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公开(公告)号：WO0168250A3
公开(公告)日：2002-01-31
申请号：PCT/US0108173
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAX MIN , MAHER JOHN MICHAEL
IPC: B01D11/04 , B01J23/46 , B01J31/18 , B01J31/24 , B01J31/40 , B01J38/00 , C07B61/00 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/19 , C07F9/02
CPC classification number: C07C45/50 , C07B63/00 , Y02P20/582 , C07C47/02
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organosphosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
Abstract translation: 本发明涉及从连续生成的反应产物流体中分离一种或多种有机磷配体降解产物，一种或多种反应副产物和一种或多种产物，所述反应产物流体包含一种或多种未反应的反应物，金属 - 有机磷配体络合物催化剂， 有机磷配体，所述一种或多种有机磷配体降解产物，所述一种或多种反应副产物，所述一种或多种产物，一种或多种非极性溶剂和一种或多种极性溶剂通过相分离，其中（i）非极性相的选择性为 相对于一种或多种产物的有机磷配体由分配系数比Ef1表示，分配系数比Ef1是大于约2.5的值，（ii）非极性相对有机磷配体相对于一种或多种有机磷配体的选择性 降解产物由分配系数比Ef2表示，分配系数比Ef2是值gre 高于约2.5，以及（iii）非极性相对于一种或多种反应副产物的有机磷配体的选择性由大于约2.5的值的分配系数比Ef3表示。
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公开(公告)号：AT314335T
公开(公告)日：2006-01-15
申请号：AT01922386
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAX MIN , MAHER JOHN MICHAEL
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more polar solvents and one or more nonpolar solvents by phase separation wherein (i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
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公开(公告)号：BR0109216A
公开(公告)日：2002-12-03
申请号：BR0109216
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAX MIN , MAHER JOHN MICHAEL
IPC: B01D11/04 , B01J23/46 , B01J31/18 , B01J31/24 , B01J31/40 , B01J38/00 , C07B61/00 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/19 , C07F9/02 , B01J31/00
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
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公开(公告)号：AU4571801A
公开(公告)日：2001-09-24
申请号：AU4571801
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAX MIN , MAHER JOHN MICHAEL
IPC: B01D11/04 , B01J23/46 , B01J31/18 , B01J31/24 , B01J31/40 , B01J38/00 , C07B61/00 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/19 , C07F9/02 , B01J31/00
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
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公开(公告)号：MXPA02009086A
公开(公告)日：2003-05-23
申请号：MXPA02009086
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： BRYANT DAVID ROBERT , MORRISON DONALD LEE , FOLEY PAUL , ARGYROPOULOS JOHN NICHOLAS , ROESCH BRIAN MICHAEL , KANEL JEFFREY SCOTT , BRIGGS JOHN ROBERT , MAHER JOHN MICHAEL , PHILLIPS AILENE GARDNER , LEE MAX MIN , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES
IPC: B01D11/04 , B01J23/46 , B01J31/18 , B01J31/24 , B01J31/40 , B01J38/00 , C07B61/00 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/19 , C07F9/02
Abstract: Esta invencion se refiere a un proceso para separar uno o mas productos de degradacion de ligandos de organofosforo, uno o mas subproductos de reaccion, y uno o mas productos a partir de un fluido de producto de reaccion continuamente generado que comprende uno o mas reactivos sin reaccionar, un catalizador de complejo de ligando de metal-organofosforo, opcionalmente un ligando de organofosforo libre, los uno o mas productos de degradacion de ligandos de organofosforo, los uno o mas subproductos de reaccion, los uno o mas productos, uno o mas solventes no polares, y uno o mas solventes polares, mediante separacion de fases, en donde: (i) la selectividad de la fase no polar para el ligando de organofosforo con respecto a los uno o mas productos se expresa mediante una relacion de coeficiente de division Ef1, que es un valor mayor a aproximadamente 2.5, (ii) la selectividad de la fase no polar para el ligando de organofosforo con respecto a los uno o mas productos de 30 degradacion de ligandos de organofosforo se expresa mediante una relacion de coeficiente de division Ef2 que es un valor mayor a aproximadamente 2.5, y (iii) la selectividad de la fase no polar para el ligando de organofosforo con respecto a los uno o mas subproductos de reaccion se expresa mediante una relacion de coeficiente de division Ef3 que es un valor mayor a aproximadamente 2.5.
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Patent Agency Ranking
公开(公告)号：NO20024358A
公开(公告)日：2002-11-13
申请号：NO20024358
申请日：2002-09-12
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAX MIN , MAHER JOHN MICHAEL
CPC classification number: C07C45/50 , C07B63/00 , Y02P20/582 , C07C47/02
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公开(公告)号：AU2001245718B2
公开(公告)日：2004-12-02
申请号：AU2001245718
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： MAHER JOHN MICHAEL , LEE MAX MIN , BRIGGS JOHN ROBERT , ROESCH BRIAN MICHAEL , PHILLIPS AILENE GARDNER , BRYANT DAVID ROBERT , FOLEY PAUL , MORRISON DONALD LEE , MILLER DAVID JAMES , TULCHINSKY MICHAEL LEO , KANEL JEFFREY SCOTT , ARGYROPOULOS JOHN NICHOLAS
IPC: B01D11/04 , B01J23/46 , B01J31/18 , B01J31/24 , B01J31/40 , B01J38/00 , C07B61/00 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/19 , C07F9/02 , B01J031/00
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
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公开(公告)号：NO20024358L
公开(公告)日：2002-11-13
申请号：NO20024358
申请日：2002-09-12
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAX MIN , MAHER JOHN MICHAEL
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more polar solvents and one or more nonpolar solvents by phase separation wherein (i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
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公开(公告)号：NO20024359D0
公开(公告)日：2002-09-12
申请号：NO20024359
申请日：2002-09-12
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAX MIN , MAHER JOHN MICHAEL
IPC: B01D11/04 , B01J23/46 , B01J31/18 , B01J31/24 , B01J31/40 , B01J38/00 , C07B61/00 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/19 , C07F9/02 , B01J
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
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公开(公告)号：CA2403091A1
公开(公告)日：2001-09-20
申请号：CA2403091
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： BRYANT DAVID ROBERT , MORRISON DONALD LEE , FOLEY PAUL , ARGYROPOULOS JOHN NICHOLAS , ROESCH BRIAN MICHAEL , KANEL JEFFREY SCOTT , BRIGGS JOHN ROBERT , MAHER JOHN MICHAEL , PHILLIPS AILENE GARDNER , LEE MAX MIN , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES
IPC: B01D11/04 , B01J23/46 , B01J31/18 , B01J31/24 , B01J31/40 , B01J38/00 , C07B61/00 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/19 , C07F9/02
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
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