公开(公告)号：BG62398B1

公开(公告)日：1999-10-29

申请号：BG9818993

申请日：1993-10-29

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID G ,  TROTT LOUIS R ,  REILING VINCENT G ,  SURESH DEV D ,  BOTT PAUL E ,  SHUKI JUN ALBERT R ,  BIGLER KENETH L ,  MIKO STEVE J ,  SEELY MICHAEL J ,  FRIEDRICH MARIA S ,  SOCHELL EDWARD J ,  KECKLER KENETH P ,  KOCJANCIC FRANK J

IPC: B01D53/58 ,  C07C253/24 ,  C07C253/26 ,  C07C255/00 ,  C07C255/08

Abstract: By the method the ammonium sulphate formed during themanufacture of acrylonitrile by direct ammoxidation (reactionbetween ammonia and oxygen) of propylene or propane, ammonia andogygen-containing gas, such as air on catalyst fluidized bedfitted in respective reactor, is eliminated to a great extent orcompletely. In the reactor organic substance, or substances,respectively, are introduced which react with practically all theresidual ammonia without this affecting the acrylonitrile yield.It is preferable that the organic substance should be methanolwhich is introduced in the reactor at temperatures bellow thepoints of its carbonization.20 claims

公开(公告)号：ZA9504931B

公开(公告)日：1996-02-07

申请号：ZA9504931

申请日：1995-06-14

Applicant: STANDARD OIL CO OHIO

Inventor： REILING VINCENT G ,  RINKER JEFFREY E ,  MCDONEL TIMOTHY R ,  SARNA JOSEPH C

IPC: B01J8/24 ,  B01J12/02 ,  C01C3/02 ,  C07C253/24 ,  C07C253/26 ,  C07C253/34 ,  C07C255/08 ,  C07C

CPC classification number: C07C253/24 ,  C07C253/26 ,  Y02P20/52 ,  C07C255/08

公开(公告)号：BG98189A

公开(公告)日：1995-02-28

申请号：BG9818993

申请日：1993-10-29

Applicant: STANDARD OIL CO

Inventor： SHAW WILFRID G ,  TROTT LOUIS R ,  REILING VINCENT G ,  SURESH DEV D ,  BOTT PAUL E ,  SHUKI ALBERT R ,  BIGLER KENETH L ,  MIKO STEVE J ,  SEELY MICHAEL J ,  FRIEDRICH MARIA S ,  SOCKELL EDWARD J ,  KECKLER KENETH P ,  KOCJANCIC FRANK J

IPC: B01D53/58 ,  C07C253/24 ,  C07C253/26 ,  C07C255/00 ,  C07C255/08

Abstract: By the method the ammonium sulphate formed during the manufacture of acrylonitrile by direct ammoxidation (reaction between ammonia and oxygen) of propylene or propane, ammonia and ogygen-containing gas, such as air on catalyst fluidized bed fitted in respective reactor, is eliminated to a great extent or completely. In the reactor organic substance, or substances, respectively, are introduced which react with practically all the residual ammonia without this affecting the acrylonitrile yield. It is preferable that the organic substance should be methanol which is introduced in the reactor at temperatures bellow the points of its carbonization.

公开(公告)号：ES2144100T3

公开(公告)日：2000-06-01

申请号：ES95304532

申请日：1995-06-27

Applicant: STANDARD OIL CO OHIO

Inventor： MCDONEL TIMOTHY R ,  RINKER JEFFREY E ,  REILING VINCENT G ,  SARNA JOSEPH C

IPC: B01J8/24 ,  B01J12/02 ,  C01C3/02 ,  C07C253/24 ,  C07C253/26 ,  C07C253/34 ,  C07C255/08

Abstract: Redn. in the amt. of unreacted ammonia exiting the reactor in acrylonitrile mfr., comprises: (a) contacting with a fluid bed catalyst, in the lower portion of a fluid bed reactor, ammonia, O2 and a hydrocarbon comprising propylene or propane, to produce acrylonitrile; (b) feeding O2 free of any oxygenate cpds. into the upper portion of the fluid bed reactor, at a point where the additional O2 does not affect the reaction, but reacts with at least some of the unreacted ammonia; (c) cooling the reactor effluent contg. acrylonitrile by feeding into a water quench column; (d) removing unwanted impurities; and (e) recovering acrylonitrile from the quench column.

公开(公告)号：DE69414660D1

公开(公告)日：1998-12-24

申请号：DE69414660

申请日：1994-02-04

Applicant: STANDARD OIL CO OHIO

Inventor： BIGLER KENNETH L ,  BOTT PAUL E ,  FRIEDRICH MARIA S ,  KECKLER KENNETH P ,  KOCJANCIC FRANK J ,  MIKO STEVE J ,  REILING VINCENT G ,  ROWE STEVEN J ,  SEELY MICHAEL J ,  SHAW WILFRID G ,  SHUKI ALBERT R ,  SOCKELL EDWARD J ,  SURESH DEV D ,  TROTT LOUIS R

IPC: B01D53/58 ,  C01C3/02 ,  B01J23/88 ,  C07B61/00 ,  C07C5/08 ,  C07C253/24 ,  C07C253/26 ,  C07C253/32 ,  C07C255/00 ,  C07C255/08

Abstract: A process for the substantial reduction or complete elimination of ammonium sulfate generated during the production of acrylonitrile by the direct ammoxidation of propylene/propane, ammonia and an oxygen containing gas (e.g. air) over a fluid bed catalyst wherein the improvement comprises introducing methanol into said reactor in the upper portion of the reactor at a location where the methanol reacts with at least a portion if not substantially all of the excess ammonia without affecting the acrylonitrile yield. Preferably, methanol is introduced into the reactor at below its coking temperature. In particular, when an oxygen lean fluid bed catalyst is utilized, an additional oxygen containing gas is introduced into the reaction at a distance between about 8 to 14 inches from the methanol feed location.

公开(公告)号：BR9503515A

公开(公告)日：1996-06-04

申请号：BR9503515

申请日：1995-08-01

Applicant: STANDARD OIL CO OHIO

Inventor： REILING VINCENT G ,  RINKER JEFFREY E ,  MCDONEL TIMOTHY R ,  SARNA JOSEPH C

IPC: B01J8/24 ,  B01J12/02 ,  C01C3/02 ,  C07C253/24 ,  C07C253/26 ,  C07C253/34 ,  C07C255/08 ,  C01C1/10

Abstract: Redn. in the amt. of unreacted ammonia exiting the reactor in acrylonitrile mfr., comprises: (a) contacting with a fluid bed catalyst, in the lower portion of a fluid bed reactor, ammonia, O2 and a hydrocarbon comprising propylene or propane, to produce acrylonitrile; (b) feeding O2 free of any oxygenate cpds. into the upper portion of the fluid bed reactor, at a point where the additional O2 does not affect the reaction, but reacts with at least some of the unreacted ammonia; (c) cooling the reactor effluent contg. acrylonitrile by feeding into a water quench column; (d) removing unwanted impurities; and (e) recovering acrylonitrile from the quench column.

公开(公告)号：BG99815A

公开(公告)日：1996-04-30

申请号：BG9981595

申请日：1995-07-24

Applicant: STANDARD OIL CO

Inventor： REILING VINCENT G ,  RINKER JEFFREY E ,  MCDONEL TIMOTHY R ,  SARNA JOSEPH C

IPC: B01J8/24 ,  B01J12/02 ,  C01C3/02 ,  C07C253/24 ,  C07C253/26 ,  C07C253/34 ,  C07C255/08

Abstract: The method consists in the introduction of additional quantity of oxygen-containing gas, preferably air, in the absence of any oxygen-saturated compounds in the upper part of the fluidized bed reactor which reacts with at last part of the unreacted ammonia, in order to reduce the content of the available, unreacted ammonia in the waste reactor fluid.

公开(公告)号：ZA941200B

公开(公告)日：1994-11-30

申请号：ZA941200

申请日：1994-02-22

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILRID G ,  TROTT LOUIS R ,  BIGLER KENNETH L ,  MIKO STEVE J ,  REILING VINCENT G ,  SURESH DEV D ,  BOTT PAUL E ,  SHUKI ALBERT R JR ,  KOCJANCIC FRANK J ,  SEELY MICHAEL J ,  FRIEDRICH MARIA S ,  SOCKELL EDWARD J ,  KECKLER KENNETH P ,  ROWE STEVEN J

IPC: C07B20060101 ,  C07C20060101 ,  C07C ,  C07B

公开(公告)号：ZA9401200B

公开(公告)日：1994-11-30

申请号：ZA9401200

申请日：1994-02-22

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILRID G ,  TROTT LOUIS R ,  BIGLER KENNETH L ,  MIKO STEVE J ,  REILING VINCENT G ,  SURESH DEV D ,  BOTT PAUL E ,  SHUKI ALBERT R JR ,  KOCJANCIC FRANK J ,  SEELY MICHAEL J ,  FRIEDRICH MARIA S ,  SOCKELL EDWARD J ,  KECKLER KENNETH P ,  ROWE STEVEN J

IPC: C07B20060101 ,  C07C20060101 ,  C07C ,  C07B

CPC classification number: Y02A50/2346

公开(公告)号：BG62926B1

公开(公告)日：2000-11-30

申请号：BG9981595

申请日：1995-07-24

Applicant: STANDARD OIL CO

Inventor： REILING VINCENT G ,  RINKER JEFFREY E ,  MCDONEL TIMOTHY R ,  SARNA JOSEPH C

IPC: B01J8/24 ,  B01J12/02 ,  C01C3/02 ,  C07C253/24 ,  C07C253/26 ,  C07C253/34 ,  C07C255/08

Abstract: The method consists in the introduction of additional quantity of oxygen-containing gas, preferably air, in the absence of any oxygen-saturated compounds in the upper part of the fluidized bed reactor which reacts with at last part of the unreacted ammonia, in order to reduce the content of the available, unreacted ammonia in the waste reactor fluid. 18 claims