公开(公告)号：US20200071344A1

公开(公告)日：2020-03-05

申请号：US16550847

申请日：2019-08-26

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Oleg V. Samsonov ,  Mikhail I. Sharikov ,  Georgy P. Goryunov ,  Dmitry Dmitry Uborsky ,  Alexander Z. Voskoboynikov ,  Michelle E. Titone ,  John R. Hagadorn ,  Jo Ann M. Canich

IPC: C07F7/00 ,  C08F4/76 ,  C07C209/60 ,  C07F5/04 ,  C07D215/40 ,  C07C221/00 ,  C07C201/08 ,  C07C45/65

Abstract: The present disclosure provides methods for making quinolinyldiamine products from quinolinyl starting materials. In addition, the quinolinyldiamines can be used as ligands or ligand precursors for catalysts, e.g. for use in olefin polymerization.

公开(公告)号：US20170217865A1

公开(公告)日：2017-08-03

申请号：US15515271

申请日：2015-10-07

Applicant: SYNGENTA PARTICIPATIONS AG

Inventor： Denis GRIBKOV

IPC: C07C45/63 ,  C07C201/08 ,  C07C205/45 ,  C07C45/46

CPC classification number: C07C45/63 ,  C07C45/46 ,  C07C201/08 ,  C07C201/12 ,  C07C205/45 ,  C07C49/80

Abstract: A process for the preparation of a compound of formula (I) wherein R1 is hydrogen, fluoro or chloro; which process comprises: a) reacting a compound of formula (II) wherein R1 is hydrogen, fluoro or chloro; with a nitration agent to the compound of formula (III) wherein R1 is hydrogen, fluoro or chloro; b) reacting the compound of formula (III) with trichloroisocyanuric acid in the presence of sulfuric acid or fuming sulfuric acid to the compound of formula (IV) wherein R1 is hydrogen, fluoro or chloro; and c) reacting the compound of formula (III) with chlorine gas at a temperature from 180° C. to 250° C. to the compound of formula (I).

公开(公告)号：US20170152210A1

公开(公告)日：2017-06-01

申请号：US15320807

申请日：2015-06-22

Applicant: COVESTRO DEUTSCHLAND AG

Inventor： Thomas KNAUF ,  Peter DRINDA ,  Stefan WERSHOFEN ,  Klaus-Gerd GRUNER ,  Volker HARTJES

IPC: C07C201/08 ,  B01J19/24 ,  C07C201/16

CPC classification number: C07C201/08 ,  B01J19/24 ,  B01J2208/00637 ,  B01J2208/00646 ,  B01J2208/00716 ,  B01J2219/00033 ,  B01J2219/24 ,  C07C201/16 ,  C07C205/06

Abstract: This invention relates to methods for producing chemical products, wherein the one or more feed materials are reacted to form a chemical product or a chemical composition. The invention further relates to plants for performing such methods, said plants being designed in such a way that, during an interruption of the methods, no input of at least one feed material into the reaction occurs and the plant parts not affected by a revision measure, maintenance measure, repair measure, or cleaning measure are operated in so-called re-circulation mode. It is thereby achieved, among other things, that only the affected plant part needs to be shut down for the time of the measure, which can be advantageous with regard to the productivity and economy of the method and the quality of the produced products. Finally, the invention relates to methods for operating plants in the event that individual plant parts are taken out of service.

公开(公告)号：US09663445B2

公开(公告)日：2017-05-30

申请号：US14801001

申请日：2015-07-16

Applicant: SUMITOMO RUBBER INDUSTRIES, LTD.

Inventor： Takayuki Hattori ,  Takao Wada ,  Keitaro Fujikura ,  Yuka Yokoyama ,  Toshiro Matsuo

IPC: C07C15/46 ,  C07C211/46 ,  C07C209/04 ,  C07C37/16 ,  B01J29/40 ,  B01J29/46 ,  B01J29/48 ,  B60C1/00 ,  C07C1/20 ,  C07C201/08 ,  C07C209/36 ,  C12P7/22 ,  C12P7/28 ,  C07C1/22 ,  C08F236/10 ,  C08G73/02 ,  C08L9/06 ,  C07C209/18 ,  C07C1/24 ,  C07C2/68

CPC classification number: C07C209/04 ,  B01J29/40 ,  B01J29/46 ,  B01J29/48 ,  B60C1/0016 ,  C07C1/20 ,  C07C1/22 ,  C07C1/24 ,  C07C2/68 ,  C07C15/46 ,  C07C37/16 ,  C07C201/08 ,  C07C209/18 ,  C07C209/36 ,  C07C211/46 ,  C07C2521/04 ,  C07C2527/126 ,  C07C2529/18 ,  C07C2529/40 ,  C08F236/10 ,  C08G73/02 ,  C08L9/06 ,  C08L2205/025 ,  C08L2205/03 ,  C12P7/22 ,  C12P7/28 ,  C12P2203/00 ,  Y02P20/52 ,  C07C205/06 ,  C07C11/167 ,  C07C15/04 ,  C07C11/04 ,  C07C37/004 ,  C07C39/04 ,  C07C37/11

Abstract: The present invention provides a synthesis system that can synthesize aniline and/or styrene efficiently, a synthesis system that can synthesize butadiene (1,3-butadiene) efficiently, a rubber chemical for a tire which is synthesized from the aniline obtained by the synthesis system, a synthetic rubber for a tire which is synthesized from the styrene and/or butadiene obtained by the synthesis systems, and a pneumatic tire produced using the rubber chemical for a tire and/or the synthetic rubber for a tire. The present invention relates to a synthesis system for synthesizing aniline and/or styrene from an alcohol having two or more carbon atoms via an aromatic compound.

公开(公告)号：US09434709B2

公开(公告)日：2016-09-06

申请号：US14854780

申请日：2015-09-15

Applicant: Rennovia Inc.

Inventor： Thomas R. Boussie ,  Eric L. Dias ,  Zachary M. Fresco ,  Vincent J. Murphy ,  James Shoemaker ,  Raymond Archer ,  Hong Jiang

IPC: C07C51/36 ,  C07C51/31 ,  C07D309/30 ,  B01J23/40 ,  B01J23/44 ,  B01J23/46 ,  B01J23/52 ,  B01J23/652 ,  B01J23/656 ,  B01J23/89 ,  B01J35/00 ,  B01J37/02 ,  C07C51/235 ,  C07C51/377 ,  C07C51/41 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  C07C201/08 ,  B01J21/06 ,  B01J21/08 ,  B01J21/16 ,  B01J21/18

CPC classification number: C07C51/377 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J21/16 ,  B01J21/18 ,  B01J23/40 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/468 ,  B01J23/52 ,  B01J23/6525 ,  B01J23/6562 ,  B01J23/6567 ,  B01J23/8906 ,  B01J23/8913 ,  B01J23/8926 ,  B01J35/006 ,  B01J37/0205 ,  C07B2200/07 ,  C07C51/235 ,  C07C51/31 ,  C07C51/412 ,  C07C201/08 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  Y02P20/582 ,  C07C55/14 ,  C07C211/12 ,  C07C255/04

Abstract: The present invention generally relates to processes for the chemocatalytic conversion of a glucose source to an adipic acid product. The present invention includes processes for the conversion of glucose to an adipic acid product via glucaric acid or derivatives thereof. The present invention also includes processes comprising catalytic oxidation of glucose to glucaric acid or derivative thereof and processes comprising the catalytic hydrodeoxygenation of glucaric acid or derivatives thereof to an adipic acid product. The present invention also includes products produced from adipic acid product and processes for the production thereof from such adipic acid product.

公开(公告)号：US09428441B2

公开(公告)日：2016-08-30

申请号：US14916210

申请日：2014-09-01

Applicant: BASF SE

Inventor： Yuan Shen Dai ,  Katharina Spuhl ,  Renate Hempel

IPC: C07C205/00 ,  C07C201/16 ,  C07C201/08 ,  C07C205/06

CPC classification number: C07C201/16 ,  C07C201/08 ,  C07C205/06

Abstract: A process for the preparation of dintrotoluene which comprises (a) nitrating toluene with a nitrating acid, wherein said nitrating acid is a mixture of nitric acid and sulfuric acid, in one or more nitration steps, and separating the nitrating acid from the process stream thus formed, wherein a crude mixture comprising dinitrotoluene and a fraction of said nitrating acid dissolved therein is obtained, said crude mixture further comprising at least 50 ppm of HCN, and (b) washing the crude dinitrotoluene containing mixture in one or more washing steps, wherein, before the first washing step is carried out, the crude mixture is distilled and/or stripped to remove HCN therefrom, wherein a crude dinitrotoluene containing mixture which is essentially free of HCN is obtained.

Abstract translation: 一种制备二苯并芴的方法，其包括（a）在一个或多个硝化步骤中将硝酸与硝酸反应，其中所述硝酸是硝酸和硫酸的混合物，并将硝酸与工艺流分离，因此 形成，其中获得包含二硝基甲苯和所述硝酸的一部分溶解在其中的粗混合物，所述粗混合物还包含至少50ppm的HCN，和（b）在一个或多个洗涤步骤中洗涤含有二硝基甲苯的粗混合物，其中 ，在进行第一洗涤步骤之前，将粗混合物蒸馏和/或汽提以从其中除去HCN，其中获得基本上不含HCN的粗二硝基甲苯混合物。

公开(公告)号：US20160145191A1

公开(公告)日：2016-05-26

申请号：US14895867

申请日：2014-06-03

Applicant: COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH

Inventor： Shubhangi Bhalchandra Umbarkar ,  Mohan Keraba Dongare ,  Ankush Venkatrao Biradar ,  Atul Balasaheb Kulal ,  Trupti Vyankatesh Kotbagi ,  Ashvini Ramesh Bhosale ,  Macchindra Gulabrao Chandgude

IPC: C07C201/08 ,  B01J23/30 ,  B01J37/08 ,  B01J37/02 ,  B01J37/04 ,  C07B43/02 ,  B01J21/08

CPC classification number: C07C201/08 ,  B01J21/08 ,  B01J23/30 ,  B01J29/0341 ,  B01J35/1019 ,  B01J37/0236 ,  B01J37/036 ,  B01J37/04 ,  B01J37/08 ,  C07B43/02 ,  Y02P20/588 ,  C07C205/12 ,  C07C205/22 ,  C07C205/06

Abstract: The present invention discloses an improved process for the liquid phase nitration of aromatic compounds catalyzed by WO3 supported on mesoporous silica support, at low temperature, with high conversion and selectivity.

Abstract translation: 本发明公开了一种用于在低温下以高转化率和选择性负载在介孔二氧化硅载体上的WO 3催化的芳族化合物的液相硝化的改进方法。

公开(公告)号：US09340486B2

公开(公告)日：2016-05-17

申请号：US13854491

申请日：2013-04-01

Applicant: ANGUS Chemical Company

Inventor： Mahesh Sawant ,  Daniel M. Trauth ,  John G. Pendergast, Jr.

IPC: B01J19/00 ,  C07C201/08 ,  C07C201/16 ,  C07C201/06 ,  B01J10/00

CPC classification number: C07C201/06 ,  B01J10/00 ,  B01J19/00 ,  C07C201/08 ,  C07C201/16 ,  C07C205/02

Abstract: Disclosed are a process and an apparatus for synthesizing nitroalkanes by reaction of a hydrocarbon feedstock with aqueous nitric acid. Energy and capital costs may be reduced by recycling a majority of the aqueous phase back to the reactor.

公开(公告)号：US20160083332A1

公开(公告)日：2016-03-24

申请号：US14785763

申请日：2014-04-24

Applicant: Covestro Deutschland AG

Inventor： Antoni Mairata ,  Thomas Knauf

IPC: C07C201/08 ,  C07C201/16

CPC classification number: C07C201/08 ,  C07C201/16 ,  C07C205/06

Abstract: The present invention relates to a continuously operated adiabatic process for the preparation of nitrobenzene by nitration of benzene with nitric acid and sulfuric acid, in which the dilute sulfuric acid obtained after the nitration has taken place and the crude nitrobenzene has been separated off from the aqueous phase is concentrated for the purpose of re-use in the nitration, and after its concentration, at least one minute before it comes into contact with fresh nitric acid again an oxidizing agent is added such that a concentration of the oxidizing agent of from 10 ppm to 5,000 ppm, based on the total weight of the concentrated sulfuric acid to be recycled into the nitration, is established.

Abstract translation: 本发明涉及用硝酸和硫酸硝化苯来制备硝基苯的连续操作的绝热方法，其中在硝化发生后获得的稀硫酸和粗硝基苯已从水溶液中分离出来 浓缩的浓度是为了在硝化中重复使用，并且在其浓缩之后，再次与新鲜硝酸接触至少一分钟，加入氧化剂使得氧化剂的浓度为10ppm 至5,000ppm，基于要再循环到硝化中的浓硫酸的总重量。

公开(公告)号：US20150336875A9

公开(公告)日：2015-11-26

申请号：US14046068

申请日：2013-10-04

Applicant: Bayer MaterialScience AG

Inventor： Thomas Knauf ,  Jurgen Munnig ,  Joerg Schmiedler

IPC: C07C201/08

CPC classification number: C07C201/08 ,  C07C201/16 ,  C07C205/06

Abstract: The present invention relates to a method for producing nitrobenzene, in which the waste gas streams accruing in the process and containing benzene and (traces of) nitrobenzene, possibly low- and medium-boiling components, possibly non-condensable gases and possibly water, optionally after removal of nitrogen oxides, are scrubbed in an absorption column with nitrobenzene, which comprises only very small amounts (maximum 50 ppm) of benzene and is distributed by means of a liquid distributor at a rate of 50 to 200 drip points per square metre, preferably 60 to 120 drip points per square metre, wherein (i) a liquid stream containing benzene and nitrobenzene, possibly organic low- and medium-boiling components and additionally containing sulfuric acid if sulfuric acid is used as the scrubbing agent and (ii) waste gas depleted in benzene and possibly in organic low- and medium-boiling components are obtained. A waste gas purified by the method according to the invention is particularly suitable for burning in a thermal exhaust air treatment process.

Abstract translation: 本发明涉及生产硝基苯的方法，其中在该方法中产生的含有苯和（痕量）硝基苯的废气流，可能是低沸点和中沸点组分，可能是不可冷凝气体和可能的水，任选地 在除去氮氧化物之后，用硝基苯洗涤吸收塔，硝基苯仅包含极少量（最大50ppm）的苯，并以50至200滴每平方米的液滴分配器分配， 优选60至120滴/平方米，其中（i）含有苯和硝基苯的液体流，可能是有机低沸点和中沸点组分，如果使用硫酸作为洗涤剂，另外含有硫酸，和（ii）废物 获得了在苯中以及可能在有机低沸点和中沸点组分中贫化的气体。 通过根据本发明的方法净化的废气特别适用于在热排气处理过程中燃烧。