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公开(公告)号：CA2511017A1
公开(公告)日：2004-07-15
申请号：CA2511017
申请日：2003-12-18
Applicant: SYMYX TECHNOLOGIES INC , HONDA MOTOR CO LTD
Inventor： PHILLIPS CORY BERNARD , BROOKS CHRISTOPHER JAMES , HAGEMEYER ALFRED , CARHART RAYMOND F , LESIK ANDREAS , YACCATO KARIN , HERRMANN MICHAEL
Abstract: A method and catalysts and fuel processing apparatus for producing a hydroge n- rich gas, such as a hydrogen-rich syngas are disclosed. According to the method, a CO-containing gas, such as a syngas, contacts a platinum-free ruthenium-cobalt water gas shift ("WGS") catalyst, in the presence of water and preferably at a temperature of less than about 450~C, to produce a hydrogen-rich gas, such as a hydrogen-rich syngas. Also disclosed is a platinum-free ruthenium-cobalt water gas shift catalyst formulated from: a) Ru, its oxides or mixtures thereof; b) Co, Mo, their oxides or mixtures thereof; and c) at least one of Li, Na, K, Rb, Cs, Ti, Zr, Cr, Fe, La, Ce, E u, their oxides and mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, zeolite, perovskite, silica cla y, yttria and iron oxide. Fuel processors containing such water gas shift catalysts are also disclosed.
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公开(公告)号：WO0204112A3
公开(公告)日：2002-05-16
申请号：PCT/US0121718
申请日：2001-07-09
Applicant: SYMYX TECHNOLOGIES INC
Inventor： HAGEMEYER ALFRED , VOLPE ANTHONY F JR , LEFORT LAURENT , LUGMAIR CLAUS , LOWE DAVID M , LIU YUMIN , BERGH H SAM , GUAN SHENHENG , PINKAS DANIEL M , ENGSTROM JAMES R , SELF KYLE W
CPC classification number: B07B1/00 , B01J19/0046 , B01J35/10 , B01J37/0036 , B01J37/009 , B01J2219/00313 , B01J2219/00319 , B01J2219/00351 , B01J2219/00481 , B01J2219/00484 , B01J2219/00495 , B01J2219/00585 , B01J2219/007 , B01J2219/00704 , B01J2219/00745 , B01J2219/00747 , B01J2219/00756 , B01L3/5025 , B22F2998/00 , C40B30/08 , C40B40/18 , G01N31/10 , B22F9/04
Abstract: Protocols for designing and implementing sets of simultaneous experiments, in a parallel, multi-variable process optimization reactor, are disclosed. The multi-variable process optimization reactor is preferably a parallel flow reactor having the operational capability to simultaneously vary reaction conditions between reaction vessels - either modularly or independently. The simultaneously varied reaction conditions preferably include at least two of the following, in various combinations and permutations: space velocity, contact time, temperature, pressure and feed composition. Compositional variations in the catalysts residing in each of the reaction vessels can also be investigated in the set of simultaneous experiments implemented in the parallel reactor. Sufficient data is obtained from a single set of simultaneous experiments to generate a master curve.
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公开(公告)号：DE60125618T2
公开(公告)日：2007-05-03
申请号：DE60125618
申请日：2001-03-01
Applicant: SYMYX TECHNOLOGIES INC
Inventor： LUGMAIR CLAUS G , POOJARY DAMODARA M , HAGEMEYER ALFRED
Abstract: A method and system for the in situ synthesis of a combinatorial library including impregnating a first component with a second component. The method and system advantageously may be employed in the synthesis of materials for screening for usefulness as a catalyst.
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公开(公告)号：DE60125618D1
公开(公告)日：2007-02-15
申请号：DE60125618
申请日：2001-03-01
Applicant: SYMYX TECHNOLOGIES INC
Inventor： LUGMAIR CLAUS G , POOJARY DAMODARA M , HAGEMEYER ALFRED
Abstract: A method and system for the in situ synthesis of a combinatorial library including impregnating a first component with a second component. The method and system advantageously may be employed in the synthesis of materials for screening for usefulness as a catalyst.
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公开(公告)号：AU2003301060A8
公开(公告)日：2004-07-22
申请号：AU2003301060
申请日：2003-12-18
Applicant: HONDA MOTOR CO LTD , SYMYX TECHNOLOGIES INC
Inventor： HAGEMEYER ALFRED , CARHART RAYMOND F , HERRMANN MICHAEL , YACCATO KARIN , BROOKS CHRISTOPHER JAMES
IPC: B01J19/00 , B01J23/80 , B01J23/835 , B01J23/843 , B01J27/057 , C01B3/00 , C01B3/16 , C01B32/50 , C40B30/08 , C40B40/18 , C40B60/14
Abstract: The invention relates to noble metal-free nickel catalysts that exhibit both high activity and selectivity to hydrogen generation and carbon monoxide oxidation. The noble metal-free water gas shift catalyst of the invention comprises Ni in either a supported or a bulk state and at least one of Ge, Cd, In, Sn, Sb, Te, Pb, their oxides and mixtures thereof.
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Patent Agency Ranking6.发明专利
公开(公告)号：AU2003297472A8
公开(公告)日：2004-07-22
申请号：AU2003297472
申请日：2003-12-18
Applicant: HONDA MOTOR CO LTD , SYMYX TECHNOLOGIES INC
Inventor： YACCATO KARIN , LESIK ANDREAS , BROOKS CHRISTOPHER JAMES , HAGEMEYER ALFRED , CARHART RAYMOND F
Abstract: The invention is directed toward methods of using alkali-containing catalysts for generation of hydrogen-rich gas at temperatures of less than about 260° C. A WGS catalyst of the invention may have the following composition: a) at least one of Pt, Ru, their oxides and mixtures thereof; b) Na, its oxides or mixtures thereof; and optionally, c) Li, its oxides and mixtures thereof. The catalysts may be supported on a variety of catalyst support materials. The invention is also directed toward catalysts that exhibit both high activity and selectivity to hydrogen generation and carbon monoxide oxidation.
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公开(公告)号：AU2003297427A8
公开(公告)日：2004-07-22
申请号：AU2003297427
申请日：2003-12-18
Applicant: SYMYX TECHNOLOGIES INC , HONDA MOTOR CO LTD
Inventor： HAGEMEYER ALFRED , BROOKS CHRISTOPHER JAMES , CARHART RAYMOND F , YACCATO KARIN , LESIK ANDREAS
IPC: B01J19/00 , B01J21/06 , B01J23/42 , B01J23/58 , B01J23/75 , B01J23/89 , B01J37/02 , B01J37/03 , C01B3/16 , C40B30/08 , C40B40/18
Abstract: A method of preparing a platinum-and sodium-containing catalyst comprising : impregnating all non-platinum-and non-sodium-containing components of the catalyst composition onto a surface to form a first surface; impregnating a platinum-containing solution to the first surface to form a platinum-containing surface; calcining the platinum-containing surface to form a calcined platinum containing coating; impregnating a sodium-containing solution to the calcined platinum-containing coating to form a second surface; and drying the second surface.
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公开(公告)号：CA2511173A1
公开(公告)日：2004-07-15
申请号：CA2511173
申请日：2003-12-18
Applicant: SYMYX TECHNOLOGIES INC , HONDA MOTOR CO LTD
Inventor： HAGEMEYER ALFRED , BROOKS CHRISTOPHER JAMES , HERRMANN MICHAEL , YACCATO KARIN , CARHART RAYMOND F
IPC: B01J19/00 , B01J23/80 , B01J23/835 , B01J23/843 , B01J27/057 , C01B3/00 , C01B3/16 , C01B32/50 , C40B30/08 , C40B40/18 , C40B60/14
Abstract: The invention relates to methods of using noble metal-free nickel catalysts to generate a hydrogen-rich gas from gas mixtures containing carbon monoxide an d water, such as water-containing syngas mixtures, where the nickel may exist in either a supported or a bulk state. The noble metal-free water gas shift catalyst of the invention comprises Ni in either a supported or a bulk state and at least one of Ge, Cd, In, Sn, Sb, Te, Pb, their oxides and mixtures thereof. The invention is also directed toward noble metal-free nickel catalysts that exhibit both high activity and selectivity to hydrogen generation and carbon monoxide oxidation.
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公开(公告)号：AU7333101A
公开(公告)日：2002-01-21
申请号：AU7333101
申请日：2001-07-09
Applicant: SYMYX TECHNOLOGIES INC
Inventor： LUGMAIR CLAUS , HAGEMEYER ALFRED , ERDEN LYNN VAN , VOLPE ANTHONY F JR , LOWE DAVID M , LIU YUMIN
Abstract: Methods and apparatus for combinatorial (i.e., high-throughput) materials research, such as catalysis research, that involves parallel apparatus for simultaneously effecting mechanical treatments such as grinding, mixing, pressing, crushing, sieving, and/or fractionating of such materials are disclosed. The methods and apparatus are useful for mechanically treating catalysis materials and other solid materials, including without limitation, electronic materials such as phosphors, colorants such as pigments, and pharmaceuticals such as crystalline drugs or drug candidates. The simultaneous protocols and parallel apparatus offer substantial improvements in overall throughput for preparing arrays of materials, such as catalysis materials.
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公开(公告)号：AU7331701A
公开(公告)日：2002-01-21
申请号：AU7331701
申请日：2001-07-09
Applicant: SYMYX TECHNOLOGIES INC
Inventor： HAGEMEYER ALFRED , VOLPE ANTHONY F JR , LEFORT LAURENT , LUGMAIR CLAUS , LOWE DAVID M , LIU YUMIN , BERGH H SAM , GUAN SHENHENG , PINKAS DANIEL M , ENGSTROM JAMES R , SELF KYLE W
Abstract: Methods and apparatus for combinatorial (i.e., high-throughput) materials research, such as catalysis research, that involves parallel apparatus for simultaneously effecting mechanical treatments such as grinding, mixing, pressing, crushing, sieving, and/or fractionating of such materials are disclosed. The methods and apparatus are useful for mechanically treating catalysis materials and other solid materials, including without limitation, electronic materials such as phosphors, colorants such as pigments, and pharmaceuticals such as crystalline drugs or drug candidates. The simultaneous protocols and parallel apparatus offer substantial improvements in overall throughput for preparing arrays of materials, such as catalysis materials.
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