公开(公告)号：US3236911A

公开(公告)日：1966-02-22

申请号：US7856460

申请日：1960-12-27

Applicant: STANDARD OIL CO

Inventor： SHAW WILFRID G ,  CARDON NEVA L

IPC: C08F10/00

CPC classification number: C08F10/00 ,  C08F4/26

公开(公告)号：US3329603A

公开(公告)日：1967-07-04

申请号：US42219664

申请日：1964-12-30

Applicant: STANDARD OIL CO

Inventor： HUGHES EVERETT C ,  SHAW WILFRID G ,  ARTHUR STRECKER HAROLD

IPC: B01J8/24

CPC classification number: B01J8/24 ,  C10G47/12 ,  C10G47/30

公开(公告)号：US3578695A

公开(公告)日：1971-05-11

申请号：US3578695D

申请日：1967-07-26

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  SHAW WILFRID G

IPC: C07C121/32 ,  C07C121/00

CPC classification number: C07C253/10 ,  C07C255/08

Abstract: THE INSTANT APPLICATION DEALS WITH A PROCESS FOR THE MANUFACTURE OF MONOOLEFINICALLY UNSATURATED ALIPHATIC NITRILES BY THE CATALYTIC OXIDATION OF OLEFIN USING CYANIDE AND A MOLECULAR OXYGEN-CONTAINING GAS, BUT NO AMMONIA.

公开(公告)号：US3882159A

公开(公告)日：1975-05-06

申请号：US39017573

申请日：1973-08-20

Applicant: STANDARD OIL CO

Inventor： CALLAHAN JAMES L ,  SHAW WILFRID G ,  MILLER ARTHUR F

IPC: C07C5/48 ,  B01J8/26 ,  B01J23/36 ,  B01J23/86 ,  B01J23/92 ,  B01J23/94 ,  B01J38/00 ,  C07B31/00 ,  C07B33/00 ,  C07B61/00 ,  C07C1/00 ,  C07C11/00 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  C07C121/02

CPC classification number: B01J38/16 ,  B01J8/26 ,  B01J23/28 ,  B01J23/86 ,  B01J23/92 ,  B01J23/94 ,  B01J35/0006 ,  C07C253/26 ,  Y02P20/52 ,  Y02P20/584 ,  Y10S585/901 ,  C07C255/08

Abstract: Molybdenum-containing oxidation catalysts used in a fluid-bed reactor have been discovered to become partially deactivated through loss of molybdenum from the catalyst. These partially deactivated catalysts are regenerated in situ by the addition of fluid-bed particles consisting of an essentially inert support material containing molybdenum.

Abstract translation: 已经发现在流化床反应器中使用的含钼氧化催化剂通过从催化剂中的钼损失而部分失活。 这些部分失活的催化剂通过加入由含钼的基本上惰性的载体材料组成的流化床颗粒原位再生。

公开(公告)号：US3551470A

公开(公告)日：1970-12-29

申请号：US3551470D

申请日：1967-12-20

Applicant: STANDARD OIL CO

Inventor： SHAW WILFRID G ,  GRASSELLI ROBERT K ,  HARDMAN HARLEY F

IPC: B01J23/16 ,  B01J23/28 ,  B01J23/31 ,  B01J23/84 ,  B01J23/887 ,  B01J37/02 ,  B01J37/04 ,  C07C5/48 ,  C07C45/35 ,  C22B41/00 ,  C07C121/02

CPC classification number: C22B41/00 ,  B01J23/16 ,  B01J23/28 ,  B01J23/31 ,  B01J23/84 ,  B01J23/8876 ,  B01J37/0201 ,  B01J37/04 ,  B01J2523/00 ,  C07C5/48 ,  C07C45/34 ,  C07C45/35 ,  C07C253/26 ,  Y02P20/52 ,  C07C47/22 ,  B01J2523/397 ,  B01J2523/41 ,  B01J2523/53 ,  B01J2523/68 ,  B01J2523/842 ,  C07C255/08

公开(公告)号：HU181732B

公开(公告)日：1983-11-28

申请号：HU223174

申请日：1974-09-03

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  MILLER ARTHUR F ,  SHAW WILFRID G

IPC: C07C27/14 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J23/887 ,  B01J23/888 ,  B01J23/89 ,  B01J27/192 ,  B01J27/198 ,  B01J27/199 ,  C07B35/04 ,  C07B61/00 ,  C07C5/333 ,  C07C5/48 ,  C07C27/00 ,  C07C27/12 ,  C07C45/00 ,  C07C45/34 ,  C07C45/35 ,  C07C47/20 ,  C07C47/22 ,  C07C51/25 ,  C07C57/05 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  C07B3/00 ,  B01J23/00

Abstract: Catalysts containing at least nickel or cobalt, chromium, bismuth and molybdenum have been found to be especially useful for the ammoxidation of olefins, the oxidation of olefins and the oxidative dehydrogenation of olefins.

公开(公告)号：CA1150731A

公开(公告)日：1983-07-26

申请号：CA377752

申请日：1981-05-15

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID G ,  KUCH PHILIP L ,  PAPARIZOS CHRISTOS

IPC: C07C69/533 ,  B01J27/00 ,  C07B61/00 ,  C07C51/00 ,  C07C51/377 ,  C07C57/03 ,  C07C57/05 ,  C07C67/00 ,  C07C57/04 ,  C07C69/54

Abstract: Olefinic acids and esters such as methacrylic acid and methylmethacrylate, are prepared by contacting in the presence of molecular oxygen the corresponding saturated acid or ester, such as isobutyric acid or methylisobutyrate with the catalyst of the empirical formula Mo12 P0.1-3 M0.1-3 CU0.01-2 V0.01-2 X0.01-2 M' a 0b (I) where M is at least one of K, Rb and Cs; X is at least one of Ba, La, Ca, Al, Ag, Cd, Ti, Tl, HB, Pb and Zn; M' is at least one of Fe, Co, Ni, Sr, Mn, In, Ta, Ge, S and Be when a > 0; a is a number of 0 to about 2; and b is a number that satisfies the valence requirements of the other elements present

公开(公告)号：CA1099250A

公开(公告)日：1981-04-14

申请号：CA288657

申请日：1977-10-13

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  SHAW WILFRID G ,  APPLEQUIST MICHAEL D

IPC: B01J23/28 ,  B01J23/54 ,  B01J23/88 ,  B01J23/887 ,  B01J23/89 ,  B01J27/19 ,  B01J27/198 ,  B01J27/199 ,  B01J27/24 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/05 ,  C07C57/055 ,  C07C67/00 ,  B01J27/14 ,  C07C51/24

Abstract: PROCESS FOR THE PREPARATION OF UNSATURATED ACIDS FROM UNSATURATED ALDEHYDES Methacrylic acid or acrylic acid are produced by the oxidation of methacrolein or acrolein, respectively, with molecular oxygen in the vapor phase in the presence of a catalytic oxide of molybdenum, phosphorus, arsenic, oxygen and the following components delineated in Groups I to III: (I) a rare earth element or mixture thereof, and optionally, at least one of Ag, Tl, Rh, Pd, Ru, Pt, Cd, Al, Au, Cu, alkaline earth metal, Cl and NH4; or (II) at least one element selected from the group consisting of U, Ti, Nb, Re, Pb, Zn and Ga, and optionally, at least one of Cu, a rare earth element, Ag, Ta, In, Th, Cd, Tl, alkaline earth metal, NH4, Cl, Ni, Al, and Ge; or (III) at least one element selected from the group consisting of Ag, Rh, Ru and Au, and optionally, at least one of Cd, Pt, Tl, Pd, Al, Ge, Cu, Ni, alkaline earth metal, NH4 and Cl.

公开(公告)号：CA1090767A

公开(公告)日：1980-12-02

申请号：CA277512

申请日：1977-05-03

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID G ,  TERRILL DAVID B

IPC: B01J23/28 ,  B01J23/30 ,  B01J23/32 ,  B01J23/34 ,  B01J23/36 ,  B01J23/68 ,  B01J23/88 ,  B01J23/887 ,  B01J23/89 ,  B01J27/199 ,  C07C51/25 ,  B01J23/00 ,  C07C57/04

Abstract: PROCESS FOR PRODUCING UNSATURATED ALIPHATIC ACIDS AND CATALYSTS THEREFORE The present invention relates to a process for the production of unsaturated aliphatic acids and the catalyst therefore by the vapor phase oxidation of the corresponding unsaturated aliphatic aldehydes with molecular oxygen, optionally in the presence of steam, in the presence of an oxidation catalyst consisting of the oxides of the elements molybdenum, antimony and vanadium in combination with at least one of the oxides of the element selected from the group consisting of silver, magnesium, thallium and cadmium, and optionally one or more of the oxides of the elements of the group, manganese, cobalt, nickel, copper, iron, tin, chromium, titanium, bismuth, arsenic, phosphorus, rhenium, and zinc.

公开(公告)号：DD132335A5

公开(公告)日：1978-09-20

申请号：DD19872777

申请日：1977-05-03

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID G ,  TERRIL DAVID B ,  MILBERGER ERNEST C ,  WOODBURY DAVID R ,  DOLHYJ SERGE R

IPC: C07D307/60 ,  B01J23/28 ,  B01J23/30 ,  B01J23/31 ,  B01J23/32 ,  B01J23/34 ,  B01J23/36 ,  B01J23/68 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J23/89 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C57/04 ,  B01J21/02 ,  B01J23/16 ,  B01J23/54 ,  B01J23/76 ,  C07C51/32