Abstract:
Provided are porogen compositions and methods of using such porogen compositions in the manufacture of porous materials, for example, porous silicone elastomers. The porogens generally include comprising a core material and shell material different from the core material. The porogens can be used to form a scaffold for making a resulting porous elastomer when the scaffold is removed.
Abstract:
Crosslinked organic polymeric porous particles have a crosslinked organic solid phase and discrete pores dispersed within the crosslinked solid phase which pores are isolated from each other. These porous particles are prepared using one or more water-in-oil emulsions containing a polyfunctional reactive compound, a reagent that causes crosslinking, optionally an ethylenically unsaturated polymerizable monomer, and optionally an organic solvent, and can include various marker materials.
Abstract:
A cellulose aerogel comprises a plurality of cellulose nanoparticles. The cellulose nanoparticles preferably comprise at least 50% or 80% cellulose nanocrystals by weight of cellulose nanoparticles, and the cellulose nanoparticle aerogel preferably has a density of from 0.001 to 0.2 g/cm3 or from 0.2 to 1.59 g/cm3 The cellulose nanoparticle aerogel typically has an average pore diameter of less than 100 nmm and the cellulose nanoparticles may comprise anionic and/or cationic surface groups.
Abstract translation:纤维素气凝胶包含多个纤维素纳米颗粒。 纤维素纳米颗粒优选包含纤维素纳米颗粒重量的至少50%或80%纤维素纳米晶体,纤维素纳米颗粒气凝胶优选具有0.001至0.2g / cm 3或0.2至1.59g / cm 3的密度。纤维素纳米颗粒气凝胶通常 平均孔径小于100nmm,纤维素纳米颗粒可以包含阴离子和/或阳离子表面基团。
Abstract:
A process and apparatus for producing a nanovoided article, a nanovoided coating, and a low refractive index coating is described. The process includes providing a first solution of a polymerizable material in a solvent; at least partially polymerizing the polymerizable material to form a composition that includes an insoluble polymer matrix and a second solution, wherein the insoluble polymer matrix includes a plurality of nanovoids that are filled with the second solution; and removing a major portion of the solvent from the second solution. An apparatus for the process is also described, and includes a webline, a coating section, a partial polymerization section, and a solvent removal section.
Abstract:
Disclosed are dried porous crumbs of a hydrogenated block copolymer which is obtained by hydrogenating a block copolymer comprising (a) at least one polymer block composed mainly of aromatic vinyl monomer units and (b) at least one polymer block composed mainly of conjugated diene monomer units, and which has a molecular weight of 70,000 or more. The dried porous crumbs have a water content of 1% by weight or less and having the capability of absorbing an oil in an amount of 1.0 or more, in terms of the ratio of the weight of an oil, which is absorbed by the dried porous crumbs when the dried porous crumbs are immersed in the oil at 25° C. under atmospheric pressure for 1 minute, to the weight of the dried porous crumbs. Also disclosed is a method for producing the same. When the dried porous crumbs are used as a modifier in the production of a molding resin composition from a thermoplastic resin and a liquid additive, such as a softening agent or a silicone oil, a shaped article having an excellent appearance can be produced by molding the molding resin composition.
Abstract:
Synthetic methods for the preparation of hydrophobic organics aerogels. One method involves the sol-gel polymerization of 1,3-dimethoxybenzene or 1,3,5-trimethoxybenzene with formaldehyde in non-aqueous solvents. Using a procedure analogous to the preparation of resorcinol-formaldehyde (RF) aerogels, this approach generates wet gels that can be dried using either supercritical solvent extraction to generate the new organic aerogels or air dried to produce an xerogel. Other methods involve the sol-gel polymerization of 1,3,5 trihydroxy benzene (phloroglucinol) or 1,3 dihydroxy benzene (resorcinol) and various aldehydes in non-aqueous solvents. These methods use a procedure analogous to the one-step base and two-step base/acid catalyzed polycondensation of phloroglucinol and formaldehyde, but the base catalyst used is triethylamine. These methods can be applied to a variety of other sol-gel precursors and solvent systems. These hydrophobic organics aerogels have numerous application potentials in the field of material absorbers and water-proof insulation.
Abstract:
Fluoropolymer is advantageously foamed by first forming a composite structure of a layer of the fluoropolymer to be foamed and a layer of different material such as a different fluoropolymer not to be foamed, followed by heating the composite structure to the foamable state for the layer of fluoropolymer to be foamed, pressurizing the heated composite structure with supercritical carbon dioxide, rapidly depressurizing the heated composite structure, whereby the foamable layer foams and the other layer foams less or not at all, and cooling the foamed composite structure.
Abstract:
Normally hydrophobic foams, such as polyurethane foams and polymerized water-in-oil emulsion foams, are rendered hydrophilic by means of treatment with simple surfactants and hydrophilizing agent salts. Thus, a surfactant-containing foam is treated with a solution of, for example, calcium chloride, and is dried to leave a substantially uniformly distributed residue of hydrated or hydratable calcium chloride on the surfactant-containing internal foam surfaces. In-use, the combination of surfactant and calcium chloride hydrate provides a hydrophilic surface to the foam. Other hydratable calcium or magnesium salts such as magnesium chloride can be used. The resulting hydrophilized foams are suitable for use in absorbent devices, including diapers, sanitary napkins, bandages, and the like.
Abstract:
A microporous, polymeric film is prepared by dissolving methylene-chloride-soluble, film-forming polymers completely in methylene chloride. Then an aqueous phase is prepared containing non-methylene-chloride-soluble, water-soluble thickeners and, if desired, additives, and brought to a viscosity of about 0.07 to 0.5 Pa s. The aqueous phase is then dispersed in the polymer solution and the resultant paste is spread onto a support material or intermediate support, the methylene chloride is evaporated, the resultant membrane is transferred to the actual support, and finally the water is removed by drying.
Abstract:
AN AQUEOUS LATEX COATING COMPOSITION ADAPTED TO DEPOSIT FILMS WHICH DRY TO FORM A CELLULAR LAYER OF HIGH OPACITY IS PROVIDED BY SWELLING THE RESIN PARTICULES OF THE AQUEOUS LATEX WITH A PRIMARY ORGANIC SOLVENT WHICH IS ESSENTIALLY IMMISICIBLE IN THE AQUEOUS PHASE OF THE LATEX SUCH AS XYLENE, AND BY INTRODUCING INTO THE AQUEOUS PHASE AN AT LEAST PARTIALLY WATER MISCIBLE ORGANIC SOLVENT, SUCH AS PROPYLENE GLYCOL, HAVING A LOWER EVAPORATION RATE AND A LESSER CAPACITY FOR SOLVATING THE RESIN OF THE LATEX THAN SAID PRIMARY SOLVENT. WHEN THE PRIMARY SOLVENT EVAPORATES, A CELLULAR FILM IS FORMED, THE SECONDARY SOLVENT SERVING TO INCREASE THE OPACIFICATION WHICH IS OBTAINED. PARTICULATE MATTER OR MATERIAL WHICH CRYSTALLIZES TO FORM PARTICULATE MATTER IS INCORPORATED INTO THE LATEX IN SMALL AMOUNT. THE PARTICULATE MATTER SERVES TO INCREASE ULTIMATE OPACITY AND ALSO TO GENERATE OPACITY MORE RAPIDLY WHEN A DEPOSITED FILM IS DRIED.