Abstract:
The present invention provides a novel 7a-alkoxy-4H-pyrano-Ä3,2-dÜ-oxazol-2(3H)-one represented by the formula (I): wherein R and R each represent a hydrogen atom, an alkyl group, an alkenyl group, an aryl group or an aralkyl group; R represents an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group or an aralkyl group, provided that a 2-alkenyl group is excluded from the alkenyl group of R ; and R represents an alkyl group, an aryl group, an alkoxycarbonyl group or a cyano group, and a process for producing the same which comprises reacting 5-alkoxy-2(3H)-oxazolone with an alpha , beta -unsaturated ketone in the presence of a Lewis acid in a solvent.
Abstract:
The present invention provides a novel 7a-alkoxy-4H-pyrano-Ä3,2-dÜ-oxazol-2(3H)-one represented by the formula (I): wherein R and R each represent a hydrogen atom, an alkyl group, an alkenyl group, an aryl group or an aralkyl group; R represents an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group or an aralkyl group, provided that a 2-alkenyl group is excluded from the alkenyl group of R ; and R represents an alkyl group, an aryl group, an alkoxycarbonyl group or a cyano group, and a process for producing the same which comprises reacting 5-alkoxy-2(3H)-oxazolone with an alpha , beta -unsaturated ketone in the presence of a Lewis acid in a solvent.
Abstract:
An object of the present invention is to provide a benzobis(thiadiazole) derivative, which has an excellent mobility of electron (field-effect mobility) and also has an excellent stability in the atmosphere. The present invention relates to a benzobis(thiadiazole) derivative or the like, which has cyclic imide structures annelated to an aromatic ring in the molecule, represented by the following general formula (1) or (2) wherein R, A and Z represent predetermined groups.
Abstract:
The present invention relates to a benzobis(thiadiazole) derivative represented by the following general formula (1): wherein R 1 represents a linear or branched alkyl group, or any one of the groups of the following formula (2): wherein R represents a linear or branched alkyl group; R 2 represents a hydrogen atom; and R 3 represents a hydrogen atom, a linear or branched alkyl group, or any one of the groups of the formula (2); with the proviso that at least one of R 1 and R 3 represents any one of the groups of the formula (2); and two R 1 groups, two R 2 groups, and two R 3 groups may be the same as, or different from each other.
Abstract:
A process for producing 4-alkoxycarbonyl-2-oxazolidinone compounds of general formula (III) (wherein R1 is H, alkyl, cycloalkyl, alkenyl or phenyl; R2 is H, alkyl, phenyl or alkenyl; R3 is alkyl, cycloalkyl, alkenyl or phenyl; and R4 is H, alkyl, alkenyl, cycloalkyl, alkynyl, aryl, 5- or 6-membered heteroaryl, alkoxycarbonyl, acetyl or benzoy1), characterized by reacting a 5-alkoxy-2(3H)-oxazolone compound of general formula (I) (wherein R?1, R2 and R3¿ are each as defined above) with an aldehyde compound of the general formula (II): R4CHO (wherein R4 is as defined above) in the presence of a Lewis acid catalyst.
Abstract:
PROBLEM TO BE SOLVED: To provide a method for producing a vicinal diol compound from the corresponding epoxy compound with easy separation of the catalyst and under mild conditions with slight production of impurities. SOLUTION: This method for producing a vicinal diol compound is characterized by comprising contacting the corresponding epoxy compound with a readily available activated alumina and water.
Abstract:
PURPOSE:To reduce hygroscopicity and to improve reliability in the liquid crystal display panel by sticking a rectangular glass rod to the peripheral edge part of bases to seal the inside of the bases. CONSTITUTION:A medium layer 4 formed by dispersing a medium in liquid crystal is held between two bases 1, 2 on which transparent electrodes are formed so that both the electrodes are opposed to each other. The rectangular glass rod 2 is arranged on the peripheral edge part of the bases 1, 5 and stuck to the edge part with a bonding agent 3. A hot melt group bonding agent is used as the bonding agent 3 for sticking the glass rod 2.