公开(公告)号：MXPA01008496A

公开(公告)日：2003-06-06

申请号：MXPA01008496

申请日：2000-02-22

Applicant: SYMYX TECHNOLOGIES INC

Inventor： LIU YUMIN

IPC: B01J23/76 ,  B01J23/80 ,  B01J23/83 ,  B01J23/847 ,  C07C5/48 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35

Abstract: Se divulgan catalizadores y metodos para la oxideshidrogenacion de alcanos. Los catalizadores de la invencion comprenden generalmente (i) niquel o bien un compuesto que contiene niquel y (ii) por lo menos uno o varios de los siguientes: titanio (Ti), tantalio (Ta), niobio (Nb), cobalto (Co), hafnio (Hf), tungsteno (W), itrio (Y), zinc (Zn), zirconio (Zr), o aluminio (Al) o bien un compuesto que contiene uno o varios de estos elementos. En modalidades preferidas, el catalizador es un catalizador soportado, el alcano se selecciona dentro del grupo que consiste de: etano, propano, isopropano, isobutano, n-butano y cloruro de etilo, se alimenta conjuntamente oxigeno molecular con el alcano a una zona de reaccion mantenida a una temperatura que se ubica dentro de un rango de aproximadamente 250oC a aproximadamente 350oC, y el etano es deshidrogenado de manera oxidante para formar el alqueno correspondiente con una conversion de alcano de por lo menos aproximadamente 10% y una selectividad de alqueno de por lo menos aproximadamente 70%.

公开(公告)号：AU7333101A

公开(公告)日：2002-01-21

申请号：AU7333101

申请日：2001-07-09

Applicant: SYMYX TECHNOLOGIES INC

Inventor： LUGMAIR CLAUS ,  HAGEMEYER ALFRED ,  ERDEN LYNN VAN ,  VOLPE ANTHONY F JR ,  LOWE DAVID M ,  LIU YUMIN

IPC: B01J19/00 ,  B01J37/00 ,  C40B30/08 ,  C40B40/18 ,  G01N31/10

Abstract: Methods and apparatus for combinatorial (i.e., high-throughput) materials research, such as catalysis research, that involves parallel apparatus for simultaneously effecting mechanical treatments such as grinding, mixing, pressing, crushing, sieving, and/or fractionating of such materials are disclosed. The methods and apparatus are useful for mechanically treating catalysis materials and other solid materials, including without limitation, electronic materials such as phosphors, colorants such as pigments, and pharmaceuticals such as crystalline drugs or drug candidates. The simultaneous protocols and parallel apparatus offer substantial improvements in overall throughput for preparing arrays of materials, such as catalysis materials.

公开(公告)号：AU7331701A

公开(公告)日：2002-01-21

申请号：AU7331701

申请日：2001-07-09

Applicant: SYMYX TECHNOLOGIES INC

Inventor： HAGEMEYER ALFRED ,  VOLPE ANTHONY F JR ,  LEFORT LAURENT ,  LUGMAIR CLAUS ,  LOWE DAVID M ,  LIU YUMIN ,  BERGH H SAM ,  GUAN SHENHENG ,  PINKAS DANIEL M ,  ENGSTROM JAMES R ,  SELF KYLE W

IPC: B01J19/00 ,  B01J37/00 ,  C40B30/08 ,  C40B40/18 ,  G01N31/10

Abstract: Methods and apparatus for combinatorial (i.e., high-throughput) materials research, such as catalysis research, that involves parallel apparatus for simultaneously effecting mechanical treatments such as grinding, mixing, pressing, crushing, sieving, and/or fractionating of such materials are disclosed. The methods and apparatus are useful for mechanically treating catalysis materials and other solid materials, including without limitation, electronic materials such as phosphors, colorants such as pigments, and pharmaceuticals such as crystalline drugs or drug candidates. The simultaneous protocols and parallel apparatus offer substantial improvements in overall throughput for preparing arrays of materials, such as catalysis materials.

公开(公告)号：WO0204112A3

公开(公告)日：2002-05-16

申请号：PCT/US0121718

申请日：2001-07-09

Applicant: SYMYX TECHNOLOGIES INC

Inventor： HAGEMEYER ALFRED ,  VOLPE ANTHONY F JR ,  LEFORT LAURENT ,  LUGMAIR CLAUS ,  LOWE DAVID M ,  LIU YUMIN ,  BERGH H SAM ,  GUAN SHENHENG ,  PINKAS DANIEL M ,  ENGSTROM JAMES R ,  SELF KYLE W

IPC: B01J19/00 ,  B01J37/00 ,  C40B30/08 ,  C40B40/18 ,  G01N31/10

CPC classification number: B07B1/00 ,  B01J19/0046 ,  B01J35/10 ,  B01J37/0036 ,  B01J37/009 ,  B01J2219/00313 ,  B01J2219/00319 ,  B01J2219/00351 ,  B01J2219/00481 ,  B01J2219/00484 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/007 ,  B01J2219/00704 ,  B01J2219/00745 ,  B01J2219/00747 ,  B01J2219/00756 ,  B01L3/5025 ,  B22F2998/00 ,  C40B30/08 ,  C40B40/18 ,  G01N31/10 ,  B22F9/04

Abstract: Protocols for designing and implementing sets of simultaneous experiments, in a parallel, multi-variable process optimization reactor, are disclosed. The multi-variable process optimization reactor is preferably a parallel flow reactor having the operational capability to simultaneously vary reaction conditions between reaction vessels - either modularly or independently. The simultaneously varied reaction conditions preferably include at least two of the following, in various combinations and permutations: space velocity, contact time, temperature, pressure and feed composition. Compositional variations in the catalysts residing in each of the reaction vessels can also be investigated in the set of simultaneous experiments implemented in the parallel reactor. Sufficient data is obtained from a single set of simultaneous experiments to generate a master curve.

公开(公告)号：AU3601900A

公开(公告)日：2000-09-04

申请号：AU3601900

申请日：2000-02-22

Applicant: SYMYX TECHNOLOGIES INC

Inventor： LIU YUMIN

IPC: B01J23/76 ,  B01J23/80 ,  B01J23/83 ,  B01J23/847 ,  C07C5/48 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  B01J23/755 ,  C01G53/04

Abstract: Catalysts and methods for alkane oxydehydrogenation are disclosed. The catalysts of the invention generally comprise (i) nickel or a nickel-containing compound and (ii) at least one or more of titanium (Ti), tantalum (Ta), niobium (Nb), hafnium (Hf), tungsten (W), yttrium (Y), zinc (Zn), zirconium (Zr), or aluminum (Al), or a compound containing one or more of such element(s). In preferred embodiments, the catalyst is a supported catalyst, the alkane is selected from the group consisting of ethane, propane, isobutane, n-butane and ethyl chloride, molecular oxygen is co-fed with the alkane to a reaction zone maintained at a temperature ranging from about 250° C. to about 350° C., and the ethane is oxidatively dehydrogenated to form the corresponding alkene with an alkane conversion of at least about 10% and an alkene selectivity of at least about 70%.

公开(公告)号：WO0204121A3

公开(公告)日：2003-01-03

申请号：PCT/US0121771

申请日：2001-07-09

Applicant: SYMYX TECHNOLOGIES INC

Inventor： LUGMAIR CLAUS ,  HAGEMEYER ALFRED ,  VANERDEN LYNN ,  VOLPE ANTHONY F JR ,  LOWE DAVID M ,  LIU YUMIN

IPC: B01J19/00 ,  B01J37/00 ,  C40B30/08 ,  C40B40/18 ,  G01N31/10

CPC classification number: B07B1/00 ,  B01J19/0046 ,  B01J35/10 ,  B01J37/0036 ,  B01J37/009 ,  B01J2219/00313 ,  B01J2219/00319 ,  B01J2219/00351 ,  B01J2219/00481 ,  B01J2219/00484 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/007 ,  B01J2219/00704 ,  B01J2219/00745 ,  B01J2219/00747 ,  B01J2219/00756 ,  B01L3/5025 ,  B22F2998/00 ,  C40B30/08 ,  C40B40/18 ,  G01N31/10 ,  B22F9/04

Abstract: Methods and apparatus for combinatorial (i.e., high-throughput) materials research, such as catalysis research, that involves parallel apparatus for simultaneously effecting mechanical treatments such as grinding, mixing, pressing, crushing, sieving, and/or fractionating of such materials are disclosed. The methods and apparatus are useful for mechanically treating catalysis materials and other solid materials, including without limitation, electronic materials such as phosphors, colorants such as pigments, and pharmaceuticals such as crystalline drugs or drug candidates. The simultaneous protocols and parallel apparatus offer substantial improvements in overall throughput for preparing arrays of materials, such as catalysis materials.

Abstract translation: 公开了用于组合（即，高通量）材料研究的方法和装置，例如催化研究，其涉及用于同时进行诸如研磨，混合，压制，压碎，筛分和/或分级的机械处理的并行装置。 。 所述方法和装置可用于机械处理催化材料和其它固体材料，包括但不限于电子材料如磷光体，着色剂如颜料，以及药物如结晶药物或药物候选物。 同时协议和并行设备在制备材料阵列（例如催化材料）方面提供总体通量的显着改进。

公开(公告)号：WO0204112A9

公开(公告)日：2002-10-10

申请号：PCT/US0121718

申请日：2001-07-09

Applicant: SYMYX TECHNOLOGIES INC

Inventor： HAGEMEYER ALFRED ,  VOLPE ANTHONY F JR ,  LEFORT LAURENT ,  LUGMAIR CLAUS ,  LOWE DAVID M ,  LIU YUMIN ,  BERGH H SAM ,  GUAN SHENHENG ,  PINKAS DANIEL M ,  ENGSTROM JAMES R ,  SELF KYLE W

IPC: B01J19/00 ,  B01J37/00 ,  C40B30/08 ,  C40B40/18 ,  G01N31/10

CPC classification number: B07B1/00 ,  B01J19/0046 ,  B01J35/10 ,  B01J37/0036 ,  B01J37/009 ,  B01J2219/00313 ,  B01J2219/00319 ,  B01J2219/00351 ,  B01J2219/00481 ,  B01J2219/00484 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/007 ,  B01J2219/00704 ,  B01J2219/00745 ,  B01J2219/00747 ,  B01J2219/00756 ,  B01L3/5025 ,  B22F2998/00 ,  C40B30/08 ,  C40B40/18 ,  G01N31/10 ,  B22F9/04

Abstract: Protocols for designing and implementing sets of simultaneous experiments, in a parallel, multi-variable process optimization reactor, are disclosed. The multi-variable process optimization reactor is preferably a parallel flow reactor having the operational capability to simultaneously vary reaction conditions between reaction vessels - either modularly or independently. The simultaneously varied reaction conditions preferably include at least two of the following, in various combinations and permutations: space velocity, contact time, temperature, pressure and feed composition. Compositional variations in the catalysts residing in each of the reaction vessels can also be investigated in the set of simultaneous experiments implemented in the parallel reactor. Sufficient data is obtained from a single set of simultaneous experiments to generate a master curve.

Abstract translation: 公开了在并行，多变量过程优化反应器中设计和实施多组同时进行的实验的协议。 多变量过程优化反应器优选是具有操作能力的并流反应器，以便同时改变反应容器之间的反应条件 - 模块化或独立。 同时改变的反应条件优选包括以下各项中的至少两种，以各种组合和置换：空间速度，接触时间，温度，压力和进料组成。 驻留在每个反应容器中的催化剂的组成变化也可以在平行反应器中实施的一组同时实验中进行研究。 从一组同时进行的实验中获得足够的数据以生成主曲线。

公开(公告)号：CA2363035C

公开(公告)日：2007-09-04

申请号：CA2363035

申请日：2000-02-22

Applicant: SYMYX TECHNOLOGIES INC

Inventor： LIU YUMIN

IPC: C07C5/48 ,  B01J23/755 ,  B01J23/76 ,  B01J23/80 ,  B01J23/83 ,  B01J23/847 ,  C01G53/04 ,  C07C17/357 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35

Abstract: Catalysts and methods for alkane oxydehydrogenation are disclosed. The catalysts of the invention generally comprise (i) nickel or a nickel-containing compound and (ii) at least one or more of titanium (Ti), tantalum (Ta), niobium (Nb), cobalt (Co), hafnium (Hf), tungsten (W), yttrium (Y), zinc (Zn), zirconium (Zr), or aluminum (Al), or a compound containing one or more of such element(s). In preferred embodiments, the catalyst is a supported catalyst, the alkane is selected fr om the group consisting of ethane, propane, isopropane, isobutane, n-butane and ethyl chloride, molecular oxygen is co-fed with the alkane to a reaction zone maintained at a temperature ranging from about 250 .degree.C to about 350 .degree.C, and the ethane is oxidatively dehydrogenated to form the corresponding the alkene with an alkane conversio n of at least about 10 % and an alkene selectivity of at least about 70 %.

公开(公告)号：CA2363035A1

公开(公告)日：2000-08-24

申请号：CA2363035

申请日：2000-02-22

Applicant: SYMYX TECHNOLOGIES INC

Inventor： LIU YUMIN

IPC: B01J23/76 ,  B01J23/80 ,  B01J23/83 ,  B01J23/847 ,  C07C5/48 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C01G53/04 ,  B01J23/755

Abstract: Catalysts and methods for alkane oxydehydrogenation are disclosed. The catalysts of the invention generally comprise (i) nickel or a nickel- containing compound and (ii) at least one or more of titanium (Ti), tantalum (Ta), niobium (Nb), cobalt (Co), hafnium (Hf), tungsten (W), yttrium (Y), zi nc (Zn), zirconium (Zr), or aluminum (Al), or a compound containing one or more of such element(s). In preferred embodiments, the catalyst is a supported catalyst, the alkane is selected from the group consisting of ethane, propan e, isopropane, isobutane, n-butane and ethyl chloride, molecular oxygen is co-f ed with the alkane to a reaction zone maintained at a temperature ranging from about 250 ~C to about 350 ~C, and the ethane is oxidatively dehydrogenated t o form the corresponding the alkene with an alkane conversion of at least abou t 10 % and an alkene selectivity of at least about 70 %.