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公开(公告)号:US11247193B2
公开(公告)日:2022-02-15
申请号:US16608342
申请日:2018-04-23
Applicant: IFP Energies Nouvelles
Inventor: Sophie Bernadet , Antoine Fecant , Denis Uzio , Renal-Vasco Backov , Serge Ravaine
IPC: B01J21/18 , B01J21/06 , B01J23/10 , B01J35/00 , B01J35/04 , B01J35/08 , B01J35/10 , B01J37/04 , B01J37/08
Abstract: Process for preparing a porous monolith comprising between 10% and 100% by weight of a semiconductor relative to the total weight of the porous monolith, which process comprises the following steps: a) a first aqueous suspension containing polymer particles is prepared; b) a second aqueous suspension containing particles of least one inorganic semiconductor is prepared; c) the two aqueous suspensions prepared in steps a) and b) are mixed in order to obtain a paste; d) a heat treatment of the paste obtained in step c) is carried out in order to obtain the monolith with multimodal porosity.
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公开(公告)号:US11077427B2
公开(公告)日:2021-08-03
申请号:US16608312
申请日:2018-04-23
Applicant: IFP Energies Nouvelles
Inventor: Sophie Bernadet , Antoine Fecant , Denis Uzio , Renal-Vasco Backov , Serge Ravaine
IPC: B01J21/08 , B01J21/06 , B01J35/00 , B01J35/04 , B01J35/10 , B01J37/02 , B01J37/03 , B01J37/04 , B01J37/08
Abstract: The invention relates to a porous monolith comprising between 20 wt.-% and 70 wt.-% TiO 2 relative to the total weight of the monolith, and between 30 wt.-% and 80 wt.-% a refractory oxide, selected from silica, alumina or silica-alumina, relative to the total weight of the monolith, characterized in that said porous monolith has a bulk density of less than 0.19 g/mL.
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公开(公告)号:US10695753B2
公开(公告)日:2020-06-30
申请号:US15518931
申请日:2015-10-06
Applicant: Centre National de la Recherche Scientifique , Universite Claude Bernard—Lyon 1 , IFP Energies Nouvelles
Inventor: Dina Lofficial , Antoine Fecant , Denis Uzio , Eric Puzenat , Christophe Geantet
IPC: B01J23/26 , B01J23/66 , B01J37/03 , B01J37/34 , B01J23/62 , B01J35/00 , C01B3/26 , C01B3/22 , B01J35/02 , B01J37/00 , B01J37/04 , B01J37/06 , B01J37/08
Abstract: The invention relates to a composition that contains a first semiconductor SC1, particles that comprise one or more element(s) M in the metal state selected from among an element of groups IVB, VB, VIB, VIIB, VIIIB, IB, IIB, IIIA, IVA and VA of the periodic table, and a second semiconductor SC2 that comprises indium oxide, with said first semiconductor SC1 being in direct contact with said particles that comprise one or more element(s) M in the metal state, with said particles being in direct contact with said second semiconductor SC2 that comprises indium oxide in such a way that the second semiconductor SC2 covers at least 50% of the surfaces of the particles that comprise one or more element(s) M in the metal state. The invention also relates to its preparation method as well as its application of photocatalysis.
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公开(公告)号:US10682630B2
公开(公告)日:2020-06-16
申请号:US15518967
申请日:2015-10-06
Applicant: IFP ENERGIES NOUVELLES , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE , UNIVERSITE CLAUDE BERNARD—LYON 1
Inventor: Dina Lofficial , Antoine Fecant , Denis Uzio , Eric Puzenat , Christophe Geantet
Abstract: The invention relates to a composition that contains a first semiconductor SC1, particles that comprise one or more element(s) M in the metal state selected from among an element of groups IVB, VB, VIB, VIIB, VIIIB, IB, IIB, IIIA, IVA and VA of the periodic table, and a second semiconductor SC2 that comprises cerium oxide, with said first semiconductor SC1 being in direct contact with said particles that comprise one or more element(s) M in the metal state, with said particles being in direct contact with said second semiconductor SC2 that comprises cerium oxide in such a way that the second semiconductor SC2 covers at least 50% of the surfaces of the particles that comprise one or more element(s) M in the metal state. The invention also relates to its preparation method as well as its application of photocatalysis.
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公开(公告)号:US09796935B2
公开(公告)日:2017-10-24
申请号:US15029966
申请日:2014-09-19
Applicant: IFP Energies nouvelles
Inventor: Fabien Corvaisier , Antoine Fecant , Cecile Thomazeau , Pascal Raybaud , Yves Schuurman , David Farrusseng
CPC classification number: C10G45/34 , B01J21/04 , B01J23/745 , B01J23/80 , B01J35/0006
Abstract: The invention concerns a method for selectively hydrogenating a hydrocarbon charge containing at least two carbon atoms per molecule, having a final boiling point which is less than or equal to 250° C., and comprising at least one polyunsaturated compound, wherein the charge, in the presence of hydrogen, is brought into contact with at least one catalyst comprising a carrier and an active metal phase deposited on the carrier, the active metal phase comprising iron and at least one metal selected from zinc and copper in a molar ratio of Fe:(Zn and/or Cu) of between 0.35 and 0.99.
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公开(公告)号:US11806695B2
公开(公告)日:2023-11-07
申请号:US17622886
申请日:2020-06-16
Applicant: IFP Energies Nouvelles
Inventor: Antoine Fecant , Raquel Martinez Franco , Gerhard Pirngruber , Philibert Leflaive
CPC classification number: B01J27/04 , B01D53/007 , B01D53/8671 , B01J31/0237 , B01J35/004 , C01B32/40 , C07C1/02 , B01D2255/2094 , B01D2255/20792 , B01D2255/802 , B01D2255/9205 , B01D2257/504 , C07C2523/06 , C07C2523/14 , C07C2527/04 , C07C2531/02
Abstract: The invention describes a process for the photocatalytic reduction of carbon dioxide carried out in the liquid phase and/or in the gas phase under irradiation employing a photocatalyst of microporous crystalline metal sulfide type, said process being carried out by bringing a charge containing the CO2 and at least one sacrificial compound into contact with said photocatalyst, then by irradiating the photocatalyst by at least one irradiation source producing at least one wavelength lower than the bandgap width of said photocatalyst, so as to reduce the CO2 and to oxidize the sacrificial compound, so as to produce an effluent containing, at least in part, C1 or more carbon-based molecules other than CO2.
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公开(公告)号:US11660590B2
公开(公告)日:2023-05-30
申请号:US16558597
申请日:2019-09-03
Applicant: IFP Energies Nouvelles
Inventor: Elodie Tellier , Dominique Decottignies , Antoine Fecant
IPC: B01J23/75 , B01J37/02 , B01J37/08 , B01J35/10 , B01J23/72 , B01J23/745 , B01J23/80 , B01J23/34 , B01J23/755 , B01J21/12
CPC classification number: B01J37/0201 , B01J21/12 , B01J23/34 , B01J23/72 , B01J23/745 , B01J23/75 , B01J23/755 , B01J23/80 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J37/0236 , B01J37/08
Abstract: Process for preparing a catalyst or a trapping mass comprising the following steps:
bringing a porous oxide support into contact with a metal salt comprising at least one metal belonging to groups VIB, VIIB, VIIIB, IB or IIB, of which the melting point of said metal salt is between 20° C. and 150° C., for a period of between 5 minutes and 5 hours in order to form a solid mixture, the weight ratio of said metal salt to said porous oxide support being between 0.1 and 1;
heating the solid mixture with stirring at a temperature between the melting point of said metal salt and 200° C. and for 5 minutes to 12 hours;
calcining the solid obtained in the preceding step at a temperature above 200° C. and below or equal to 1100° C. under an inert atmosphere or under an oxygen-containing atmosphere.-
公开(公告)号:US11583836B2
公开(公告)日:2023-02-21
申请号:US17382478
申请日:2021-07-22
Applicant: IFP Energies Nouvelles
Inventor: Mathieu Digne , Antoine Fecant , Chloe Bertrand-Drira
Abstract: The present invention relates to a process for deparaffinning a middle distillate feedstock, to convert, in good yield, feedstocks having high pour points into at least one cut having an improved pour point.
Said process is performed with at least one catalyst comprising at least one hydro-dehydrogenating phase containing at least one metal from group VIB and at least one metal from group VIII of the Periodic Table of the Elements, and a support comprising at least one IZM-2 zeolite, a zeolite of WI framework type code and at least one binder.-
公开(公告)号:US10655069B2
公开(公告)日:2020-05-19
申请号:US15778101
申请日:2016-11-07
Applicant: IFP Energies Nouvelles
Inventor: Alexandra Chaumonnot , Antoine Fecant
IPC: C10G2/00 , B01J23/74 , B01J23/75 , B01J37/18 , B01J29/03 , B01J35/10 , B01J37/00 , B01J23/89 , B01J35/08 , B01J37/02 , B01J37/04 , B01J37/08 , B01J37/03
Abstract: A process for the synthesis of linear paraffinic hydrocarbons from a feed of carbon monoxide and dihydrogen in the presence of a catalyst of a mesoporous oxide matrix and a content by weight of the element cobalt of 0.5% to 60%, wherein the catalyst is prepared by a) mixing, in an aqueous or hydro-organic solvent, a molecular precursor containing cobalt and a molecular precursor of the mesoporous oxide matrix containing element X of silicon, aluminium, titanium, zirconium and or cerium; b) aerosol spray drying the mixture to form spherical liquid droplets; c) drying to obtain solid particles at a temperature of 10° C. to 300° C.; d) activation by a reduction treatment to form nanoparticles of cobalt with an oxidation state of 0.
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公开(公告)号:US10563131B2
公开(公告)日:2020-02-18
申请号:US15778508
申请日:2016-11-07
Applicant: IFP Energies nouvelles
Inventor: Alexandra Chaumonnot , Antoine Fecant
Abstract: A process for the synthesis of linear paraffinic hydrocarbons from a feed comprising carbon monoxide and dihydrogen in the presence of a mesoporous oxide matrix and cobalt prepared by mixing, at least one molecular precursor of cobalt and at least one colloidal precursor of mesoporous oxide matrix and by silicon, aluminium, titanium, zirconium, cerium or mixtures thereof, dissolved in aqueous or hydro-organic solvent; spray drying the mixture obtained to form spherical liquid droplets; drying the droplets to obtain solid particles activating the solid particles by reduction to form nanoparticles of cobalt with an oxidation state of 0.
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