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公开(公告)号：DE3170547D1
公开(公告)日：1985-06-20
申请号：DE3170547
申请日：1981-11-24
Applicant: TORAY INDUSTRIES
Inventor： ASAKURA TOSHIYUKI , KOBAYASHI HIROAKI , NOGUCHI YUKIO
Abstract: A stabilized polyphenylene sulfide is provided which comprises a recurring unit wherein the average n between foreign units is greater than about 5, and about 0.05 to about 10 mole % per phenylene sulfide unit of an aromatic constituent chemically bonded with said polyphenylene sulfide chain, said aromatic constituent containing an electron attractive group selected from the group consisting of -SO2-, -CO-, -NO2, -SO3R, -COOR, wherein R is H, lower aliphatic hydrocarbon groups, aromatic hydrocarbon groups or alkaline metals, and -CONH-, and said stabilized polyphenylene sulfide has a melting point in the range of about 250 DEG C. to about 350 DEG C. Also provided is a method for preparing stabilized polyphenylene sulfide comprising preparing a polyphenylene sulfide consisting mainly of a recurring unit wherein the degree of polymerization of said recurring unit is greater than about 20, and reacting said polyphenylene sulfide with about 0.05 to about 20 mole % per said phenylene sulfide unit of a halogenated aromatic compound having an electron attractive group.
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公开(公告)号：DE3107562A1
公开(公告)日：1982-10-14
申请号：DE3107562
申请日：1981-02-27
Applicant: TORAY INDUSTRIES
Inventor： DEGUCHI YUKICHI , NOGUCHI YUKIO , KOBAYASHI HIROAKI
IPC: C08G75/0209 , C08G75/0213 , C08G75/0254 , C08G75/0277 , C08G75/0281 , C08J5/18 , H05K1/03 , C08L81/04 , B32B15/08
Abstract: A film material essentially comprising a high-molecular-weight poly-p-phenyl sulphide, where, on extraction with chloroform, the amount of extract therefrom is less than 1.5% by weight of the total weight before extraction, and its crystallinity index is greater than 2.5 and less than 8.0, its crystal size is greater than 5 x 10 cm and less than 10 x 10 cm, and its orientation factors, measured perpendicular to the film plane and in the transverse and longitudinal directions, are in each case greater than 0.70, measured by wide-angle X-ray diffraction. The film material is particularly suitable for use for printed circuits, in which case it is coated with a thin metal foil.
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公开(公告)号：DE2916841A1
公开(公告)日：1979-11-08
申请号：DE2916841
申请日：1979-04-26
Applicant: TORAY INDUSTRIES
Inventor： ASAKURA TOSHIYUKI , NOGUCHI YUKIO , KOBAYASHI HIROAKI
Abstract: A biaxially oriented poly-p-phenylene sulfide film comprising recurring units of the formula a melt viscosity of more than 100 poise and less than 600,000 poise at a shear rate of 200 sec-1 and at 300 DEG C., and a specific gravity of which is more than 1.330 and less than 1.400. The film has improved mechanical properties, thermal dimensional stability and high temperature durability. Typical applications of the film are as electrical insulation, capacitor, magnetic recording medium, packaging material, and so forth.
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公开(公告)号：HK1007323A1
公开(公告)日：1999-04-09
申请号：HK98106576
申请日：1998-06-25
Applicant: TORAY INDUSTRIES
Inventor： DEGUCHI YUKICHI , NOGUCHI YUKIO , SUDO MASAAKI , ITO KIYOHIKO
IPC: B29C47/10 , C08G75/02 , C08G75/0209 , C08J5/18 , C08K7/18 , G11B5/73 , G11B5/84 , H01B3/30 , H01G4/18 , C08J , B29C , H01G , G11B
Abstract: A polyphenylene sulfide film formed from a resin composition mainly composed of polyphenylene sulfide, characterized in that fine particles of 0.05 to 3 mu m in the mean particle size are dispersed in the film and a single particle index of said fine particle is 0.5 or more. This film is useful as dielectric film for film capacitors having stabilized initial properties by virtue of its excellent sliding properties and largely reduced electrical insulation defects. Furthermore, it is also useful as the base film for a magnetic recording medium having excellent electromagnetic transduction properties and reduced dropout by virtue of its excellent sliding properties and surface smoothness.
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公开(公告)号：DE68922699D1
公开(公告)日：1995-06-22
申请号：DE68922699
申请日：1989-03-07
Applicant: TORAY INDUSTRIES
Inventor： DEGUCHI YUKICHI , NOGUCHI YUKIO , SUDO MASAAKI , ITO KIYOHIKO
IPC: B29C47/10 , C08G75/02 , C08G75/0209 , C08J5/18 , C08K7/18 , G11B5/73 , G11B5/84 , H01B3/30 , H01G4/18 , G11B5/704
Abstract: A polyphenylene sulfide film formed from a resin composition mainly composed of polyphenylene sulfide, characterized in that fine particles of 0.05 to 3 mu m in the mean particle size are dispersed in the film and a single particle index of said fine particle is 0.5 or more. This film is useful as dielectric film for film capacitors having stabilized initial properties by virtue of its excellent sliding properties and largely reduced electrical insulation defects. Furthermore, it is also useful as the base film for a magnetic recording medium having excellent electromagnetic transduction properties and reduced dropout by virtue of its excellent sliding properties and surface smoothness.
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Patent Agency Ranking
公开(公告)号：FR2500841A1
公开(公告)日：1982-09-03
申请号：FR8103999
申请日：1981-02-27
Applicant: TORAY INDUSTRIES
Inventor： DEGUCHI YUKICHI , NOGUCHI YUKIO , KOBAYASHI HIROAKI
IPC: C08G75/02 , C08G75/0209 , C08G75/0213 , C08G75/0254 , C08G75/0277 , C08G75/0281 , H01B3/30 , H05K1/03 , C08L81/04 , B29D7/02
Abstract: Sheet of high mole wt poly p-phenylene sulphide (PPS) has an index of crystallinity of 2.5-8.0, a crystallite size of 50-100 Angstroms and orientation factors above 0.70 in each of the through, Edge and End directions as measured by wide angle X-ray diffraction. Less than 1.5 wt% of the sheet can be extracted by chloroform. Sheet can be laminated to a thin metallic film to produce a printed circuit board. The PPS has better flexibility and impact resistance than known sheets of PPS, with less resk of cracking when boring or drilling holes through it.
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公开(公告)号：FR2433029A1
公开(公告)日：1980-03-07
申请号：FR7910940
申请日：1979-04-27
Applicant: TORAY INDUSTRIES
Inventor： ASAKURA TOSHIYUKI , NOGUCHI YUKIO , KOBAYASHI HIROAKI
IPC: C08G75/02 , C08G75/0209 , C08J5/18 , G11B5/73 , H01B3/30 , C08G75/14 , B29D7/22 , B29D7/24 , H01G4/18
Abstract: A biaxially oriented poly-p-phenylene sulfide film comprising recurring units of the formula a melt viscosity of more than 100 poise and less than 600,000 poise at a shear rate of 200 sec-1 and at 300 DEG C., and a specific gravity of which is more than 1.330 and less than 1.400. The film has improved mechanical properties, thermal dimensional stability and high temperature durability. Typical applications of the film are as electrical insulation, capacitor, magnetic recording medium, packaging material, and so forth.
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公开(公告)号：DE68922699T2
公开(公告)日：1996-02-22
申请号：DE68922699
申请日：1989-03-07
Applicant: TORAY INDUSTRIES
Inventor： DEGUCHI YUKICHI , NOGUCHI YUKIO , SUDO MASAAKI , ITO KIYOHIKO
IPC: B29C47/10 , C08G75/02 , C08G75/0209 , C08J5/18 , C08K7/18 , G11B5/73 , G11B5/84 , H01B3/30 , H01G4/18 , G11B5/704
Abstract: A polyphenylene sulfide film formed from a resin composition mainly composed of polyphenylene sulfide, characterized in that fine particles of 0.05 to 3 mu m in the mean particle size are dispersed in the film and a single particle index of said fine particle is 0.5 or more. This film is useful as dielectric film for film capacitors having stabilized initial properties by virtue of its excellent sliding properties and largely reduced electrical insulation defects. Furthermore, it is also useful as the base film for a magnetic recording medium having excellent electromagnetic transduction properties and reduced dropout by virtue of its excellent sliding properties and surface smoothness.
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公开(公告)号：DE3107562C2
公开(公告)日：1995-09-28
申请号：DE3107562
申请日：1981-02-27
Applicant: TORAY INDUSTRIES
Inventor： DEGUCHI YUKICHI , NOGUCHI YUKIO , KOBAYASHI HIROAKI
IPC: C08G75/0209 , C08G75/0213 , C08G75/0254 , C08G75/0277 , C08G75/0281 , C08J5/18 , H05K1/03 , C08L81/02
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公开(公告)号：JPH06322150A
公开(公告)日：1994-11-22
申请号：JP10699593
申请日：1993-05-07
Applicant: TORAY INDUSTRIES
Inventor： KIDA KENJI , NOGUCHI YUKIO , UEDA TOMOAKI
Abstract: PURPOSE:To obtain the subject film, containing a specific amount of high- melting polyphenylene sulfide nuclei, excellent in abrasion resistance, surface smoothness and slipperiness and useful as a material for dielectrics, electrical insulators, etc., for capacitors. CONSTITUTION:The objective film comprises 1000-1000000nuclei/g film of a high-melting polyphenylene sulfide, containing at least >=90mol% recurring unit composed of the p-phenylene sulfide and having 1-3mum diameter without melting at 300 deg.C.
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