公开(公告)号：US20190105237A1

公开(公告)日：2019-04-11

申请号：US16214224

申请日：2018-12-10

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： William D. Moser ,  Guy D. Joly ,  Ann R. Fornof ,  Ahmed S. Abuelyaman ,  Afshin Falsafi ,  Larry R. Krepski

IPC: A61K6/00 ,  C09J5/00 ,  C08K9/00 ,  C08F222/20 ,  C07C271/28 ,  C09D4/00 ,  C09J4/00 ,  A61K6/083 ,  C08F222/10 ,  C07C69/76

Abstract: Addition-fragmentation agents having the following functional groups: 1) a labile addition-fragmentation group that can cleave and reform to relieve strain, 2) at least one high refractive index group, and 3) at least one ethylenically unsaturated, polymerizable group are described.

公开(公告)号：US10011735B2

公开(公告)日：2018-07-03

申请号：US14419324

申请日：2013-03-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Thomas P. Klun ,  Alan K. Nachtigal ,  Joseph C. Spagnola ,  Mark A. Roehrig ,  Jennifer K. Schnobrich ,  Guy D. Joly ,  Christopher S. Lyons

IPC: H01L51/00 ,  C09D143/04 ,  C07F7/18 ,  H01L51/52 ,  H01L51/44 ,  H01L51/10 ,  B05D3/06 ,  B32B27/30 ,  C08J7/04 ,  C09D133/14 ,  B05D1/00 ,  B05D3/10 ,  C08K3/34 ,  C09D135/02 ,  C23C14/08 ,  C23C14/34 ,  C23C16/40 ,  C23C16/44 ,  C08F130/08 ,  C09J133/14

CPC classification number: C09D143/04 ,  B05D1/60 ,  B05D3/067 ,  B05D3/068 ,  B05D3/101 ,  B32B27/308 ,  B32B2250/04 ,  B32B2307/7242 ,  B32B2307/7244 ,  C07F7/1804 ,  C08F130/08 ,  C08J7/045 ,  C08J2333/12 ,  C08K3/34 ,  C09D133/14 ,  C09D135/02 ,  C09J133/14 ,  C23C14/08 ,  C23C14/34 ,  C23C16/40 ,  C23C16/44 ,  H01L51/004 ,  H01L51/107 ,  H01L51/448 ,  H01L51/5253 ,  Y10T428/1064 ,  Y10T428/31507 ,  Y10T428/31551 ,  Y10T428/31609 ,  Y10T428/31663

Abstract: Diurethane (meth)acrylate-silane precursor compounds prepared by reacting a primary or secondary aminosilane with a cyclic carbonate to yield a hydroxylalkylene-carbamoylalkylene-alkoxysilanes (referred to as a “hydroxylcarbamoylsilane”), which is reacted with a (meth)acrylated material having isocyanate functionality, either neat or in solvent, and optionally with a catalyst, such as a tin compound. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one diurethane (meth)acrylate-silane precursor compound. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making the diurethane (meth)acrylate-silane and their use in composite films and electronic devices are described.

公开(公告)号：US09790396B2

公开(公告)日：2017-10-17

申请号：US14416303

申请日：2013-03-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Thomas P. Klun ,  Alan K. Nachtigal ,  Joseph C. Spagnola ,  Mark A. Roehrig ,  Jennifer K. Schnobrich ,  Guy D. Joly ,  Christopher S. Lyons

IPC: C09D143/04 ,  C07F7/18 ,  H01L51/00 ,  H01L51/52 ,  H01L51/44 ,  H01L51/10 ,  B05D3/06 ,  B32B27/30 ,  C08J7/04 ,  C09D133/14 ,  B05D1/00 ,  B05D3/10 ,  C08K3/34 ,  C09D135/02 ,  C23C14/08 ,  C23C14/34 ,  C23C16/40 ,  C23C16/44 ,  C08F130/08 ,  C09J133/14

CPC classification number: C09D143/04 ,  B05D1/60 ,  B05D3/067 ,  B05D3/068 ,  B05D3/101 ,  B32B27/308 ,  B32B2250/04 ,  B32B2307/7242 ,  B32B2307/7244 ,  C07F7/1804 ,  C08F130/08 ,  C08J7/045 ,  C08J2333/12 ,  C08K3/34 ,  C09D133/14 ,  C09D135/02 ,  C09J133/14 ,  C23C14/08 ,  C23C14/34 ,  C23C16/40 ,  C23C16/44 ,  H01L51/004 ,  H01L51/107 ,  H01L51/448 ,  H01L51/5253 ,  Y10T428/1064 ,  Y10T428/31507 ,  Y10T428/31551 ,  Y10T428/31609 ,  Y10T428/31663

Abstract: Urethane (multi)-(meth)acrylate (multi)-silane compositions, and articles including a (co)polymer reaction product of at least one urethane (multi)-(meth)acrylate (multi)-silane precursor compound. The disclosure also articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urethane (multi) (meth)acrylate (multi)-silane precursor compound. The substrate may be a (co)polymeric film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making urethane (multi)-(meth)acrylate (multi)-silane precursor compounds and their use in composite multilayer barrier films are also described. Methods of using such barrier films in articles selected from a solid state lighting device, a display device, and combinations thereof, are also described.

公开(公告)号：US09532929B2

公开(公告)日：2017-01-03

申请号：US14915429

申请日：2014-09-05

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ann R. Fornof ,  William H. Moser ,  Ahmed S. Abuelyaman ,  Guy D. Joly ,  Larry R. Krepski

IPC: C08F2/46 ,  C08F2/50 ,  C08G61/04 ,  A61K6/083 ,  C08F2/38 ,  C08K5/38 ,  A61K6/00 ,  C08F220/20 ,  C07C381/00

CPC classification number: A61K6/083 ,  A61K6/0023 ,  A61K6/0047 ,  A61K6/005 ,  A61K6/0052 ,  A61K6/0088 ,  C07C381/00 ,  C08F2/38 ,  C08F220/20 ,  C08F2438/03 ,  C08K5/38 ,  C08L33/10 ,  C08F2222/1013 ,  C08F2220/382

Abstract: The present disclosure provides addition-fragmentation oligomers of the general formula: The crosslinking oligomers of this disclosure provide stress relief by including labile crosslinks that can cleave and reform during the polymerization process.

Abstract translation: 本公开提供了通式的加成 - 断裂低聚物：本公开的交联低聚物通过包括可在聚合过程中切割和改性的不稳定交联而提供应力消除。

公开(公告)号：US09477354B2

公开(公告)日：2016-10-25

申请号：US13832457

申请日：2013-03-15

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Encai Hao ,  Abdujabar K. Dire ,  Albert I. Everaerts ,  Aya Nakada ,  Ross E. Behling ,  Guy D. Joly ,  David B. Olson

IPC: G06F3/044 ,  G02B1/115 ,  H05K1/02

CPC classification number: G06F3/044 ,  G02B1/115 ,  G06F2203/04103 ,  H05K1/0274 ,  H05K2201/0108 ,  H05K2201/0326 ,  Y10T156/10 ,  Y10T428/1452 ,  Y10T428/24942 ,  Y10T428/31649 ,  Y10T428/31797 ,  Y10T428/31928

Abstract: An article includes a patterned substrate including a substrate surface with an inorganic electro-conductive trace adjacent thereto (wherein the substrate and the inorganic material of the trace each has an index of refraction), and a layer including a polymerized acrylate matrix adjacent to at least a portion of the surface of the substrate and the inorganic electro-conductive trace, wherein the layer has an index of refraction that is within ±10% of the average of the indices of refraction of the substrate and the inorganic material of the trace.

Abstract translation: 一种制品包括图案化衬底，其包括具有与其相邻的无机导电迹线的衬底表面（其中衬底和迹线的无机材料各自具有折射率），以及包括至少相邻的聚合的丙烯酸酯基体的层 衬底的表面的一部分和无机导电迹线，其中该层的折射率在衬底的折射率和迹线的无机材料的平均值的±10％以内。

公开(公告)号：US09463146B2

公开(公告)日：2016-10-11

申请号：US14652134

申请日：2013-11-27

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ann R. Fornof ,  William H. Moser ,  Larry R. Krepski ,  Guy D. Joly ,  Ahmed S. Abuelyaman ,  Afshin Falsafi ,  Babu N. Gaddam

IPC: A61K6/083 ,  C09D133/14 ,  C09J133/14 ,  C08K3/36 ,  C07C69/604 ,  C07C67/26 ,  C07C271/16 ,  C07C269/02 ,  A61C19/06 ,  C08F2/38 ,  C08F220/18 ,  C08F220/56

CPC classification number: A61K6/0835 ,  A61C19/063 ,  A61K6/083 ,  C07C67/26 ,  C07C69/604 ,  C07C269/02 ,  C07C271/16 ,  C08F2/38 ,  C08F220/18 ,  C08F220/56 ,  C08F2438/03 ,  C08K3/36 ,  C09D133/14 ,  C09J133/14

Abstract: Addition-fragmentation oligomers of the general formula Z—By-A-(B-A)x-B-A-By—Z, where the A monomers units are derived from a diester or diacid, the B monomer units are derived from a difunctional monomer having functional groups co-reactive and at least one of the A or B monomers comprise a 1-methylene-3,3-dimethylpropyl group.

Abstract translation: 通式为Z-By-A-（BA）xBA-By-Z的加成裂解低聚物，其中A单体单元衍生自二酯或二酸，B单体单元衍生自具有官能团共轭的双官能单体 - 反应性的并且A或B单体中的至少一种包含1-亚甲基-3,3-二甲基丙基。

公开(公告)号：US09414996B2

公开(公告)日：2016-08-16

申请号：US14437200

申请日：2013-10-31

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Guy D. Joly ,  Ahmed S. Abuelyaman ,  Ann R. Fornof ,  Bradley D. Craig ,  Larry R. Krepski ,  William H. Moser ,  Serkan Yurt ,  Joel D. Oxman ,  Afshin Falsafi

IPC: A61K6/083 ,  A61K6/00 ,  C09J133/14

CPC classification number: A61K6/083 ,  A61K6/0023 ,  A61K6/0088 ,  A61K6/0835 ,  C09J133/14 ,  C08L33/10

Abstract: A curable dental composition comprising an addition-fragmentation agent and a curable dental resin is disclosed.

Abstract translation: 公开了一种包含加成碎裂剂和可固化牙科用树脂的可固化牙科用组合物。

公开(公告)号：US09403966B2

公开(公告)日：2016-08-02

申请号：US14674666

申请日：2015-03-31

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Guy D. Joly ,  Larry R. Krepski ,  Ann R. Fornof ,  Serkan Yurt ,  Babu N. Gaddam ,  Ahmed S. Abuelyaman

IPC: C07C67/00 ,  C08K5/205 ,  C07C69/593 ,  C07C271/16 ,  C07C67/14 ,  C07C67/26 ,  A61K6/083 ,  C08K3/22 ,  C08K3/36 ,  C08K5/11 ,  C08K5/12 ,  C09D133/08

CPC classification number: C08K5/205 ,  A61K6/083 ,  C07C67/14 ,  C07C67/26 ,  C07C69/593 ,  C07C271/16 ,  C08K3/22 ,  C08K3/36 ,  C08K5/11 ,  C08K5/12 ,  C09D133/08 ,  C08L33/10 ,  C08L33/08

Abstract: Addition-fragmentation agents of the formula are disclosed: wherein R1, R2 and R3 are each independently Z-Q-, a (hetero)alkyl group or a (hetero)aryl group with the proviso that at least one of R1, R2 and R3 is Zm-Q-, Q is a linking group have a valence of m+1; Z is an ethylenically unsaturated polymerizable group, m is 1 to 6; each X1 is independently —O— or —NR4—, where R4 is H or C1-C4 alkyl, and n is 0 or 1.

Abstract translation: 公开了下式的加成碎裂剂：其中R1，R2和R3各自独立地为ZQ-，（杂）烷基或（杂）芳基，条件是R1，R2和R3中的至少一个为Zm -Q-，Q为连接基团，其价数为m + 1; Z为烯键式不饱和可聚合基团，m为1至6; 每个X1独立地是-O-或-NR4-，其中R4是H或C1-C4烷基，n是0或1。

公开(公告)号：US20150238389A1

公开(公告)日：2015-08-27

申请号：US14707096

申请日：2015-05-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： William H. Moser ,  Guy D. Joly ,  Larry R. Krepski ,  Babu N. Gaddam ,  Ahmed S. Abuelyaman ,  Bradley D. Craig ,  Timothy D. Dunbar ,  Chuntao Cao ,  Joel D. Oxman ,  Afshin Falsafi ,  Hoa T. Bui

IPC: A61K6/083 ,  A61K6/00

CPC classification number: A61K6/083 ,  A61K6/0023 ,  A61K6/0029 ,  A61K6/005 ,  C08L33/10

Abstract: Dental compositions are described comprising an addition-fragmentation agent of the formula: wherein R1, R2 and R3 are each independently Zm-Q-, a (hetero)alkyl group or a (hetero)aryl group with the proviso that at least one of R1, R2 and R3 is Zm-Q-; Q is a linking group have a valence of m+1; Z is an ethylenically unsaturated polymerizable group; m is 1 to 6; each X1 is independently —O— or —NR4—, where R4 is H or C1-C4 alkyl; and n is 0 or 1. Also described are dental articles prepared from a dental composition comprising an addition-fragmentation agent and methods of treating a tooth surface.

Abstract translation: 描述了牙科组合物，其包含下式的加成断裂剂：其中R 1，R 2和R 3各自独立地为Zm-Q-，（杂）烷基或（杂）芳基，条件是R 1 ，R2和R3是Zm-Q-; Q是连接基团，其价态为m + 1; Z是烯属不饱和可聚合基团; m为1〜6; 每个X 1独立地是-O-或-NR 4 - ，其中R 4是H或C 1 -C 4烷基; 并且n为0或1.还描述了由包含加成碎裂剂的牙科组合物制备的牙科用品和治疗牙齿表面的方法。

公开(公告)号：US11192989B2

公开(公告)日：2021-12-07

申请号：US16705336

申请日：2019-12-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Thomas P. Klun ,  Alan K. Nachtigal ,  Joseph C. Spagnola ,  Mark A. Roehrig ,  Jennifer K. Schnobrich ,  Guy D. Joly ,  Christopher S. Lyons

IPC: B32B27/08 ,  C08J7/04 ,  H01L51/00 ,  H01L51/52 ,  H01L51/44 ,  H01L51/10 ,  B05D3/06 ,  B32B27/30 ,  C07F7/18 ,  C09J133/14 ,  C08J7/043 ,  C08J7/044 ,  C08J7/048 ,  C09D133/14 ,  B05D1/00 ,  B05D3/10 ,  C08K3/34 ,  C09D135/02 ,  C23C14/08 ,  C23C14/34 ,  C23C16/40 ,  C23C16/44 ,  C08F130/08 ,  C09D143/04 ,  B32B27/28

Abstract: Compositions of matter described as urea (multi)-urethane (meth)acrylate-silanes having the general formula RA—NH—C(O)—N(R4)—R11—[O—C(O)NH—RS]n, or RS—NH—C(O)—N(R4)—R11—[O—C(O)NH—RA]n. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi)-urethane (meth)acrylate-silane precursor compound. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making such urea (multi)-urethane (meth)acrylate-silane precursor compounds, and their use in composite films and electronic devices are also described. Methods of using multilayer composite films as barrier films in articles selected from solid state lighting devices, display devices, and photovoltaic devices are also described.