Abstract:
A holographic grating spectrophotometer for detecting ozone and sulphur dioxide in the atmosphere is described which provides automatic calibration and which provides automatic linearity correction for the photomultiplier tube. Automatic calibration is provided by using a computer to control a stepper motor to move the grating so that the photomultiplier tube receives maximum intensity at the calibration wavelength of 302.1 nm from a mercury source. Automatic linearity correction is obtained by cycling a wavelength selection mask across exit slits located in the focal plane of the device and firstly combines separately taken counts of two different wavelengths and comparing this sum with the sum of counts of these wavelengths taken simultaneously. The difference is used to calculate photomultiplier tube deadtime and improve accuracy of the results. In a preferred embodiment five wavelengths are used to calculate ozone and sulphur dioxide levels, and a stepper motor driving a cylindrical wavelength selection mask permits exit slits to be exposed to predetermined wavelengths one at a time.
Abstract:
In a spectrophotometric instrument, a system is provided to correct for distortion caused by rapid scanning of the spectrum. In the instrument, photodetectors (19) detect light energy which is scanned through a spectrum at a rapid rate. An amplifier (20) amplifies the output signal generated by the photodetectors (19). The output signal of the amplifier (20) is sampled at increments and the samples are converted to digital values. A first derivative is determined from the digital values by subtracting from each value the value from the preceding increment. The first derivative values are multiplied times a constant selected to correct for the distortion and the resulting product values are added to the amplitude digital values to provide a set of corrected values representing the intensity detected by the photodetectors.
Abstract:
There is provided an optical measurement method using a detector having a detection sensitivity to at least a near-infrared region. The optical measurement method including: obtaining an output value by measuring a light sample at any exposure time with the detector; and correcting the output value with an amount of correction corresponding to the output value, when the exposure time at which the output value is obtained is within a second range. The amount of correction includes a product of a coefficient and a square of the exposure time, the coefficient indicating a degree to which an output value obtained when the light sample is measured with the detector at an exposure time within the second range deviates from output linearity obtained when the light sample is measured with the detector at an exposure time within a first range.
Abstract:
A reference light source device for calibration of a spectral radiance meter includes an integrating sphere having a radiance reference plane, which is an opening; and a plurality of first optical ports, which are formed apart from each other in an outer wall of the integrating sphere to allow light rays with equivalent wavelength characteristics to enter an interior of the integrating sphere.
Abstract:
In a spectrophotometric instrument, a system is provided to correct for distortion caused by rapid scanning of the spectrum. In the instrument, photodetectors detect light energy which is scanned through a spectrum at a rapid rate. An amplifier amplifies the output signal generated by the photodetectors. The output signal of the amplifier is sampled at increments and the samples are converted to digital values. A first derivative is determined from the digital values by subtracting from each value the value from the preceding increment. The first derivative values are multiplied times a constant selected to correct for the distortion and the resulting product values are added to the amplitude digital values to provide a set of corrected values representing the intensity detected by the photodetectors.
Abstract:
A spectrometer for tailored spectral sampling includes a dispersive element for spatially dispersing a spectrum of a light beam, a detector including a plurality of pixels distributed along a sampling direction, and a spectrum reshaping element including at least one of a reflective surface or a transmissive surface for reshaping the spatially-dispersed spectrum of the light beam from the dispersive element along the sampling direction to provide a selected distribution of the spectrum to the detector. The detector may spatially sample the spectrum of incident light with the plurality of pixels at selected spectral intervals based on the selected distribution of the spectrum.