公开(公告)号：US11161806B2

公开(公告)日：2021-11-02

申请号：US16604485

申请日：2018-06-19

Applicant: ASAHI KASEI KABUSHIKI KAISHA

Inventor： Dai Nagata ,  Sho Tamura

IPC: C07C253/24 ,  B01J8/24 ,  B01J23/00 ,  B01J8/00 ,  B01J35/08 ,  C07C255/08

Abstract: A process for producing a compound by use of a fluidized bed reactor comprising an internal space having a catalyst housed in a fluidizable manner therein, a first feed port into which a starting material gas comprising a hydrocarbon is fed to the fluidized bed reactor, a second feed port into which an oxygen-containing gas comprising oxygen is fed to the fluidized bed reactor, and a discharge port into which a reaction product gas is discharged from the fluidized bed reactor, including a reaction step of subjecting the hydrocarbon to a vapor phase catalytic oxidation reaction or a vapor phase catalytic ammoxidation reaction in the presence of the catalyst in the internal space to produce the corresponding unsaturated acid or unsaturated nitrile, respectively, wherein in the reaction step, a linear velocity (m/sec) of the starting material gas at the first feed port is adjusted against a degree of abrasion resistance (%) of the catalyst so as to satisfy a prescribed relation between them.

公开(公告)号：US20210316276A1

公开(公告)日：2021-10-14

申请号：US17191370

申请日：2021-03-03

Applicant: Alliance for Sustainable Energy, LLC

Inventor： Michael Brandon GRIFFIN ,  Calvin MUKARAKATE ,  Maarit Kristiina IISA ,  Abhijit DUTTA ,  Joshua A. SCHAIDLE ,  Andrew Nolan WILSON ,  Mark R. NIMLOS ,  Matthew Maurice Yung

IPC: B01J23/42 ,  B01J35/10 ,  B01J21/06 ,  B01J35/08 ,  B01D53/02

Abstract: The present disclosure relates to a catalyst that includes a support that includes a metal oxide and a metal deposited on the support, where the metal oxide includes at least one of TiO2, Al2O3, SiO2, CeO2, and/or ZrO2, the metal includes at least one of Pt, Pd, Ru Rh, Ni, and/or Mo, the metal is in the form of a particle, and the metal is present on the support at a concentration between about 0.1 wt % and about 5.0 wt %.

公开(公告)号：US20210308656A1

公开(公告)日：2021-10-07

申请号：US17349897

申请日：2021-06-16

Applicant: HUIZHOU UNIVERSITY

Inventor： Jinyun LIAO ,  Dongsheng LU ,  Hao LI ,  Quanbing LIU ,  Junhao LI

IPC: B01J23/75 ,  B01J35/00 ,  B01J37/04 ,  B01J37/06 ,  B01J37/00 ,  B01J37/08 ,  B01J35/08 ,  B01J35/02 ,  C01B3/04

Abstract: The present invention relates to the technical field of catalysts, and discloses a yolk/shell-type CoxCu1-xCo2O4@CoyCu1-yCo2O4 catalyst as well as a preparation method and application thereof to catalytic hydrogen generation. The preparation method of the yolk/shell-type CoxCu1-xCo2O4@CoyCu1-yCo2O4 catalyst includes the steps of: successfully synthesizing, by applying a hydrothermal synthesis method, a [Co(C6H12N4)2](NO3)2 solid sphere complex from a cobalt salt and hexamethyleneteramine serving as an alkali source; and then, performing calcination to obtain a yolk/shell-type Co3O4 microsphere structure, adsorbing Cu2+ on a surface in a physical adsorption manner, and performing calcination again to form yolk/shell-type CoxCu1-xCo2O4@CoyCu1-yCo2O4. The preparation method is simple, raw materials are cheap and available, and the prepared yolk/shell-type CoxCu1-xCo2O4@CoyCu1-yCo2O4 catalyst is high in purity, good in catalysis performance and capable of showing excellent catalytic activity in term of ammonia borane catalytic hydrolysis for hydrogen generation.

公开(公告)号：US11130109B2

公开(公告)日：2021-09-28

申请号：US16038167

申请日：2018-07-17

Applicant: BEIJING SANJU ENVIRONMENTAL PROTECTION & NEW MATERIALS CO., LTD

Inventor： Ke Lin ,  Carol A Ellis-Terrell ,  Ronghua Wei

IPC: B01J2/06 ,  B01J2/20 ,  B01J21/04 ,  B01J35/08 ,  B01J37/00 ,  B01J35/02

Abstract: Apparatuses and methods for making uniform spherical beads are disclosed. Specifically, the uniform spherical beads are made by dropping droplets on a droplet rolling part, creating beads by rolling the droplets on the droplet rolling part from one spot to another spot, and collecting the beads by a beads collector.

公开(公告)号：US20210206632A1

公开(公告)日：2021-07-08

申请号：US17058808

申请日：2019-05-14

Applicant: SAIDA FDS INC. ,  N.E. CHEMCAT CORPORATION

Inventor： Takeo YOSHIMURA ,  Noriyuki OHNEDA ,  Hironao SAJIKI ,  Yasunari MONGUCHI ,  Yoshinari SAWAMA ,  Tsuyoshi YAMADA ,  Tomohiro ICHIKAWA ,  Tomohiro MATSUO ,  Takumu TACHIKAWA ,  Akira KOMATSU

IPC: C01B3/22 ,  B01J23/42 ,  B01J21/18 ,  B01J35/10 ,  B01J35/08 ,  B01J8/02 ,  C07C5/367 ,  B01J35/02 ,  C07D217/02 ,  C07D213/16

Abstract: A device includes: a storage section which stores a solution containing an organic compound; a catalyst holding section to hold a solid catalyst; and a microwave irradiation mechanism which irradiates the solution passing through the catalyst holding section with a microwave, wherein the solid catalyst is a molded catalyst containing a noble metal supported on a carrier that has an average particle diameter larger than 100 μm. A hydrogen production method includes irradiating a solution containing an organic compound, the solution passing through a catalyst holding section holding a solid catalyst, with a microwave, the solid catalyst being a molded catalyst containing a noble metal supported on a carrier that has an average particle diameter larger than 100 μm. Both device and method do not require a high-temperature heat source, enable easy collection, replacement, of the catalyst, and can be used for production of hydrogen.

公开(公告)号：US10988556B2

公开(公告)日：2021-04-27

申请号：US16934434

申请日：2020-07-21

Applicant: King Abdullah University of Science and Technology

Inventor： Yu Han ,  Qiwei Tian ,  Xinglong Dong ,  Zhaohui Liu ,  Jean-Marie Basset ,  Youssef Saih

IPC: C08F8/30 ,  C01B39/04 ,  B01J29/40 ,  B01J29/89 ,  B01J29/08 ,  B01J29/70 ,  B01J29/80 ,  B01J37/00 ,  B01J37/02 ,  C08F226/04 ,  C08F230/02 ,  B01J29/44 ,  B01J29/03 ,  B01J35/00 ,  B01J35/10 ,  C08F8/44 ,  C10G3/00 ,  B01J35/08 ,  B01J29/00 ,  C08F8/32 ,  C08F8/40 ,  B01J29/06

Abstract: According to one or more embodiments, cationic polymers may be produced which include one or more monomers containing cations. Such cationic polymers may be utilized as structure directing agents to for mesoporous zeolites. The mesoporous zeolites may include micropores as well as mesopores, and may have a surface area of greater than 350 m2/g and a pore volume of greater than 0.3 cm3/g. Also described are core/shell zeolites, where at least the shell portion includes a mesoporous zeolite material.

公开(公告)号：US10967361B2

公开(公告)日：2021-04-06

申请号：US15940122

申请日：2018-03-29

Applicant: ACADEMIA SINICA ,  National Taiwan University

Inventor： Kuei-Hsien Chen ,  Indrajit Shown ,  Wei-Fu Chen ,  Li-Chyong Chen Lin

IPC: B01J27/04 ,  B01J35/00 ,  B01J35/08 ,  B01J35/02 ,  B01J37/10 ,  B01J37/34 ,  B01J19/12 ,  C01B3/04 ,  C01B13/02 ,  C07C45/00 ,  C07C1/02 ,  B01J21/18 ,  C07C29/159 ,  C07C45/45 ,  B01J27/20 ,  B01J23/14 ,  B01J37/03 ,  B01J37/04

Abstract: Disclosed herein are carbon doped tin disulphide (C—SnS2) and other SnS2 composites as visible light photocatalyst for CO2 reduction to solar fuels. The in situ carbon doped SnS2 photocatalyst provide higher efficiency than the undoped pure SnS2. Also disclosed herein are methods for preparing the catalysts.

公开(公告)号：US20210060537A1

公开(公告)日：2021-03-04

申请号：US16963639

申请日：2019-11-19

Applicant: LG CHEM, LTD.

Inventor： Ye Seul HWANG ,  Dong Hyun KO ,  Joohyuck LEE ,  Myungji SUH

IPC: B01J23/889 ,  B01J23/80 ,  B01J23/86 ,  B01J21/12 ,  B01J35/08 ,  B01J37/02 ,  C07C5/48

Abstract: Provided is a catalyst for an oxidative dehydrogenation reaction that comprises: a porous support; a core portion supported on the porous support and containing a first zinc ferrite-based catalyst; and a shell portion supported on the core portion and containing a second zinc ferrite-based catalyst, in which the first zinc ferrite-based catalyst and the second zinc ferrite-based catalyst are different from each other.

公开(公告)号：US10933406B2

公开(公告)日：2021-03-02

申请号：US16395218

申请日：2019-04-25

Applicant: JIANGXI UNIVERSITY OF SCIENCE & TECHNOLOGY

Inventor： Honghui Jiang ,  Yiqun Deng ,  Hui Yang ,  Tongxiang Liang ,  Xiaopeng Qi ,  Zhuowu Zhen ,  Rigang Nie ,  Yucheng Lv ,  Wenyu Shen

IPC: B01J23/78 ,  B01J23/745 ,  B01J23/80 ,  B01J23/83 ,  B01J35/00 ,  B01J35/02 ,  B01J35/08 ,  B01J37/00 ,  B01J37/04 ,  B01J37/08 ,  C02F1/32 ,  C02F1/72 ,  C02F101/30

Abstract: A method of preparing large-size high-porosity Fe-doped photocatalytic porous magnetic microspheres, including: dissolving a soluble macromolecule in a distilled water to obtain a solution A having a concentration of 0.5-1.5 wt %; adding a photocatalyst to the solution A, and uniformly stirring the solution A to obtain a suspension B; mixing a saturated soluble ferric salt solution with the suspension B, and uniformly stirring the mixture to obtain a suspension C; dropwise adding the suspension C to a high-concentration alkali solution by a syringe equipped with a suitable needle size to form microspheres; ageing the reaction system and drying the formed microspheres after adding; calcining the dried microspheres at 600-1100° C.; cooling the calcined microspheres to obtain the large-size high-porosity Fe-doped photocatalytic porous magnetic microspheres.

公开(公告)号：US20210046468A1

公开(公告)日：2021-02-18

申请号：US16488728

申请日：2018-04-04

Applicant: Sasol Germany GmbH

Inventor： Christian Schrage ,  Marco Friedrich

IPC: B01J37/00 ,  B01J35/00 ,  B01J35/02 ,  B01J35/08 ,  B01J35/10 ,  B01J37/10 ,  B01J21/04 ,  B01J2/16

Abstract: The present invention relates to granulated particles with improved attrition and a method for producing granulated particles by fluidized bed granulation of inorganic particles wherein particles of reduced particle size are fed into a fluldized-bed granulation reactor thereby producing granulated particles with improved attrition.