Non-plasma etch of titanium-containing material layers with tunable selectivity to alternate metals and dielectrics

    公开(公告)号:US11322350B2

    公开(公告)日:2022-05-03

    申请号:US16868277

    申请日:2020-05-06

    Abstract: Embodiments provide a non-plasma etch, such as a gas-phase and/or remote plasma etch, of titanium-containing material layers with tunable selectivity to other material layers. A substrate is received within a process chamber, and the substrate has exposed material layers including a titanium-containing material layer and at least one additional material layer. The additional material layer is selectively etched with respect to the titanium-containing material layer by exposing the substrate to a controlled environment including a halogen-containing gas. For one embodiment, the halogen-containing gas includes a fluorine-based gas. For one embodiment, the titanium-containing material layer is a titanium or a titanium nitride material layer. For one embodiment, the additional material layer includes tungsten, tungsten oxide, hafnium oxide, silicon oxide, silicon-germanium, silicon, silicon nitride, and/or aluminum oxide. A non-selective etch with respect to the titanium-containing material layer can be performed by modulating the process parameters such as temperature.

    Method and system for selective spacer etch for multi-patterning schemes

    公开(公告)号:US09748110B2

    公开(公告)日:2017-08-29

    申请号:US15247138

    申请日:2016-08-25

    Abstract: Provided is a method for increasing pattern density of a structure on a substrate using an integration scheme, the method comprising: providing a substrate having a first spacer pattern and an underlying layer, the underlying layer comprising a first underlying layer, a second underlying layer, and a target layer; performing a conformal spacer deposition using an oxide, the deposition creating a conformal layer; performing a spacer RIE process and a pull process, thereby generating a second spacer pattern, the spacer RIE process includes adsorption of N-containing gas on a surface of the substrate which activates the surface to react with an F- and/or an H-containing gas to form fluorosilicates; and wherein the integration targets include selectively etching spacer films within a target spacer etch rate, enhanced simultaneous selectivity to the first underlying layer and the second underlying layer and preventing pattern damage.

    GAS PHASE ETCH WITH CONTROLLABLE ETCH SELECTIVITY OF Si-CONTAINING ARC OR SILICON OXYNITRIDE TO DIFFERENT FILMS OR MASKS
    17.
    发明申请
    GAS PHASE ETCH WITH CONTROLLABLE ETCH SELECTIVITY OF Si-CONTAINING ARC OR SILICON OXYNITRIDE TO DIFFERENT FILMS OR MASKS 审中-公开
    具有可控硅选择性的气相相位选择性不同的薄膜或掩模的硅或硅氧化物

    公开(公告)号:US20160379842A1

    公开(公告)日:2016-12-29

    申请号:US15191956

    申请日:2016-06-24

    Abstract: A method for the dry removal of a material on a microelectronic workpiece is described. The method includes receiving a workpiece having a surface exposing a target layer composed of silicon and either (1) organic material or (2) both oxygen and nitrogen, and selectively removing at least a portion of the target layer from the workpiece. The selective removal includes exposing the surface of the workpiece to a chemical environment containing N, H, and F at a first setpoint temperature to chemically alter a surface region of the target layer, and then, elevating the temperature of the workpiece to a second setpoint temperature to remove the chemically treated surface region of the target layer.

    Abstract translation: 描述了用于干燥去除微电子工件上的材料的方法。 该方法包括接收具有暴露由硅构成的目标层的表面和(1)有机材料或(2)氧和氮两者的表面的工件,并且从工件中选择性地去除目标层的至少一部分。 选择性去除包括将工件的表面暴露于含有N,H和F的化学环境处于第一设定点温度以化学改变目标层的表面区域,然后将工件的温度升高到第二设定点 温度以去除目标层的化学处理的表面区域。

    Etch Selectivity Modulation by Fluorocarbon Treatment

    公开(公告)号:US20250069896A1

    公开(公告)日:2025-02-27

    申请号:US18453843

    申请日:2023-08-22

    Abstract: A method of fabricating a field effect transistor (FET) over a substrate that includes: growing a doped p-type semiconductor from a silicon nanosheet of the substrate, the substrate including a layer stack of alternating layers of the silicon nanosheet and a sacrificial layer, and a dummy gate formed over the layer stack, the layer stack including a trench exposing sidewalls of the layer stack, the doped p-type semiconductor and the sacrificial layer being separated by a dielectric inner spacer; removing the dummy gate; and etching the sacrificial layer selectively to the doped p-type semiconductor, the etching including exposing the substrate to a process gas including a fluorocarbon and a fluorine-containing etch gas in the absence of plasma.

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