(公告)号：EP2684897A4

公开(公告)日：2014-08-20

申请号：EP12754262

申请日：2012-03-06

Applicant: KANEKA CORP

Inventor： KAWAI YOSHIKAZU ,  SUZUKI YASUYUKI ,  MORIO KENICHIRO ,  HIRANO MASARU

IPC: C08B1/08 ,  B01J2/06 ,  B01J20/24 ,  B01J20/30 ,  C08B15/10 ,  G01N30/88

CPC classification number: C08B15/10 ,  B01J20/267 ,  B01J20/28078 ,  B01J20/285 ,  B01J20/3085 ,  C08B15/00 ,  C08J9/28 ,  C08J2201/0546 ,  C08J2301/02 ,  C08L1/02

公开(公告)号：EP2626381A4

公开(公告)日：2014-01-15

申请号：EP11823691

申请日：2011-09-12

Applicant: KANEKA CORP

Inventor： HIRANO MASARU ,  SUZUKI YASUYUKI ,  KANAYA KENTO ,  KANDA AKIHISA ,  SUZUKI TAKUMA ,  KAWAI YOSHIKAZU ,  MORIO KEN-ICHIRO

IPC: C08J3/16 ,  C08J9/28 ,  C08L1/02

CPC classification number: C08B1/003 ,  B01D15/3809 ,  B01J20/262 ,  B01J20/267 ,  B01J20/28004 ,  B01J20/285 ,  B01J20/3212 ,  B01J20/3274 ,  C07K1/22 ,  C08J3/16 ,  C08J9/28 ,  C08J2201/0482 ,  C08J2207/12 ,  C08J2301/02 ,  Y10T428/2982