公开(公告)号：US20170144137A1

公开(公告)日：2017-05-25

申请号：US15426843

申请日：2017-02-07

Applicant: BASF CORPORATION

Inventor： Gary M. Smith ,  Robert McGuire, JR. ,  Bilge Yilmaz

IPC: B01J29/14 ,  C10G11/18 ,  C10G11/05 ,  B01J37/28 ,  B01J37/02

CPC classification number: B01J29/146 ,  B01J21/04 ,  B01J21/16 ,  B01J23/8472 ,  B01J29/088 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/08 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/28 ,  B01J2229/126 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/26 ,  B01J2229/36 ,  C10G11/05 ,  C10G11/18

Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise catalytic microspheres containing a zeolite, a non-zeolitic component, and a rare earth component. The microspheres are modified with phosphorus. The FCC catalyst composition can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.

公开(公告)号：US09592495B2

公开(公告)日：2017-03-14

申请号：US14573439

申请日：2014-12-17

Applicant: DENSO CORPORATION

Inventor： Masaki Yoshinaga ,  Hiroaki Yotou ,  Goh Iijima ,  Yoshimasa Hijikata

IPC: B01J27/02 ,  B01J27/06 ,  B01J27/16 ,  B01J27/18 ,  B01J27/135 ,  B01J27/053 ,  B01J35/00 ,  C01C1/04 ,  B01J37/24 ,  B01J37/28 ,  B01J21/06 ,  B01J23/38 ,  B01J23/70

CPC classification number: B01J27/18 ,  B01J21/063 ,  B01J23/38 ,  B01J23/70 ,  B01J27/053 ,  B01J27/135 ,  B01J35/0013 ,  B01J35/004 ,  B01J37/24 ,  B01J37/28 ,  C01C1/0411 ,  Y02P20/52

Abstract: An ammonia synthesis catalyst synthesizing ammonia from nitrogen in a presence of moisture is provided. The ammonia synthesis catalysis includes a catalyst particle including an inorganic material that has a photocatalytic function and an inorganic acid. The catalyst particle is preferably an n-type semiconductor and includes oxide material including at least titanium preferably. The inorganic acid preferably corresponds to at least one of perchloric acid, hydrochloric acid, sulfuric acid, and phosphoric acid.

Abstract translation: 提供了一种在水分存在下从氮气合成氨的氨合成催化剂。 氨合成催化剂包括具有光催化功能的无机材料和无机酸的催化剂粒子。 催化剂颗粒优选为n型半导体，并且包括优选至少包含钛的氧化物材料。 无机酸优选对应于高氯酸，盐酸，硫酸和磷酸中的至少一种。

公开(公告)号：US09518229B2

公开(公告)日：2016-12-13

申请号：US13838706

申请日：2013-03-15

Applicant: Inaeris Technologies, LLC

Inventor： Jerry Jon Springs ,  Bruce ADkins ,  Stephen Schuyten ,  Gopal Juttu ,  Christine M. Henry ,  Kelsey Shogren

IPC: B01J29/06 ,  C10G1/08 ,  B01J29/40 ,  B01J29/18 ,  B01J29/65 ,  B01J29/08 ,  B01J29/70 ,  B01J37/28 ,  B01J35/10 ,  B01J37/00 ,  B01J35/00

CPC classification number: C10G1/086 ,  B01J29/084 ,  B01J29/18 ,  B01J29/40 ,  B01J29/65 ,  B01J29/7007 ,  B01J35/0026 ,  B01J35/1019 ,  B01J35/1033 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J35/1085 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/28 ,  B01J2229/42 ,  C10G1/08 ,  C10G2300/1011 ,  C10G2300/1014 ,  Y02P30/20

Abstract: Disclosed are catalyst compositions including zeolite and silica components, methods of making, and processes of using in the thermo-catalytic conversion of biomass. Such disclosed methods of making include: i) spray drying of the catalyst precursor slurry at a pH below 1, or ii) the removal of ions such as sodium from the binder material prior to spray drying the catalyst precursor slurry at a pH below 2.7, or iii) spray drying the catalyst precursor including a pore regulating agent followed by steam treating, or iv) some combination of i), ii) and iii).

Abstract translation: 公开了包括沸石和二氧化硅组分的催化剂组合物，制备方法和在生物质的热催化转化中使用的方法。 这种公开的制备方法包括：i）在低于1的pH下喷雾干燥催化剂前体浆料，或ii）在pH低于2.7的喷雾干燥催化剂前体浆料之前，从粘合剂材料中除去离子如钠， 或iii）喷雾干燥催化剂前体，包括孔调节剂，然后进行蒸汽处理，或iv）i），ii）和iii）的某些组合。

公开(公告)号：US09511359B2

公开(公告)日：2016-12-06

申请号：US14541672

申请日：2014-11-14

Applicant: Chevron Phillips Chemical Company LP

Inventor： Tin-Tack Peter Cheung ,  Zongxuan Hong ,  Joseph Bergmeister, III

IPC: B01J27/10 ,  B01J27/12 ,  B01J31/26 ,  B01J37/28 ,  B01J23/44 ,  B01J31/02 ,  B01J31/04 ,  C07C5/05 ,  C07C5/09 ,  B01J21/02 ,  B01J21/04 ,  B01J23/50 ,  B01J35/00 ,  B01J35/10 ,  B01J37/04 ,  B01J37/16

CPC classification number: B01J31/26 ,  B01J21/02 ,  B01J21/04 ,  B01J23/44 ,  B01J23/50 ,  B01J31/0209 ,  B01J31/0262 ,  B01J31/0267 ,  B01J31/04 ,  B01J35/0006 ,  B01J35/0093 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/04 ,  B01J37/16 ,  B01J37/28 ,  B01J2231/645 ,  B01J2531/002 ,  B01J2531/008 ,  C07C5/05 ,  C07C5/09 ,  C07C7/167 ,  Y02P20/52 ,  C07C11/04 ,  C07C11/06

Abstract: A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a supported-palladium composition; contacting the supported-palladium composition with an organophosphorus compound and a weak acid to form a catalyst composition; and reducing the catalyst composition to form the catalyst. A method of making a selective hydrogenation catalyst comprising contacting an alumina support with a palladium-containing compound to form a supported-palladium composition; contacting the supported-palladium composition with silver nitrate and potassium fluoride to form a mixture; contacting the mixture with an organophosphorus compound and a weak acid to form a catalyst precursor; and reducing the catalyst precursor to form the catalyst.

Abstract translation: 制备选择性氢化催化剂的方法，包括使载体与含钯​​化合物接触以形成负载型钯组合物; 使负载的钯组合物与有机磷化合物和弱酸接触以形成催化剂组合物; 并降低催化剂组成以形成催化剂。 制备选择性氢化催化剂的方法包括使氧化铝载体与含钯​​化合物接触以形成负载型钯组合物; 使负载的钯组合物与硝酸银和氟化钾接触以形成混合物; 使该混合物与有机磷化合物和弱酸接触以形成催化剂前体; 并还原催化剂前体以形成催化剂。

公开(公告)号：US20160310934A1

公开(公告)日：2016-10-27

申请号：US15105611

申请日：2014-12-18

Applicant: BASF SE

Inventor： Kirsten BRAUNSMANN ,  Bernd Bastian SCHAACK ,  Ekkehard SCHWAB ,  Manuela GAAB ,  Mathias FEYEN

IPC: B01J29/40 ,  B01J37/04 ,  B01J37/08 ,  C07C1/20 ,  B01J37/02

CPC classification number: B01J29/40 ,  B01J29/70 ,  B01J29/7038 ,  B01J29/90 ,  B01J35/002 ,  B01J35/023 ,  B01J35/10 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/04 ,  B01J37/08 ,  B01J37/28 ,  B01J38/02 ,  B01J2229/12 ,  B01J2229/123 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/32 ,  B01J2229/37 ,  B01J2229/42 ,  C07C1/20 ,  C07C1/207 ,  C07C11/02 ,  C07C11/06 ,  C07C11/08 ,  C07C2529/40 ,  C07C2529/70 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/20

Abstract: The present invention relates to a catalyst for the conversion of oxygenates to olefins, wherein the catalyst comprises one or more zeolites of the MFI, MEL and/or MWW structure type and particles of one or more metal oxides, the one or more zeolites of the MFI, MEL and/or MWW structure type comprising one or more alkaline earth metals selected from the group consisting of Mg, Ca, Sr, Ba and combinations of two or more thereof, wherein the catalyst displays a water uptake of 9.0 wt.-% or less, as well as to a process for the production thereof and to its use, in particular in a process for converting oxygenates to olefins.

公开(公告)号：US09433927B2

公开(公告)日：2016-09-06

申请号：US14764350

申请日：2014-01-31

Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.

Inventor： Masanori Ikeda ,  Kazuyoshi Komata ,  Shigekazu Minami ,  Yuji Ogino ,  Hideki Goto

IPC: B01D53/56 ,  B01D53/94 ,  B01J8/02 ,  B01J23/00 ,  B01J23/02 ,  B01J23/10 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/56 ,  B01J21/04 ,  B01J23/63 ,  B01J37/02 ,  B01J35/00

CPC classification number: B01J23/63 ,  B01D53/945 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/40 ,  B01D2255/407 ,  B01D2255/9022 ,  B01J23/002 ,  B01J35/0006 ,  B01J35/002 ,  B01J37/0036 ,  B01J37/0244 ,  B01J37/0248 ,  B01J37/04 ,  B01J37/28 ,  B01J2523/00 ,  Y02T10/22 ,  B01J2523/31 ,  B01J2523/36 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/822 ,  B01J2523/824

Abstract: As a way to suppress deterioration of catalytic performance in an exhaust gas purification catalyst even after being exposed to an exhaust gas containing a phosphorus compound, an exhaust gas purification catalyst is provided. The catalyst purifies an exhaust gas containing a phosphorus compound, and the catalyst includes a catalyst layer containing rhodium (Rh), palladium (Pd), and either a ceria-zirconia-lanthana complex oxide or a ceria-zirconia-lanthana-yttria complex oxide as catalyst active components. Further, an average value of distances between Rh particles and the nearest Pd particles of the Rh and the Pd is within 4000 nm, a weight ratio of the Pd to the Rh is from 0.2 to 4.9, and a content rate of yttria in the ceria-zirconia-lanthana-yttria complex oxide is 19% by weight or less.

Abstract translation: 作为排出气体净化催化剂的催化性能劣化的方法，即使在暴露于含有磷化合物的废气的情况下也能够提供排气净化催化剂。 催化剂净化含有磷化合物的废气，催化剂包括含有铑（Rh），钯（Pd）和二氧化铈 - 氧化锆 - 氧化镧复合氧化物或二氧化铈 - 氧化锆 - 氧化镧 - 氧化钇复合氧化物的催化剂层 作为催化剂活性成分。 此外，Rh颗粒与Rh和Pd的最近的Pd颗粒之间的距离的平均值在4000nm以内，Pd与Rh的重量比为0.2-4.9，二氧化铈中的氧化钇含量 氧化锆 - 氧化镧 - 氧化钇复合氧化物的重量百分比为19重量％以下。

公开(公告)号：US20160199823A1

公开(公告)日：2016-07-14

申请号：US14913073

申请日：2014-08-20

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Zeeshan Nawaz

IPC: B01J29/85 ,  C07C5/333 ,  B01J37/02 ,  B01J37/16 ,  B01J37/08

CPC classification number: B01J29/85 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/08 ,  B01J37/10 ,  B01J37/16 ,  B01J37/28 ,  B01J2229/12 ,  B01J2229/186 ,  B01J2229/20 ,  C07C5/325 ,  C07C5/3337 ,  C07C2529/85 ,  Y02P20/52 ,  C07C11/06

Abstract: Selective supported catalysts compositions for alkane dehydrogenation are described, the catalyst compositions containing platinum, a tin component, a potassium component, one or more additional promoter elements, and a support. Also described are methods for the preparation of such catalyst compositions and methods for the use of such catalyst compositions in the conversion of alkanes to olefins.

Abstract translation: 描述了用于烷烃脱氢的选择性负载型催化剂组合物，所述催化剂组合物含有铂，锡组分，钾组分，一种或多种另外的启动子元件和载体。 还描述了制备这种催化剂组合物的方法和使用这种催化剂组合物将烷烃转化为烯烃的方法。

公开(公告)号：US09371255B2

公开(公告)日：2016-06-21

申请号：US14005479

申请日：2012-03-07

Applicant: Markus Winterberg ,  Christian Böing ,  Dietrich Maschmeyer ,  Asli Nau ,  Horst-Werner Zanthoff ,  Thomas Quandt ,  Christian Schulze Isfort

Inventor： Markus Winterberg ,  Christian Böing ,  Dietrich Maschmeyer ,  Asli Nau ,  Horst-Werner Zanthoff ,  Thomas Quandt ,  Christian Schulze Isfort

IPC: C07C1/22 ,  B01J21/12 ,  C07C1/213 ,  B01J37/10 ,  B01J37/28 ,  B01J23/00 ,  B01J23/04 ,  B01J27/16 ,  B01J27/18 ,  B01J35/00 ,  B01J35/10 ,  C07C29/00

CPC classification number: C07C1/22 ,  B01J21/12 ,  B01J23/002 ,  B01J23/04 ,  B01J27/16 ,  B01J27/1806 ,  B01J35/002 ,  B01J35/0073 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/10 ,  B01J37/28 ,  B01J2523/00 ,  C07C1/213 ,  C07C29/00 ,  C07C2521/08 ,  C07C2523/04 ,  C07C2529/70 ,  Y02P20/52 ,  Y02P20/582 ,  C07C11/09 ,  B01J2523/12 ,  B01J2523/31 ,  B01J2523/41 ,  B01J2523/51

Abstract: The present invention relates to mixed oxide compositions, to the use thereof as a catalyst for cleavage of alkyl tert-alkyl ethers or tertiary alcohols, and to a process for cleaving alkyl tert-alkyl ethers or tertiary alcohols to isoolefins and alcohol or water.

Abstract translation: 本发明涉及混合氧化物组合物及其用作烷基叔烷基醚或叔醇裂解催化剂的用途，以及将烷基叔烷基醚或叔醇裂解成异烯烃和醇或水的方法。

公开(公告)号：US20160136630A1

公开(公告)日：2016-05-19

申请号：US14541672

申请日：2014-11-14

Applicant: Chevron Phillips Chemical Company LP

Inventor： Tin-Tack Peter Cheung ,  Zongxuan Hong ,  Joseph Bergmeister, III

IPC: B01J31/26 ,  B01J23/44 ,  B01J21/04 ,  B01J35/10 ,  B01J21/02 ,  B01J37/04 ,  B01J37/16 ,  B01J35/00 ,  B01J23/50 ,  B01J31/02

CPC classification number: B01J31/26 ,  B01J21/02 ,  B01J21/04 ,  B01J23/44 ,  B01J23/50 ,  B01J31/0209 ,  B01J31/0262 ,  B01J31/0267 ,  B01J31/04 ,  B01J35/0006 ,  B01J35/0093 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/04 ,  B01J37/16 ,  B01J37/28 ,  B01J2231/645 ,  B01J2531/002 ,  B01J2531/008 ,  C07C5/05 ,  C07C5/09 ,  C07C7/167 ,  Y02P20/52 ,  C07C11/04 ,  C07C11/06

Abstract: A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a supported-palladium composition; contacting the supported-palladium composition with an organophosphorus compound and a weak acid to form a catalyst composition; and reducing the catalyst composition to form the catalyst. A method of making a selective hydrogenation catalyst comprising contacting an alumina support with a palladium-containing compound to form a supported-palladium composition; contacting the supported-palladium composition with silver nitrate and potassium fluoride to form a mixture; contacting the mixture with an organophosphorus compound and a weak acid to form a catalyst precursor; and reducing the catalyst precursor to form the catalyst.

Abstract translation: 制备选择性氢化催化剂的方法，包括使载体与含钯​​化合物接触以形成负载型钯组合物; 使负载的钯组合物与有机磷化合物和弱酸接触以形成催化剂组合物; 并降低催化剂组成以形成催化剂。 制备选择性氢化催化剂的方法包括使氧化铝载体与含钯​​化合物接触以形成负载型钯组合物; 使负载的钯组合物与硝酸银和氟化钾接触以形成混合物; 使该混合物与有机磷化合物和弱酸接触以形成催化剂前体; 并还原催化剂前体以形成催化剂。

公开(公告)号：US20160121317A1

公开(公告)日：2016-05-05

申请号：US14991272

申请日：2016-01-08

Applicant: John L. Casci ,  Hai-Ying Chen ,  Joseph Michael Fedeyko ,  Jillian Elaine Collier ,  Raj Rao Rajaram ,  David Thompsett ,  Robert P. Hodgkins

Inventor： John L. Casci ,  Hai-Ying Chen ,  Joseph Michael Fedeyko ,  Jillian Elaine Collier ,  Raj Rao Rajaram ,  David Thompsett ,  Robert P. Hodgkins

IPC: B01J29/76 ,  B01J35/04

CPC classification number: B01J29/763 ,  B01D53/8628 ,  B01D53/9418 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/707 ,  B01J29/7015 ,  B01J29/85 ,  B01J29/88 ,  B01J35/04 ,  B01J37/0246 ,  B01J37/28 ,  B01J2229/183 ,  B01J2229/186 ,  C01B39/04 ,  C01B39/10 ,  C01B39/54 ,  Y02T10/24

Abstract: A catalyst washcoat is provided having a molecular sieve with a CHA crystal structure; about 0.5 to about 5.0 mol % phosphorus; and SiO2 and Al2O3 in a mole ratio of about 5 to about 40. The washcoat includes one or more promoters or stabilizers, and may be applied to a monolith substrate to produce a catalytically active article.

Abstract translation: 提供具有CHA晶体结构的分子筛的催化剂修补基面涂层; 约0.5至约5.0mol％的磷; 和SiO 2和Al 2 O 3，摩尔比为约5至约40.修补基面涂层包括一种或多种促进剂或稳定剂，并且可以施用于整料基材以产生催化活性制品。