Abstract:
The present invention is directed to the use of aromatic amide-containing phenol alkoxylate compounds having a weight average molecular weight is greater than about 600 as additives in fuel compositions. The invention is also directed to the use of these compounds for decreasing intake valve deposits, controlling octane requirement and reducing octane requirement. The invention is still further directed to the aromatic amide-containing phenol alkoxylate compounds.
Abstract:
A composition comprising:(A) a first component selected from the group consisting of:(i) an oil-soluble ethylene backbone polymer having a number average molecular weight in the range of about 500 to about 50,000;(ii) a hydrocarbyl-substituted phenol of the formula(R*).sub.a --AR--(OH).sub.b I wherein R* is a hydrocarbyl group selected from the group consisting of hydrocarbyl groups of from about 8 to about 30 carbon atoms and polymers of at least 30 carbon atoms, Ar is an aromatic moiety having 0 to 4 optional substituents selected from the group consisting of lower alkyl, lower alkoxyl, nitro, halo or combinations of two or more of said optional substituents, and a and b are each independently an integer of 1 up to 5 times the number of aromatic nuclei present in Ar with the proviso that the sum of a and b does not exceed the unsatisfied valences of Ar;(iii) mixtures of (i) and (ii); and(B) as a second component, the reaction product of (B)(I) a hydrocarbyl-substituted carboxylic acylating agent with (B)(II) one or more amines, one or more alcohols, or a mixture of one or more amines and/or one or more alcohols, the hydrocarbyl substituent of said agent (B)(I) being selected from the group consisting of(i') one or more mono-olefins of from about 8 to about 30 carbon atoms;(ii') mixtures of one or more mono-olefins of from about 8 to about 30 carbon atoms with one or more olefin polymers of at least 30 carbon atoms selected from the group consisting of polymers of mono-1-olefins of from 2 to 8 carbon atoms, or the chlorinated or brominated analogs of such polymers; and(iii') one or more olefin polymers of at least 30 carbon atoms selected from the group consisting of(a) polymers of mono-olefins of from about 8 to about 30 carbon atoms;(b) interpolymers of mono-1-olefins of from 2 to 8 carbon atoms with mono-olefins of from about 8 to about 30 carbon atoms;(c) one or more mixtures of homopolymers and/or interpolymers of mono-1-olefins of from 2 to 8 carbon atoms with homopolymers and/or interpolymers of mono-olefins of from about 8 to about 30 carbon atoms; and(d) chlorinated or brominated analogs of (a), (b), or (c).
Abstract:
Disclosed are selected alkylhydrazine and hydroxyalkylhydrazine adducts of diisocyanates having the formula ##STR1## wherein R.sub.1 is selected from the group consisting of an arylene group containing from 6 to about 12 carbon atoms and a cycloalkylene group containing from about 5 to about 20 carbon atoms; and wherein R.sub.2 is selected from the group consisting of alkyl group containing from 1 to about 20 carbon atoms and hydroxyalkyl group containing from 2 to about 20 carbon atoms. These compounds have utility as antioxidants for a variety of organic compounds subject to oxidative degradation, including functional fluids such as petroleum fuels and lubricants.
Abstract:
Diesel fuel compositions which contain minor amounts of azides having the formula:X=N.sup.+ =N.sup.-where X is selected from the group consisting of ##STR1## where R and R' can be the same or different and are selected from the group consisting of hydrogen; alkyl straight- and branched chain hydrocarbons having from 1 to 8 carbon atoms; alkoxy groups having from 1 to 8 carbon atoms; aryl; aryloxy; nitro; hydroxy; halo; amino (except ortho to the azido); alkylamino; acyl groups having from 2 to 8 carbon atoms; alkylamido; and carbalkoxy. The minor amount of the azides in part improved cetane numbers (low ignition delay) to the diesel fuel.
Abstract:
Disclosure is made of a method of improving the combustion of base fuels selected from ammonia, petroleum distillates, alcohols and amines. The method comprises the addition of hydrogen carriers to the base fuels, which possess an energy content and release it together with hydrogen for combustion upon ignition of the base fuel. The disclosure is also of novel fuel compositions which comprise from 0.5 to 15 percent by weight of a hydrogen carrier dissolved or suspended in the base fuel.
Abstract:
Motor fuel composition comprising a mixture of hydrocarbons in the gasoline boiling range containing a minor detergent amount of an aminimide represented by the formula: ##STR1## in which R' is a hydrocarbon radical having from about 10 to 24 carbon atoms and R is hydrogen or a hydrocarbon radical having from 1 to 20 carbon atoms.