公开(公告)号：US20230278013A1

公开(公告)日：2023-09-07

申请号：US17860143

申请日：2022-07-08

Applicant: NOVA Chemicals (International) S.A.

Inventor： Vasily Simanzhenkov ,  Xiaoliang Gao ,  Marie Barnes ,  David Sullivan ,  Yoonhee Kim

IPC: B01J23/28 ,  B01J21/04 ,  B01J23/00 ,  B01J37/08 ,  C07C5/48

CPC classification number: B01J23/28 ,  B01J21/04 ,  B01J23/002 ,  B01J37/08 ,  C07C5/48 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68 ,  C07C2521/04 ,  C07C2523/20 ,  C07C2523/22 ,  C07C2523/28 ,  C07C2523/32

Abstract: Provided in this disclosure are catalyst compositions. The catalyst compositions include an oxidative dehydrogenation catalyst that includes a mixed metal oxide having the empirical formula:


Mo1.0V0.12-0.49Te0.05-0.17Nb0.10-0.20AlcOd

wherein c is from 0 to 2.0 and d is a number to satisfy the valence of the oxide. The compositions are at least 40 wt. % amorphous as measured by XRD. The disclosure also provides methods of making the compositions.

公开(公告)号：US20230271170A1

公开(公告)日：2023-08-31

申请号：US18108810

申请日：2023-02-13

Applicant: EcoCatalytic Inc.

Inventor： John A. SOFRANKO

IPC: B01J27/055 ,  B01J8/18 ,  B01J8/26 ,  B01J27/25 ,  B01J21/08 ,  B01J29/08 ,  B01J23/34 ,  B01J37/02 ,  B01J37/08 ,  C07C5/48

CPC classification number: B01J27/055 ,  B01J8/1827 ,  B01J8/26 ,  B01J21/08 ,  B01J23/34 ,  B01J27/25 ,  B01J29/084 ,  B01J37/0213 ,  B01J37/08 ,  C07C5/48 ,  C07C2521/08 ,  C07C2523/34 ,  C07C2527/055 ,  C07C2527/25 ,  C07C2529/08

Abstract: An oxide of sulfur oxygen transfer reagent is provided. A method of producing olefins from hydrocarbons with a concomitant production of water (oxidative dehydrogenation), using the oxide of sulfur oxygen transfer reagent is also provided. The sulfur oxygen transfer reagent can be used as an oxygen transfer reagent, and therefore acts as a non-metal carrier, for oxygen in a redox looping reactor for an oxidative dehydrogenation process such as the conversion of ethane to ethylene. The reduced forms of oxides of sulfur, formed in in this oxidative dehydrogenation process, can be re-oxidized with air and generate useful process heat. Also provided are methods of using the oxide of sulfur oxygen transfer reagent, and an apparatus for effecting the oxidative dehydrogenation of the hydrocarbon feed. Methods of producing the oxide of sulfur oxygen transfer reagent are also provided.

公开(公告)号：US20230271164A1

公开(公告)日：2023-08-31

申请号：US17924423

申请日：2021-04-19

Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.

Inventor： Daishi FUJINO

IPC: B01J23/10 ,  C01G25/00 ,  B01J23/44 ,  B01J35/04 ,  B01J35/00 ,  B01J37/06 ,  B01J37/08 ,  F01N3/28 ,  B01D53/94

CPC classification number: B01J23/10 ,  C01G25/006 ,  B01J23/44 ,  B01J35/04 ,  B01J35/0066 ,  B01J37/06 ,  B01J37/08 ,  F01N3/2803 ,  B01D53/94 ,  C01P2002/50 ,  F01N2370/04 ,  B01D2255/20715 ,  B01D2255/2065 ,  B01D2255/2063 ,  B01D2255/2061 ,  B01D2255/407 ,  B01D2255/908 ,  B01D2255/1023

Abstract: A Ce—Zr composite oxide contains cerium and zirconium, wherein an uneven distribution ratio of cerium atoms is 1.80 or less. A method for producing a Ce—Zr composite oxide includes an acid treatment step of bringing at least one selected from the group consisting of sulfuric acid, nitric acid, and hydrochloric acid, in an amount of 4 to 28 parts by mass with respect to 100 parts by mass of the raw material composite oxide, into contact with the surface of a raw material composite oxide containing cerium and zirconium, and a calcination step of calcining the treated composite oxide obtained in the acid treatment step at 400 to 1200° C. for 5 to 300 minutes.

公开(公告)号：US20230264954A1

公开(公告)日：2023-08-24

申请号：US18049632

申请日：2022-10-26

Applicant: Phuong Thuy Ngo ,  Nguyen Phuc Le ,  Tri Van Tran ,  Thuy Ngoc Luong

Inventor： Phuong Thuy Ngo ,  Nguyen Phuc Le ,  Tri Van Tran ,  Thuy Ngoc Luong

IPC: C01B3/40 ,  B01J23/755 ,  B01J23/02 ,  B01J35/04 ,  B01J37/04 ,  B01J37/03 ,  B01J37/00 ,  B01J37/06 ,  B01J37/08 ,  B01J37/34 ,  B01J19/08

CPC classification number: C01B3/40 ,  B01J23/755 ,  B01J23/02 ,  B01J35/04 ,  B01J37/04 ,  B01J37/038 ,  B01J37/009 ,  B01J37/06 ,  B01J37/08 ,  B01J37/0036 ,  B01J37/343 ,  B01J19/088 ,  C01B2203/0238 ,  C01B2203/0261 ,  C01B2203/1058 ,  C01B2203/1082 ,  C01B2203/1241 ,  B01J2219/0896 ,  B01J2219/0875 ,  B01J2219/0892

Abstract: A method and system for reforming CO2 rich natural gases is disclosed which comprises: a cold plasma unit configured to convert CO2 rich natural gases into a plasma state; and a gas reforming reactor configured to reform said CO2 rich gas mixture at said plasma state into a syngas. The catalytic reforming reactor is separate and different from the DBD cold plasma unit. Means for latent heat of condensation, endothermic/exothermic reactions, and convection currents is used to achieve energy efficiency.

公开(公告)号：US11731118B2

公开(公告)日：2023-08-22

申请号：US17520205

申请日：2021-11-05

Applicant: ALBEMARLE CATALYSTS COMPANY B. V.

Inventor： Bastiaan Maarten Vogelaar ,  Jacob Arie Bergwerff ,  Johan van Oene ,  Henk Jan Tromp

IPC: B01J31/34 ,  B01J21/08 ,  B01J21/04 ,  B01J35/02 ,  B01J37/02 ,  B01J37/08 ,  B01J31/28

CPC classification number: B01J31/34 ,  B01J21/04 ,  B01J21/08 ,  B01J31/28 ,  B01J35/023 ,  B01J37/0203 ,  B01J37/08

Abstract: This invention provides supported catalysts comprising a carrier, phosphorus, at least one Group VI metal, at least one Group VIII metal, and a polymer. In the catalyst, the molar ratio of phosphorus to Group VI metal is about 1:1.5 to less than about 1:12, the molar ratio of the Group VI metal to the Group VIII metal is about 1:1 to about 5:1, and the polymer has a carbon backbone and comprises functional groups having at least one heteroatom. Also provided are a process for preparing such supported catalysts, as well as methods for hydrotreating, hydrodenitrogenation, and/or hydrodesulfurization, using supported catalysts.

公开(公告)号：US11731113B2

公开(公告)日：2023-08-22

申请号：US16964380

申请日：2017-08-23

Applicant: Khalifa University of Science and Technology

Inventor： Marios S. Katsiotis ,  Vasileios Tzitzios ,  Saeed Alhassan

IPC: B01J29/08 ,  C01B39/24 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/30 ,  C01B39/20 ,  C10G11/05

CPC classification number: B01J29/084 ,  B01J35/0013 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/0236 ,  B01J37/031 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/30 ,  C01B39/205 ,  C01B39/24 ,  C10G11/05 ,  B01J2229/186 ,  C01P2002/60 ,  C01P2002/72 ,  C01P2002/80 ,  C01P2004/03 ,  C01P2006/12 ,  C01P2006/16

Abstract: The present application relates to a method for synthesizing nanozeolite Y crystals, nanozeolite Y crystals obtainable by said method, and the use of the synthesized nanozeolite Y crystals in cracking hydrocarbons, as molecular sieves or as ion-exchangers.

公开(公告)号：US11717815B2

公开(公告)日：2023-08-08

申请号：US17796881

申请日：2020-12-29

Applicant: VALIANT CO., LTD.

Inventor： Xiaoling Liu ,  Hu Yuan ,  Songwei Xie ,  Fanmin Meng

IPC: B01J37/08 ,  B01J35/04

CPC classification number: B01J37/08 ,  B01J35/04 ,  B01J2523/3712 ,  B01J2523/47 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/72 ,  B01J2523/845 ,  B01J2523/847

Abstract: A method for preparing an active catalyst for high-efficiency denitration is disclosed. The method includes: a catalyst raw material is charged into a denitration reactor, NH3 and an inert gas are introduced and then heating is performed, and the temperature is held and then natural cooling is performed, thereby obtaining the catalyst. The active catalyst can greatly improve the denitration activity in low temperature range, and can not only improve the denitration efficiency under the condition without SO2 and H2O, but also can improve the denitration efficiency under the condition with both SO2 and H2O. The service life of the catalyst is prolonged under the premise of not changing the existing catalyst preparation process, and the economic benefit is significant. The denitration efficiency of a powder catalyst can be increased by 25%, and the denitration efficiency of a honeycombed catalyst or a corrugated catalyst can be increased by 20%.

公开(公告)号：US11717811B2

公开(公告)日：2023-08-08

申请号：US16471499

申请日：2017-12-21

Applicant: IFP Energies nouvelles ,  TOTAL RAFFINAGE CHIMIE

Inventor： Arnold Lambert ,  Mathieu Michau ,  Delphine Marti ,  Elodie Comte

IPC: B01J23/72 ,  B01J21/04 ,  B01J21/12 ,  B01J35/10 ,  B01J35/02 ,  B01J37/03 ,  B01J37/08 ,  B01J37/00 ,  F23C10/01 ,  F23C10/04 ,  F23C13/08 ,  B01J37/02

CPC classification number: B01J23/72 ,  B01J21/04 ,  B01J21/12 ,  B01J35/023 ,  B01J35/026 ,  B01J35/108 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1076 ,  B01J37/0018 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/0236 ,  B01J37/038 ,  B01J37/08 ,  F23C10/01 ,  F23C10/04 ,  F23C13/08

Abstract: The invention relates to an oxygen carrier solid, its preparation and its use in a method of combustion of a hydrocarbon feedstock by active mass chemical-looping oxidation-reduction, i.e. chemical-looping combustion (CLC). The solid, which is in the form of particles, comprises an oxidation-reduction active mass composed of metal oxide(s) dispersed in a ceramic matrix comprising at least one oxide with a melting point higher than 1500° C., such as alumina, and has, initially, a specific macroporous texture. The oxygen carrier solid is prepared from an aqueous suspension containing precursor oxide grains for the ceramic matrix that have a specific size, by a spray-drying technique.

公开(公告)号：US20230234035A1

公开(公告)日：2023-07-27

申请号：US17581447

申请日：2022-01-21

Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC ,  University of Central Florida Research Foundation, Inc.

Inventor： Yuntao GU ,  Wei LI ,  Fudong LIU

IPC: B01J23/44 ,  B01J23/10 ,  B01J21/04 ,  B01J35/00 ,  B01J35/10 ,  B01J37/08 ,  B01J37/02

CPC classification number: B01J23/44 ,  B01J23/10 ,  B01J21/04 ,  B01J35/0006 ,  B01J35/1014 ,  B01J35/1042 ,  B01J37/08 ,  B01J37/0215

Abstract: A layered catalyst structure for purifying an exhaust gas stream includes a catalyst support and a palladium catalyst layer including an atomic dispersion of palladium ions electrostatically adsorbed onto an exterior surface of the catalyst support. The catalyst support includes an alumina substrate, a first ceria layer disposed on and extending substantially continuously over the alumina substrate, and a second colloidal ceria layer formed directly on the first ceria layer over the alumina substrate. The palladium catalyst layer is formed on the exterior surface of the catalyst support by applying a palladium-containing precursor solution to the exterior surface of the catalyst support and then heating the catalyst support and the palladium-containing precursor solution. The palladium-containing precursor solution includes a positively charged palladium complex in an aqueous medium and has a pH greater than a point of zero charge of the second colloidal ceria layer.

公开(公告)号：US20230234030A1

公开(公告)日：2023-07-27

申请号：US18011857

申请日：2021-06-25

Applicant: BASF SE

Inventor： Sung Yeun CHOI ,  Andrey KARPOV ,  Christian WALSDORFF ,  Nicolas DUYCKAERTS ,  Kazuhiko AMAKAWA ,  Patrick HUBACH ,  Karl C. KHARAS

IPC: B01J21/04 ,  B01J23/50 ,  B01J23/36 ,  B01J35/02 ,  B01J35/10 ,  B01J35/00 ,  B01J37/04 ,  B01J37/00 ,  B01J37/08 ,  C07D301/10

CPC classification number: B01J21/04 ,  B01J23/50 ,  B01J23/36 ,  B01J35/026 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1009 ,  B01J35/1066 ,  B01J35/1061 ,  B01J35/0026 ,  B01J37/04 ,  B01J37/0063 ,  B01J37/0018 ,  B01J37/08 ,  C07D301/10

Abstract: A tableted catalyst support, characterized by an alpha-alumina content of at least 85 wt.-%, a pore volume of at least 0.40 mL/g, as determined by mercury porosimetry, and a BET surface area of 0.5 to 5.0 m2/g. The tableted catalyst support is an alpha-alumina catalyst support obtained with high geometrical precision and displaying a high overall pore volume, thus allowing for impregnation with a high amount of silver, while exhibiting a surface area sufficiently large so as to provide optimal dispersion of catalytically active species, in particular metal species. The invention further provides a process for producing a tableted alpha-alumina catalyst support, which comprises i) forming a free-flowing feed mixture comprising, based on inorganic solids content, at least 50 wt.-% of a transition alumina; ii) tableting the free-flowing feed mixture to obtain a compacted body; and iii) heat treating the compacted body at a temperature of at least 1100° C., preferably at least 1300° C., more preferably at least 1400° C., in particular at least 1450° C., to obtain the tableted alpha-alumina catalyst support. The invention moreover relates to a compacted body obtained by tableting a free-flowing feed mixture which comprises, based on inorganic solids content, at least 50 wt.-% of a transition alumina having a loose bulk density of at most 600 g/L, a pore volume of at least 0.6 mL/g, as determined, and a median pore diameter of at least 15 nm. The invention moreover relates to a shaped catalyst body for producing ethylene oxide by gas-phase oxidation of ethylene, comprising at least 15 wt.-% of silver, relative to the total weight of the catalyst, deposited on the tableted alpha-alumina catalyst support. The invention moreover relates to a process for producing ethylene oxide by gas-phase oxidation of ethylene, comprising reacting ethylene and oxygen in the presence of the shaped catalyst body.