公开(公告)号：US07160830B2

公开(公告)日：2007-01-09

申请号：US10731917

申请日：2003-12-10

Applicant: Monique Van Der Zon ,  Erik Jeroen Laheij ,  Paul O'Connor

Inventor： Monique Van Der Zon ,  Erik Jeroen Laheij ,  Paul O'Connor

IPC: B01J35/08

CPC classification number: B01J37/0063 ,  B01J29/06 ,  B01J29/084 ,  B01J35/023 ,  B01J2229/42

Abstract: The present invention relates to a process for the preparation of catalyst particles with a particle diameter in the range 20–2000 microns involving the steps of agitating at least two dry catalyst ingredients, spraying a liquid binding agent on the catalyst ingredients while continuing the agitation, and isolating formed catalyst particles with the desired particle diameter and comprising the catalyst ingredients. In contrast to the conventional way of preparing such particles, spray-drying, the present process allows the formation of small particles from slurries with a high solids content. Hence, smaller amounts of liquid have to be evaporated, which makes the process energy efficient.

Abstract translation: 本发明涉及一种制备粒径在20-2000微米范围内的催化剂颗粒的方法，包括搅拌至少两种干燥催化剂成分的步骤，在继续搅拌下将液体粘合剂喷洒在催化剂成分上， 并分离具有所需粒径的形成的催化剂颗粒并且包含催化剂成分。 与制备这种颗粒的常规方法相反，喷雾干燥，本方法允许从固体含量高的浆料形成小颗粒。 因此，必须蒸发较少量的液体，这使得工艺能量效率高。

公开(公告)号：US06968681B2

公开(公告)日：2005-11-29

申请号：US10416156

申请日：2001-11-17

Applicant: Guenter Stephani ,  Olaf Andersen ,  Gennadi Zikoridse ,  Ernstwendelin Bach ,  Frank Bretschneider

Inventor： Guenter Stephani ,  Olaf Andersen ,  Gennadi Zikoridse ,  Ernstwendelin Bach ,  Frank Bretschneider

IPC: F01N3/02 ,  B01D39/06 ,  B01D39/20 ,  B01D53/86 ,  B01J35/00 ,  B01J35/06 ,  B01J35/08 ,  F01N3/022 ,  F01N3/035 ,  F01N3/24 ,  F01N3/28 ,  F01N3/00

CPC classification number: F01N3/035 ,  B01J35/0006 ,  B01J35/06 ,  B01J35/08 ,  F01N3/0226 ,  F01N3/2832 ,  F01N2330/08 ,  F01N2330/12

Abstract: The invention relates to a device and a method for the aftertreatment of exhaust gases from combustion engines, in particular from internal combustion engines. The device according to the invention and the method are intended to be of simple construction, should be inexpensive to produce and operate and should have less adverse effect on the flow conditions in the exhaust gas stream. To achieve this object, at least one region which is filled with beads is provided in the exhaust-gas stream, the beads preferably being hollow beads. The exhaust gas from the combustion engine is passed through this region, and it is possible to achieve particle agglomeration with simultaneous separation of these particles. In addition, further regions which are filled with metal fibers may follow the at least one region filled with beads, and the exhaust gas is additionally passed through these further regions.

Abstract translation: 本发明涉及一种用于后处理来自内燃发动机，特别是内燃机的废气的装置和方法。 根据本发明的装置和方法旨在是简单的结构，其制造和操作应该便宜，并且对排气流中的流动条件应具有较小的不利影响。 为了达到这个目的，在排气流中设置至少一个填充有珠粒的区域，珠粒优选为中空珠粒。 来自内燃机的废气通过该区域，并且可以实现颗粒聚集同时分离这些颗粒。 此外，填充有金属纤维的其他区域可以跟随填充有珠粒的至少一个区域，并且废气另外通过这些其它区域。

公开(公告)号：US06911412B2

公开(公告)日：2005-06-28

申请号：US10210597

申请日：2002-08-01

Applicant: Mark J. Hampden-Smith ,  Toivo T. Kodas ,  Plamen Atanassov ,  Paolina Atanassova ,  Klaus Kunze ,  Paul Napolitano ,  David Dericotte

Inventor： Mark J. Hampden-Smith ,  Toivo T. Kodas ,  Plamen Atanassov ,  Paolina Atanassova ,  Klaus Kunze ,  Paul Napolitano ,  David Dericotte

IPC: B01J2/02 ,  B01J13/02 ,  B01J19/00 ,  B01J19/10 ,  B01J19/24 ,  B01J21/18 ,  B01J23/00 ,  B01J23/34 ,  B01J23/40 ,  B01J31/06 ,  B01J35/02 ,  B01J35/08 ,  B01J35/10 ,  B01J37/00 ,  B01J37/34 ,  B22F1/00 ,  B22F9/02 ,  B22F9/24 ,  C01B13/18 ,  C01B17/20 ,  C01G23/00 ,  C22C29/00 ,  C22C32/00 ,  H01L23/498 ,  H01M4/86 ,  H01M4/90 ,  H01M4/92 ,  H01M8/10 ,  H01M12/08 ,  H05K1/09

CPC classification number: B01J2/02 ,  B01J13/02 ,  B01J19/10 ,  B01J19/2405 ,  B01J21/18 ,  B01J23/00 ,  B01J23/34 ,  B01J23/40 ,  B01J31/06 ,  B01J35/002 ,  B01J35/0033 ,  B01J35/006 ,  B01J35/023 ,  B01J35/08 ,  B01J35/1014 ,  B01J37/0054 ,  B01J37/343 ,  B01J2219/00112 ,  B01J2219/00155 ,  B01J2219/00159 ,  B01J2219/00162 ,  B01J2219/00166 ,  B01J2219/00171 ,  B01J2219/00186 ,  B22F1/0018 ,  B22F9/026 ,  B22F9/24 ,  B22F2998/00 ,  B82Y30/00 ,  C01B13/18 ,  C01B17/20 ,  C01G23/003 ,  C01P2004/32 ,  C01P2004/61 ,  C01P2006/22 ,  C22C29/00 ,  C22C32/0084 ,  H01L23/49883 ,  H01L2924/0002 ,  H01M4/8605 ,  H01M4/90 ,  H01M4/9016 ,  H01M4/9083 ,  H01M4/926 ,  H01M8/1004 ,  H01M12/08 ,  H05K1/095 ,  Y02E60/128 ,  Y02P70/56 ,  Y10T29/49108 ,  Y10T29/49115 ,  Y10T29/5313 ,  Y10T29/53135 ,  Y10T29/532 ,  Y10T29/53204 ,  B22F1/0048 ,  B22F1/0014 ,  B22F1/025 ,  H01L2924/00

Abstract: Electrocatalyst powders and methods for producing electrocatalyst powders, such as carbon composite electrocatalyst powders. The powders have a well-controlled microstructure and morphology. The method includes forming the particles from an aerosol of precursors by heating the aerosol to a relatively low temperature, such as not greater than about 400° C.

Abstract translation: 电催化剂粉末和电催化剂粉末的制备方法，如碳复合电催化剂粉末。 粉末具有良好控制的微观结构和形态。 该方法包括通过将气溶胶加热至相对较低的温度（例如不超过约400℃）从前体气溶胶形成颗粒。

公开(公告)号：US06852665B2

公开(公告)日：2005-02-08

申请号：US09911489

申请日：2001-07-25

Applicant: Akira Morikawa ,  Miho Hatanaka ,  Haruo Imagawa ,  Akihiko Suda ,  Naoki Takahashi

Inventor： Akira Morikawa ,  Miho Hatanaka ,  Haruo Imagawa ,  Akihiko Suda ,  Naoki Takahashi

IPC: F01N3/10 ,  B01D53/94 ,  B01J21/06 ,  B01J23/10 ,  B01J23/46 ,  B01J23/56 ,  B01J23/63 ,  B01J29/44 ,  B01J32/00 ,  B01J35/00 ,  B01J35/02 ,  B01J35/08 ,  B01J37/02 ,  B01J37/03 ,  C01F7/02 ,  C01G25/02 ,  B01J23/00

CPC classification number: B01D53/945 ,  B01J23/10 ,  B01J35/0006 ,  B01J35/023 ,  B01J37/0244 ,  B01J37/0246 ,  B01J37/031 ,  C01F7/02 ,  C01F7/025 ,  C01G25/02 ,  C01P2002/52 ,  C01P2002/85 ,  C01P2004/04 ,  C01P2004/50 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/13 ,  C01P2006/16 ,  Y02T10/22

Abstract: A composite oxide includes agglomerated particles which have an average particle diameter of 20 μm or less, which are composed of a plurality of metallic element oxides being in form of fine particles having an average diameter of 50 nm or less, and which have a surface and an inner portion whose metallic element distributions differ with each other. The characteristics of the respective metallic elements are exhibited maximally. Hence, it is extremely useful as a support for an exhaust gas purifying catalyst. The catalyst exhibits the activities which degrade less even after it is subjected to a sever durability, is good in terms of the heat and sulfur-poisoning resistance, and can efficiently purify the harmful components in exhaust gases. Moreover, it is possible to produce such a composite oxide and catalyst easily and stably by production processes disclosed herein.

Abstract translation: 复合氧化物包括平均粒径为20μm以下的凝集粒子，其由平均直径为50nm以下的细颗粒形式的多个金属元素氧化物构成，并且具有表面和 其金属元素分布彼此不同的内部部分。 各金属元素的特性最大程度地呈现。 因此，作为废气净化催化剂的载体是非常有用的。 该催化剂表现出即使在耐久耐久性之后降解较少的活性，在耐热和耐硫中毒性方面也是良好的，并且可以有效地净化废气中的有害成分。 此外，通过本文公开的生产方法，可以容易且稳定地制备这种复合氧化物和催化剂。

公开(公告)号：US20050014641A1

公开(公告)日：2005-01-20

申请号：US10478478

申请日：2002-05-23

Applicant: Tor-Arne Gronland ,  Bjorn Westerberg ,  Goran Bergman ,  Kjell Anflo ,  Jesper Brandt ,  Ola Lyckfeldt ,  Johan Agrell ,  Anders Ersson ,  Sven Jaras ,  Magali Boutonnet ,  Niklas Wingborg

Inventor： Tor-Arne Gronland ,  Bjorn Westerberg ,  Goran Bergman ,  Kjell Anflo ,  Jesper Brandt ,  Ola Lyckfeldt ,  Johan Agrell ,  Anders Ersson ,  Sven Jaras ,  Magali Boutonnet ,  Niklas Wingborg

IPC: B01J21/04 ,  B01J23/02 ,  B01J23/10 ,  B01J23/34 ,  B01J23/40 ,  B01J23/46 ,  B01J35/00 ,  B01J35/02 ,  B01J35/08 ,  B01J37/00 ,  B01J37/03 ,  C01F7/16 ,  C01F17/00 ,  C04B35/634 ,  C06D5/08 ,  B01J23/00

CPC classification number: C04B35/44 ,  B01J21/04 ,  B01J23/02 ,  B01J23/10 ,  B01J23/34 ,  B01J23/40 ,  B01J23/468 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/023 ,  B01J35/08 ,  B01J37/0018 ,  B01J37/0072 ,  B01J37/033 ,  B82Y30/00 ,  C01F7/16 ,  C01F17/0025 ,  C01P2004/50 ,  C01P2006/13 ,  C04B35/634 ,  C04B2235/3205 ,  C04B2235/3217 ,  C04B2235/3224 ,  C04B2235/3227 ,  C04B2235/3262 ,  C04B2235/441 ,  C04B2235/443 ,  C04B2235/5409 ,  C04B2235/72 ,  C06D5/08

Abstract: The present invention relates to a reactor for the decomposition of ammonium dinitramide-based liquid monopropellants into hot, combustible gases for combustion in a combustion chamber, and more particularly a rocket engine or thruster comprising such reactor and a combustion chamber. The invention also relates to a process for the decompostion of ammonium dinitramide-based liquid monopropellants.

Abstract translation: 本发明涉及一种用于将二硝化铵基液体单组元推进剂分解成用于在燃烧室中燃烧的热可燃气体的反应器，更具体地涉及包括这种反应器和燃烧室的火箭发动机或推进器。 本发明还涉及一种用于分解二硝基铵的液体单推进剂的方法。

公开(公告)号：US5929260A

公开(公告)日：1999-07-27

申请号：US646277

申请日：1996-05-16

Applicant: Claudius Kormann ,  Thomas Wettling ,  Ekkehard Schwab ,  Jochem Henkelmann

Inventor： Claudius Kormann ,  Thomas Wettling ,  Ekkehard Schwab ,  Jochem Henkelmann

IPC: B01J23/89 ,  B01J35/00 ,  B01J35/08 ,  B01J37/02 ,  B01J38/00 ,  C07B35/02 ,  C07D301/00

CPC classification number: C07D301/00 ,  B01J35/0033 ,  B01J37/0221 ,  C07B35/02

Abstract: Catalysts are composed ofa) a magnetizable core,b) which may be coated with a binder andc) which carries catalytically active metals or metal compounds on its surface.

Abstract translation: PCT No.PCT / EP94 / 03747 371日期：1996年5月16日 102（e）日期1996年5月16日PCT 1994年11月11日PCT PCT。 公开号WO95 / 13874 日期1995年5月26日催化剂由a）可磁化的芯组成，b）可以用粘合剂涂覆，c）其表面上带有催化活性金属或金属化合物。

公开(公告)号：US5889187A

公开(公告)日：1999-03-30

申请号：US808649

申请日：1997-02-28

Applicant: Canh Nguyen Than ,  Blaise Didillon ,  Patrick Sarrazin ,  Charles Cameron

Inventor： Canh Nguyen Than ,  Blaise Didillon ,  Patrick Sarrazin ,  Charles Cameron

IPC: B01J23/44 ,  B01J23/48 ,  B01J23/50 ,  B01J23/58 ,  B01J23/66 ,  B01J35/00 ,  B01J35/02 ,  B01J35/08 ,  C07B61/00 ,  C07C5/09 ,  C07C7/167 ,  C07C11/04 ,  C07C11/06 ,  B01J21/04

CPC classification number: C07C5/09 ,  B01J23/44 ,  B01J23/48 ,  B01J23/50 ,  B01J23/58 ,  B01J23/66 ,  B01J35/0006 ,  C07C7/167 ,  B01J35/008 ,  C07C2521/04 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/44 ,  C07C2523/50 ,  C07C2523/66 ,  Y02P20/52

Abstract: A process for the selective hydrogenation in the gas phase of acetylene compounds containing 2 or 3 carbon atoms to the corresponding ethylene compounds is described. The process uses a catalyst in the form of spherules or extrudates containing palladium, at least one group IB metal, optionally at least one alkaline or alkaline-earth metal and alumina, in which at least 80% of the palladium and at least 80% of the group IB element are present in a volume at the periphery of the catalyst defined between a spherical or cylindrical surface of radius r.sub.1 corresponding to the average spherule or extrudate diameter and a spherical or cylindrical surface of radius r.sub.2 at least equal to 0.8r.sub.1. More particularly, the catalyst comprises an alumina, palladium in a proportion of 0.01% to 0.5% by weight, and group IB metal in a proportion of 0.001 to 0.02% by weight, with a weight ratio of group IB metal/palladium of 0.05 to 0.25.

Abstract translation: 对相应的乙烯化合物的含有2或3个碳原子的乙炔化合物气相的选择氢化的方法进行了描述。 该方法使用包含钯，至少一种IB族金属，任选至少一种碱金属或碱土金属和氧化铝的球形或挤出物形式的催化剂，其中至少80％的钯和至少80％的钯 IB族元素存在于催化剂外围的体积中，所述体积定义在对应于平均球粒或挤出物直径的半径r1的球形或圆柱形表面之间，并且半径r2的球形或圆柱形表面至少等于0.8r1。 更具体地，催化剂包含氧化铝，0.01重量％至0.5重量％的比例的钯，和比例为0.001至0.02重量％的IB族金属，IB金属/钯的重量比为0.05至 0.25。

公开(公告)号：US5625013A

公开(公告)日：1997-04-29

申请号：US422937

申请日：1995-05-24

Applicant: Hans-Joachim Mueller ,  Godofredo Follmer ,  Rainer Konrad ,  Roland Saive ,  Martin Lux ,  Hans-Helmut Goertz ,  Guido Funk

Inventor： Hans-Joachim Mueller ,  Godofredo Follmer ,  Rainer Konrad ,  Roland Saive ,  Martin Lux ,  Hans-Helmut Goertz ,  Guido Funk

IPC: C08F4/02 ,  C08F4/22 ,  C08F4/24 ,  C08F10/00 ,  B01J35/08

CPC classification number: C08F10/00

Abstract: A process for the preparation of a supported catalyst for the polymerization of .alpha.-olefins, in which(1) a silicon dioxide-containing support gel is prepared by(1.1) introducing a sodium water glass or potassium water glass solution into a swirling stream of an aqueous mineral acid longitudinally and tangentially to the stream, spraying the resultant silica hydrosol in drop form into a gaseous medium and allowing it to solidify to form a hydrogel, and freeing the resultant hydrogel from salts by washing without prior ageing,(1.2) drying the hydrogel resulting from (1.1) to form the support gel,(2) the support gel (1) is charged with chromium trioxide or a chromium compound which can be converted into chromium trioxide under the conditions of process step (3), giving a chromium-containing support gel, and(3) the chromium-containing support gel (2) is heated at from 400.degree. to 1100.degree. C. for from 10 to 1000 minutes in an anhydrous gas stream containing oxygen in a concentration of greater than 10% by volume,comprises drying the hydrogel resulting from step (1.1) in step (1.2) within a time of not more than 60 seconds in a shaping, high-speed dryer at an inlet temperature of from 80.degree. to 400.degree. C.

Abstract translation: 一种制备用于α-烯烃聚合的负载催化剂的方法，其中（1）含二氧化硅的载体凝胶通过（1.1）将钠水玻璃或钾水玻璃溶液引入旋流 将水性无机酸纵向和切向于料流，将所得的二氧化硅水溶胶以液滴形式喷雾到气态介质中并使其固化形成水凝胶，并通过在没有预先熟化的情况下洗涤将所得水凝胶从盐中释放，（1.2）干燥 由（1.1）产生的形成支持凝胶的水凝胶，（2）载体凝胶（1）中加入三氧化铬或铬化合物，其可以在工艺步骤（3）的条件下转化为三氧化铬，得到 含铬载体凝胶，（3）含铬载体凝胶（2）在含有浓度浓度的氧的无水气流中在400〜1100℃下加热10〜1000分钟 大于10体积％包括在入口温度为80°至400°的成形高速干燥器中在不超过60秒的时间内将步骤（1.2）中由步骤（1.1）得到的水凝胶干燥 DEG C.

公开(公告)号：US5500396A

公开(公告)日：1996-03-19

申请号：US385619

申请日：1995-02-09

Applicant: Joel L. Martin

Inventor： Joel L. Martin

IPC: C07F3/02 ,  B01J27/138 ,  B01J31/02 ,  B01J31/26 ,  B01J32/00 ,  B01J35/08 ,  B01J37/00 ,  C01F5/30 ,  C08F4/02 ,  C08F4/06 ,  C08F4/10 ,  C08F4/654 ,  C08F10/00

CPC classification number: B01J35/08 ,  B01J27/138 ,  B01J31/0202 ,  B01J31/26 ,  C01F5/30 ,  C08F4/022 ,  B01J37/0072 ,  C01P2004/32 ,  C01P2004/61 ,  C01P2006/22

Abstract: A process to make a small, discrete, spherical magnesium dihalide alcohol adduct is provided. This process comprises: contacting a magnesium dihalide and an alcohol in a high-viscosity liquid that consists of hydrocarbons, to obtain a dispersion; heating and agitating the dispersion to obtain a molten dipersion; cooling the molten dispersion to form said small, discrete, spherical magnesium dihalide alcohol adduct.

Abstract translation: 提供了制备小型离散球形二卤化镁醇加合物的方法。 该方法包括：使由二氧化碳组成的高粘度液体中的二卤化镁与醇接触得到分散体; 加热并搅拌分散体以获得熔融浸渍液; 冷却熔融分散体形成所述小的离散的球形二卤化镁醇加合物。

公开(公告)号：US5464593A

公开(公告)日：1995-11-07

申请号：US273874

申请日：1994-07-12

Applicant: Kazuo Takahashi ,  Fumio Kumata ,  Hitoshi Nozaki ,  Shinichi Inoue ,  Toshiji Makabe

Inventor： Kazuo Takahashi ,  Fumio Kumata ,  Hitoshi Nozaki ,  Shinichi Inoue ,  Toshiji Makabe

IPC: B01J29/06 ,  B01J29/40 ,  B01J35/08 ,  B01J20/18

CPC classification number: B01J29/06 ,  B01J29/40 ,  B01J35/08 ,  B01J2229/42

Abstract: A process for producing a spherical zeolite catalyst is disclosed, which comprises dropping a zeolite-containing alumina sol into a surfactant-containing oil phase from a dropping opening directly or through air to thereby form spherical droplets of the sol, and then allowing the droplets to gel in an aqueous alkaline solution phase underlying the oil phase and withdrawing the thus gelled droplets, said dropping of the sol being conducted while the dropping opening is being impulsed to thereby impart a spherical and uniform shape to the resulting zeolite particles containing alumina as a binder, and a novel apparatus therefor.

Abstract translation: 公开了一种制备球形沸石催化剂的方法，其包括将含沸石的氧化铝溶胶直接或通过空气从滴入口滴入含表面活性剂的油相中，从而形成溶胶的球形液滴，然后使液滴 凝胶在水相下面的碱性溶液相中并且抽出如此凝胶化的液滴，当滴下的开口被冲击时，所述溶胶的滴下被引导，从而赋予所得到的含有氧化铝作为粘合剂的沸石颗粒的球形和均匀形状 ，及其新颖的装置。